All-solid state li ion batteries comprising mechanically flexible ceramic electrolytes and manufacturing methods for the same
By using mechanically flexible ceramic solid-state electrolyte and freeze-casting technology of nanoparticle slurry in Li-ion batteries, the existing battery's difficulties in balancing energy density, cycle life and safety are solved, and efficient and safe battery performance is achieved.
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[0058] Disclosed herein is an all-solid-state mechanically flexible Li-ion battery (LIB) with a mechanically flexible solid-state ceramic electrolyte formed by preparing a nanoparticle slurry of ceramic ultra-high-speed ionic conductors in accordance with the present disclosure, and freeze casting the slurry or casting, and preferably combined with sintering. The nanoparticle slurry is formed into a thin film by casting, preferably followed by sintering at temperatures below 1100°C, and then the structure in the LIB is further formed. Their conductivity at operating temperature is preferably similar to that of liquid electrolytes, i.e., 10 -6 -1 S cm -1 , and the activation energy is less than 0.6 eV.
[0059] Disclosed herein is an all-solid-state mechanically flexible LIB comprising a ceramic solid-state electrolyte comprising lithium selected from the group consisting of perovskite-type oxides, NASICON-structured lithium electrolytes, and transition metal oxide-containing...
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