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Preparation method of smoke suppressant

A smoke suppressant and a technology for preparation steps are applied in the field of smoke suppressant preparation, and can solve the problems of no conversion, poor plastic compatibility and the like, and achieve the effects of improving compatibility and maintaining integrity

Inactive Publication Date: 2019-08-09
李伯平
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The main technical problem to be solved by the present invention is that a large amount of toxic smoke and CO are easily produced when burning polymer materials, wherein CO is the main toxic gas that causes casualties in fires. At present, most of the smoke suppressants use expensive ammonium molybdate and trioxide Molybdenum has a good smoke suppression effect, but has poor compatibility with plastics and has no conversion effect on CO generated by combustion. A preparation method for smoke suppressant is provided

Method used

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Examples

Experimental program
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Effect test

preparation example Construction

[0031] Preparation of oxidized starch: Take 50g of corn starch and 200mL of deionized water into a three-necked flask with a stirrer, heat in a water bath to 80°C, start the stirrer, and stir at a speed of 250r / min for 30min to obtain gelatinized starch. Add 180 mL of deionized water to the gelatinized starch, and cool down to normal temperature to obtain diluted gelatinized starch;

[0032] Add 50 mL of 3% ferrous sulfate solution to the diluted gelatinized starch, stir for 25 minutes, then continue to add 60 mL of 20% hydrogen peroxide, and adjust the pH to 6.0 with 15% sodium bicarbonate solution. After stirring for 2 hours, the oxidized starch solution was obtained, and the oxidized starch solution was mixed with 600 mL of absolute ethanol, placed in a high-speed centrifuge at a speed of 3200 r / min for 10 minutes, and the supernatant was removed to obtain the oxidized starch, which was set aside;

[0033] Preparation of vanadyl phosphate:

[0034] Put 4g of vanadium pento...

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PUM

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Abstract

Belonging to the technical field of smoke suppression, the invention discloses a preparation method of a smoke suppressant. Sepiolite powder involved in the invention is a magnesium-rich silicate compound, and can produce magnesium hydroxide crystals and phosphate under the action of ammonia gas and phosphate, the micro-porous structure in sepiolite itself is filled with magnesium hydroxide crystals, sepiolite powder is rich in high-temperature resistant silicate fiber crystals, polymer molten drops do not drip easily under the action of large molecular action force, thus keeping the integrityof the polymer matrix skeleton, and achieving flame retardant purpose. The melamine and sodium pyrophosphate in the smoke suppressant react to generate reacts with melamine pyrophosphate, a sepiolite-based smoke suppression carrier can expand during combustion at a high temperature state to coat melamine pyrophosphate, the residual carbon rate increases, and the smoke emission decreases, thusreaching the purposes of flame retardance and smoke suppression. The method provided by the invention uses a ferrous sulfate solution and hydrogen peroxide to oxidize corn starch, and improves the compatibility of modified corn starch and the polymer resin.

Description

technical field [0001] The invention discloses a preparation method of a smoke suppressant and belongs to the technical field of smoke suppression. Background technique [0002] Smoke suppressant is a compound that can suppress the amount of smoke generated by various polymer materials during combustion. Through special chemical and physical effects, it can significantly reduce the smoke of various flame-retardant polymer materials such as wood under the condition of a small amount of use. , plastics, rubber, coatings, adhesives and thermal insulation foam materials in the combustion process of smoke density and smoke, and appropriately improve the flame retardancy and oxygen index of these materials. The characteristic is to reduce the amount of smoke generated by product combustion and play a role in delaying combustion. The application fields include building decoration material industry, plastic industry, thermal insulation material industry, packaging material industry...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L3/10C08L63/00C08L5/16C08K13/06C08K9/02C08K7/10C08K5/3492C08K3/32C08K3/28C08B31/18C08B30/18
CPCC08B30/18C08B31/18C08L3/10C08L2201/02C08L2205/03C08L63/00C08L5/16C08K13/06C08K9/02C08K7/10C08K5/34928C08K3/32C08K3/28
Inventor 李伯平
Owner 李伯平
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