Ultrathin aerogel composite material and method for preparing same
A composite material and airgel technology, applied in the field of ultra-thin airgel materials, can solve the problems that cannot be applied to environmental protection and flexibility requirements, airgel paper cannot be applied to the field of clothing and apparel, and cannot be applied to the field of electronic products. Achieve excellent heat insulation performance, high pass rate, and soft hand feeling
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Embodiment 1
[0029] Example 1: 1.5mm polyester non-woven ultra-thin aerogel material
[0030] Place a 100m long, 1.5m wide and 1.5mm thick polyester non-woven fabric in a roll form in a suitable container.
[0031] Take 50kg, 120kg, 20kg, 150g, 100g ethyl orthosilicate, ethanol, water, 2mol / L ammonia water, 0.2mol / L ammonium fluoride sulfuric acid solution and put them into a stainless steel mixing tank and mix them evenly. After stirring for 10-20 minutes , Pour the sol into a container placed in a roll of polyester non-woven fabric and fully immerse it. Seal and let stand for 24h, wait for gel. After gelation, unwind and rewind the whole wet gel into absolute ethanol for 36h aging, after aging, transfer the wet gel into a mixed modification solution containing 30L hexamethyldisilazane and 300L absolute ethanol , Modified for 24h. After the modification, the wet gel is taken out and dried by supercritical fluid to obtain a silica aerogel and polyester non-woven fabric composite material.
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Embodiment 2
[0033] Example 2: 0.1mm polyester non-woven fabric ultra-thin aerogel material
[0034] Place a 100m long, 0.5m wide, and 0.1mm thick polyester non-woven fabric in a roll form in a suitable container.
[0035] Take 2.5kg, 6kg, 0.8kg, 10g, 5g of ethyl orthosilicate, ethanol, water, 2mol / L ammonia water, 0.2mol / L ammonium fluoride sulfuric acid solution, respectively, into a stainless steel mixing tank and mix well, and stir for 10-20 Minutes later, pour the sol into a container placed in a roll of polyester non-woven fabric and fully impregnate it. Seal and let stand for 24h, wait for gel. After gelation, put the whole wet gel in absolute ethanol to age for 36h. After aging, transfer the wet gel into a mixed modification solution containing 0.5L of hexamethyldisilazane and 5L of absolute ethanol. 24h. After the modification, the wet gel is taken out, dried by supercritical fluid and then unwinded and rewinded to obtain a silica aerogel and polyester non-woven fabric composite mat...
Embodiment 3
[0037] Example 3: 0.2mm glass fiber surface felt ultra-thin aerogel material
[0038] Cut 100 pieces of 30cm long, 20cm wide, and 0.2mm thick glass fiber surface mat, stack them neatly in a suitable container, take ethyl orthosilicate, ethanol, water, 2mol / L ammonia, 0.2mol / L 2.5kg, 6kg, 0.8kg, 10g, and 5g of ammonium fluoride sulfuric acid solution were added into a stainless steel stirring tank and mixed uniformly. After stirring for 10-20 minutes, the sol was poured into a container on which glass fiber surface felt was placed and fully immersed. Seal and let stand for 24h, wait for gel. After aging, transfer the wet gel into a mixed modification solution containing 1L of dimethyldiethoxysilane, 10L of absolute ethanol and catalyst, and modify for 48h. After the modification, the wet gel is taken out, dried by supercritical fluid, and then unwound and rewinded to obtain a silica aerogel and glass fiber surface mat composite material.
[0039] The prepared silica aerogel and gl...
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