Conductive foamed polypropylene material and preparation method thereof

A technology for foaming polypropylene and polypropylene, applied in the field of conductive foamed polypropylene materials and their preparation, can solve the problems of limiting the use range of materials, affecting the mechanical properties of materials, and poor foaming effect, and achieving good mechanical properties, The effect of improving electrical conductivity and reducing surface resistance

Pending Publication Date: 2020-04-03
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] For traditional conductive materials, in order to achieve a better conductive effect, the amount of conductive carbon black added to the material is usually about 25-40%, which greatly increases the cost of the material. At the same time, the addition of a large amount of conductive carbon black will greatly affect the material. The mechanical properties of the material itself, which limits the scope of use of the material
At the same time, due to the low melt strength of the traditional micro-foamed polypropylene material, the foaming effect is often poor, and the cells are easy to collapse and rupture, so the practical application is very limited

Method used

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  • Conductive foamed polypropylene material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Weigh 74.4 parts of copolymerized polypropylene with a melt index of 45g / 10min, 10 parts of conductive carbon black, 5 parts of POE toughening agent with a melt index of 5g / 10min, 10 parts of filler talcum powder, and 0.1 parts of hindered amine antioxidant. parts, 0.2 parts of hindered phenolic antioxidant, and 0.3 parts of processing aids are pre-mixed in a high mixer to obtain uniformly mixed raw materials; the mixed raw materials are placed in a twin-screw extruder, and the temperature is controlled at 190-230 ° C , under the condition of screw speed of 300 rpm, melt extrusion, granulation and drying, and prepare a prefabricated material of conductive foamed polypropylene material; mix the foaming agent with the prefabricated material prepared above according to the ratio of 4% by mass fraction Finally, according to the normal injection molding process, it is injected into a product or a sample to obtain a foamed polypropylene material with excellent electrical condu...

Embodiment 2

[0034] Weigh 64.6 parts of homopolypropylene with a melt index of 60g / 10min, 12 parts of conductive carbon black, 8 parts of POE toughening agent with a melt index of 8g / 10min, 15 parts of filler calcium carbonate, hindered phenolic antioxidant 0.1 part, 0.1 part of phosphite antioxidant, and 0.2 part of processing aid are pre-mixed in a high-mixer to obtain uniformly mixed raw materials; the mixed raw materials are placed in a twin-screw extruder, and the temperature is controlled at 190- 230°C, melt extrusion under the condition of screw speed 320 rpm, granulate and dry, and prepare the prefabricated material of conductive foamed polypropylene material; mix the foaming agent with the prefabricated material prepared above in a proportion of 4% by mass After the materials are mixed evenly, they are injected into parts or samples according to the normal injection molding process to obtain a foamed polypropylene material with excellent electrical conductivity.

Embodiment 3

[0036] Weighed 71.5 parts of copolymerized polypropylene with a melt index of 80g / 10min, 13 parts of conductive carbon black, 7 parts of POE toughening agent with a melt index of 0.1g / 10min, 8 parts of filler barium sulfate, hindered amine antioxidant 0.1 part, 0.1 part of hindered phenolic antioxidant, 0.2 part of phosphite antioxidant, 0.1 part of processing aid are pre-mixed in a high-mixer to obtain uniformly mixed raw materials; the mixed raw materials are placed in a twin-screw extruder In the machine, the temperature is controlled at 190-230 ° C, the screw speed is 350 rpm, melted and extruded, granulated and dried, and the prefabricated material of the conductive foamed polypropylene material is prepared; the foaming agent is mixed with a mass fraction of 3%. After mixing the prefabricated material with the above-mentioned ratio evenly, injection molded into parts or samples according to the normal injection molding process to obtain a foamed polypropylene material with...

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Abstract

The invention discloses a conductive foamed polypropylene material and a preparation method thereof. The conductive foamed polypropylene material is prepared from a conductive foamed polypropylene prefabricated material and a foaming agent, the adding amount of the foaming agent accounts for 2-5% of the weight of the conductive foamed polypropylene material, and the conductive foamed polypropyleneprefabricated material is prepared from the following components in parts by weight: 54 to 86.8 parts of polypropylene, 8 to 15 parts of conductive carbon black, 0 to 10 parts of a toughening agent,5 to 20 parts of a filler, 0.1 to 0.5 part of an antioxidant and 0.1 to 0.5 part of a processing aid. According to the invention, a micro-foaming process is applied to a conductive modified polypropylene material, conductive carbon black is added to form a cross-linked network structure, and based on the formation of foam holes in the material, the conductive carbon black dispersed in a base material is gathered in the base body intensively in volume, so that the effective and compact conductive path is formed in the material so as to reduce the use amount of the conductive additive of the material, effectively and significantly reduce the surface resistance of the material, improve the conductive effect of the material and reduce the cost of the material; and the preparation process is simple, and the prepared polypropylene material is excellent in performance.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, in particular to a conductive foamed polypropylene material and a preparation method thereof. Background technique [0002] Due to its good comprehensive properties, polypropylene materials are widely used in the automotive field and electronic and electrical products. However, in addition to the requirements of good mechanical properties, processing properties, weather resistance and other characteristics of these polypropylene parts, some special fields require materials to have special properties such as antistatic performance and light weight performance. Combined with the conductive technology, a polypropylene material with low price and excellent mechanical properties can be prepared. [0003] For traditional conductive materials, in order to achieve a better conductive effect, the amount of conductive carbon black added to the material is usually about 25-40%, which greatly incr...

Claims

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Application Information

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IPC IPC(8): C08L23/14C08L23/12C08L23/08C08K13/02C08K3/04C08J9/32
CPCC08J9/32C08J2323/14C08J2323/12C08K13/02C08K3/04C08K2201/001C08J2203/22
Inventor 杨桂生计娉婷朱敏廖雄兵
Owner HEFEI GENIUS NEW MATERIALS
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