Method for preparing ruthenium trichloride from ruthenium-containing waste
A technology of ruthenium trichloride and waste materials, which is applied in the field of preparing ruthenium trichloride, can solve the problems of high equipment cost, poor safety, and large consumption, and achieve fast reaction rate, good safety, and high conversion rate Effect
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Embodiment 1
[0020] Embodiment 1, prepares ruthenium trichloride with ruthenium carbon catalyst recovery waste material, comprises the following steps:
[0021] (1) Roasting: Take 1000kg of ruthenium carbon catalyst to recycle waste, in which the ruthenium content is 0.24%, and roast it at 200°C, 400°C, and 800°C for 2 hours, and pass it into nitrogen protection to obtain 10.25kg of roasted material , wherein the ruthenium content is 23.35%;
[0022] (2) Preparation of RuO 4 : Roasting material is added in the reaction kettle, then add 11.50kg sodium chlorate, 0.14kg liquid bromine and 12.00kg water, stir reaction under 100 ℃ of conditions, react 1.5h, wherein the described roasting material in parts by weight Ruthenium content: sodium chlorate: liquid bromine: water is 100:480:6:500;
[0023] (3) Preparation of H 2 RuCl 5 Solution: absorb the RuO produced by the reaction with a 5-grade hydrochloric acid bottle at room temperature 4 , that is, get H 2 RuCl 5 solution;
[0024] (4) ...
Embodiment 2
[0026] Embodiment 2, prepares ruthenium trichloride with ruthenium alumina catalyst recovery waste material, comprises the following steps:
[0027] (1) Roasting: Take 500kg of ruthenium alumina catalyst to recycle waste, in which the ruthenium content is 1.39%, and roast it at 200°C, 400°C, and 800°C for 2 hours, and pass through nitrogen protection to obtain 129.89kg of roasted material , the ruthenium content is 5.35%;
[0028] (2) Preparation of RuO 4 Roasting material is added in the reactor, then add 38.23kg sodium chlorate, 0.28kg liquid bromine and 55.60kg water, stir reaction under 60 ℃ of conditions, react 5h, wherein said roasting material by weight part contains The amount of ruthenium: sodium chlorate: liquid bromine: water is 100:550:4:800;
[0029] (3) Preparation of H 2 RuCl 5 Solution: absorb the RuO produced by the reaction with a 5-grade hydrochloric acid bottle at room temperature 4 , that is, get H 2 RuCl 5 solution;
[0030] (4) Drying: the genera...
Embodiment 3
[0032] Embodiment 3, prepare ruthenium trichloride with the aqua regia insoluble slag containing ruthenium waste after having extracted platinum, palladium, comprise the following steps:
[0033] (1) Roasting: Take 50kg of ruthenium-containing waste in aqua regia insoluble slag after extracting platinum and palladium, in which the ruthenium content is 34.81%, and roast it at 200°C, 400°C, and 800°C for 2 hours, and pass it into Nitrogen protection, obtain roasting material 46.31kg, ruthenium content is 37.57%;
[0034] (2) Preparation of RuO 4 : Roasting material is added in the reactor, then add 34.80kg sodium chlorate, 0.52kg liquid bromine and 104.40kg water, stir reaction under 80 ℃ of conditions, react 3h, wherein said roasting material by weight part contains The amount of ruthenium: sodium chlorate: liquid bromine: water is 100:200:3:600;
[0035] (3) Preparation of H 2 RuCl 5 Solution: Absorb the RuO produced by the above reaction with a 5-grade hydrochloric acid b...
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