Waterborne anti-corrosion coating composition and anti-corrosion coating method
A technology of anti-corrosion coatings and compositions, applied in anti-corrosion coatings, epoxy resin coatings, devices for coating liquids on the surface, etc., can solve problems such as inability to exhibit anti-corrosion properties, spot rust, etc., and achieve excellent storage stability , sufficient corrosion resistance, and the effect of reducing the total labor force
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[0177] The present invention is further explained below with reference to Examples. Hereinafter, "parts" and "%" represent "parts by mass" and "% by mass", respectively.
[0178] Production of water-reducible polyamine resin (A)
manufacture example 1
[0180] 3200 parts of "jER828" (trade name, manufactured by Mitsubishi Chemical Corporation; bisphenol A resin with an epoxy equivalent of 190 and a number average molecular weight of 375), 1700 parts of bisphenol A (molecular weight of 228), 900 parts of methyliso Butyl ketone and 5.0 parts of benzyldimethylamine were placed in a flask equipped with a stirrer, a thermometer, a nitrogen gas introduction tube, and a reflux condenser, and reacted at 120 °C until the epoxy equivalent per unit of non-volatile content It is 2500g / equivalent.
[0181] Then, 590 parts of a ketimidation product of 3,3'-diaminodipropylamine and methyl isobutyl ketone were added, and reacted at 120°C for 1 hour.
[0182] Then, 54 parts of deionized water and 380 parts of glycidyl neodecanoate were put therein, and reacted at 100° C. for 2 hours.
[0183] Thereafter, 90 parts of acetic acid and 70 parts of deionized water were added, and the inner solution was stirred and mixed. After adding 6,500 parts...
manufacture example 2 to manufacture example 8
[0186] Water-dilutable polyamine resins (A-2) to (A8) were produced in the same manner as above except for using the formulation composition of Table 1 below.
[0187] Table 1
[0188]
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