Quartz glass fiber-containing prepreg quartz glass fiber-containing film and quartz glass fiber-containing substrate

A technology of quartz glass fiber and prepreg, which is applied in the direction of glass/slag layered products, layered products, chemical instruments and methods, etc., and can solve problems such as the inability to adhere to the plating layer, the reduction of dielectric properties, and poor conduction. , to achieve excellent surface uniformity, high tensile stiffness characteristics, and excellent plating properties

Inactive Publication Date: 2019-07-26
SHIN ETSU CHEM IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In addition, since the general-purpose glass cloth has hollow fibers containing air bubbles, the plating solution, cleaning solution, etching solution, etc. used in the substrate forming process will seep into the air bubbles in the cloth, so that the plating layer cannot be adhered, resulting in damage. The above defects: the occurrence of poor conduction and the reduction of dielectric properties, etc.

Method used

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  • Quartz glass fiber-containing prepreg quartz glass fiber-containing film and quartz glass fiber-containing substrate
  • Quartz glass fiber-containing prepreg quartz glass fiber-containing film and quartz glass fiber-containing substrate
  • Quartz glass fiber-containing prepreg quartz glass fiber-containing film and quartz glass fiber-containing substrate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1～2、 comparative example 1～7

[0131] (Preparation of quartz glass fiber)

[0132] Glass cloths having a thickness of 0.1 mm used in Examples 1 to 2 and Comparative Examples 1 to 7 were prepared using glasses shown in Table 1 below. Table 1 also describes the types and doses of α-rays, and the ion components of Na, Li, and K. In addition, the quartz glass cloths of Comparative Examples 6 and 7 were prepared by adding an ionic component when producing the quartz glass cloth of Example 1.

[0133] [Table 1]

[0134]

[0135] (Preparation of Curable Resin Composition)

[0136] Prepare by 10 mass parts of cresol novolac type epoxy resin (trade name: EPICLON N-695, DIC Co., Ltd. manufacture), 5 mass parts of phenol novolac resin (trade name: PEHNOLITE TD-2090, DIC Co., Ltd. manufactured by the company), 0.1 parts by mass of imidazole-based curing accelerator (trade name: 2E4MZ, manufactured by Shikoku Chemicals Co., Ltd.), 85 parts by mass of spherical silica (trade name: SC-2050-SE, manufactured by Admate...

Embodiment 1、2

[0146] As shown in Table 2, it can be seen that Examples 1 and 2 show good values ​​in dielectric properties by using high-purity quartz glass cloth. Thus, it was shown that the invention is useful.

Embodiment 3～4、 comparative example 8～14

[0151] (glass cloth)

[0152] Glass cloths having a thickness of 0.1 mm were prepared using glasses shown in Table 3 below. The species and bubbles are recorded at the same time. In addition, the glass of Comparative Examples 8 to 13 had too many bubbles, and only 200 cells could be measured.

[0153] [table 3]

[0154]

[0155] (Preparation of film)

[0156] Prepare by 10 mass parts of cresol novolac type epoxy resin (trade name: EPICLON N-695, DIC Co., Ltd. manufacture), 5 mass parts of phenol novolac resin (trade name: PEHNOLITE TD-2090, DIC Co., Ltd. manufactured by the company), 0.1 parts by mass of imidazole-based curing accelerator (trade name: 2E4MZ, manufactured by Shikoku Chemicals Co., Ltd.), 85 parts by mass of spherical silica (trade name: SC-2050-SE, manufactured by Admatechs Co., Ltd. ) and the slurry of the filler-containing epoxy resin composition that the MEK solvent of 50 mass parts forms.

[0157] Each of the glass cloths shown in Table 3 was impreg...

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Abstract

The present invention is a quartz glass fiber-containing prepreg, which is characterized by including: (A) a quartz glass fiber; and (B) a curable resin composition, wherein at least one condition ofconditions: (1) a dose of alpha-ray contained in the quartz glass fiber is 0.005 c / cm<2>*hr or smaller, and, each of metal ion contents of Na<+>, Li<+> and K<+> is 1 ppm or lower; (2) the quartz glassfiber contains the number of foams of 10 foams / m<2> or smaller a unit area; and (3) the quartz glass fiber-containing prepreg has the common bending stiffness in the range of a thickness of 100 to 200 [mu]m measured by a method described in JIS R 3420:2013 of 500 N*m<2> or larger is satisfied. This provides a quartz glass fiber-containing prepreg that has particularly excellent dielectric characteristics, has excellent dielectric characteristics and the heat resistance, and / or has high handling property because of high bending stiffness characteristics.

Description

technical field [0001] The invention relates to a prepreg containing quartz glass fiber, a film containing quartz glass fiber and a substrate containing quartz glass fiber. Background technique [0002] With the development of digital technology, electronic equipment represented by personal computers and mobile phones has become thinner, lighter, smaller, and more functional. Therefore, for example, printed circuit boards, which are typical components, require high-density packaging and thinner and smaller sizes. In response to this situation, there is a strong demand for improved properties of glass fiber-containing prepregs, glass fiber-containing substrates, and films. [0003] In addition, with the advancement of high-speed and high-frequency computers, mobile devices, and communication infrastructure, etc., there is a demand for low-dielectric substrates and films that have excellent transmission loss, that is, low transmission loss, which is a characteristic required f...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/04C08L61/10C08K7/26C08K7/14C08J5/24C08J5/18B32B17/04B32B17/12B32B33/00
CPCC08J5/18B32B5/02B32B5/26B32B33/00C08J2363/04C08J2461/06C08K7/26C08K7/14B32B2250/02B32B2250/20B32B2260/046B32B2260/023B32B2262/101B32B2307/204B32B2307/306B32B2307/3065B32B2307/51C08J5/244C03C3/06C03C2201/02C03C13/045C03C25/47C08J5/043C08J2363/00C08K3/013C08J5/08C08K3/36
Inventor 堤吉弘浜本佳英塩原利夫大崎明彦
Owner SHIN ETSU CHEM IND CO LTD
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