Acrylic protective paint for helmet and preparation method thereof
A protective paint, acrylic technology, applied in the field of coatings, can solve the problems of not meeting the requirements of helmet paint, high VOC content in paint, pollution and fire, etc., to achieve good alignment, good adhesion, and solve the effect of blackening
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preparation example Construction
[0041] Wherein the preparation method of polypyrrole modified porous silicon is as follows:
[0042] 1. First prepare the Si-H surface, the preparation process of the Si-H surface is as follows:
[0043] Silicon wafers were ultrasonically cleaned with deionized water, acetone and ethanol in sequence, and then dried with high-purity nitrogen; at 90°C, in a mixed solution of 98wt% concentrated sulfuric acid and 30wt% hydrogen peroxide (3 / 1, v / v) Oxidation for 2 hours; after the oxidation reaction, wash with ionized water and dry with nitrogen, then in 40% NH 4 Soak in F aqueous solution for 15 minutes; take out the silicon wafer, rinse it with deionized water, and then dry it with high-purity nitrogen.
[0044] 2. Prepare the Si-Cl surface, the preparation process is as follows:
[0045] Incorporation of freshly prepared Si-H surfaces into PCl 5 Add a small amount of benzoyl peroxide as an initiator to a chlorobenzene solution, and react with 80°C to 100°C for 45 to 60 minute...
Embodiment 1
[0082] An acrylic protective paint for a helmet, wherein the protective paint comprises: 30 parts by mass of water-based acrylic resin A and 10 parts by mass of water-based acrylic resin B;
[0083] Wherein, the glass transition temperature of the water-based acrylic resin A is 100°C to 110°C, the glass transition temperature of the water-based acrylic resin B is 50°C to 60°C, and the water-based acrylic resin B is vinyl chloride / N-substituted Maleic amine / acrylate copolymer resin.
[0084] In the above scheme, the mass ratio of vinyl chloride, N-substituted maleic amine and acrylate copolymer resin in the water-based acrylic resin B is 1 / 0.3 / 0.5.
[0085] In the above scheme, the protective paint also includes 5 parts by mass of film-forming aids, 0.1 parts by mass of neutralizers, 0.1 parts by mass of defoamers, 0.3 parts by mass of leveling agents, and 0.3 parts by mass of substrate wetting Agent, 1 mass part of silver powder directional agent, 0.5 mass part of thickener a...
Embodiment 2
[0094] An acrylic protective paint for a helmet, wherein the protective paint comprises: 40 parts by mass of water-based acrylic resin A and 20 parts by mass of water-based acrylic resin B;
[0095] Wherein, the glass transition temperature of the water-based acrylic resin A is 100°C to 110°C, the glass transition temperature of the water-based acrylic resin B is 50°C to 60°C, and the water-based acrylic resin B is vinyl chloride / N-substituted Maleic amine / acrylate copolymer resin.
[0096] In the above scheme, the mass ratio of vinyl chloride, N-substituted maleic acid amine and acrylate copolymer resin in the water-based acrylic resin B is 1 / 0.7 / 0.8.
[0097] In the above scheme, the protective paint also includes 10 parts by mass of film-forming aids, 0.3 parts by mass of neutralizers, 0.2 parts by mass of defoamers, 0.5 parts by mass of leveling agents, 0.5 parts by mass of substrate wetting Agent, 2 parts by mass of silver powder directional agent, 1 part by mass of thic...
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