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Ultrathin aerogel composite material and method for preparing same

A composite material and airgel technology, applied in the field of ultra-thin airgel materials, can solve the problems that cannot be applied to environmental protection and flexibility requirements, airgel paper cannot be applied to the field of clothing and apparel, and cannot be applied to the field of electronic products. Achieve excellent heat insulation performance, high pass rate, and soft hand feeling

Inactive Publication Date: 2017-09-05
航天海鹰(镇江)特种材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are also studies on ultra-thin airgel composite materials in the prior art, such as patent CN201310247592.2-airgel paper, its preparation method and application, CN201310260138-a kind of airgel paperboard and its preparation method, all of which are silicon dioxide Airgel is combined with inorganic fiber paper, and the airgel paper is prepared by ethanol supercritical drying method. However, the strength of the inorganic fiber paper itself is very low, and it is easily damaged when unwinding and rewinding. Most of them exist in the form of cardboard, which is difficult to meet the rough Industrial construction requirements, no description of product qualification rate, thickness range 0.3mm-1.2mm
In addition, airgel paper cannot be applied to the field of clothing and accessories that have higher requirements for environmental protection of materials, and cannot be applied to the field of electronic products that have higher requirements for thickness, such as mobile phone heat insulation materials that require a thickness of 0.1mm
[0005] The thickness of conventional glass fiber needle felt airgel material is more than 3mm, and its flexibility is poor; the thickness of conventional inorganic fiber airgel material is more than 0.5mm, the optimal thickness is 0.3mm, and it is difficult to meet the rough industrial construction requirements, so it is prepared into a coil The pass rate is low and the flexibility is poor
It cannot be applied to the field of clothing and accessories that have higher requirements for environmental protection and flexibility of materials, and cannot be applied to the field of electronic products that have higher requirements for thickness

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Example 1: 1.5mm polyester non-woven ultra-thin aerogel material

[0030] Place a 100m long, 1.5m wide and 1.5mm thick polyester non-woven fabric in a roll form in a suitable container.

[0031] Take 50kg, 120kg, 20kg, 150g, 100g ethyl orthosilicate, ethanol, water, 2mol / L ammonia water, 0.2mol / L ammonium fluoride sulfuric acid solution and put them into a stainless steel mixing tank and mix them evenly. After stirring for 10-20 minutes , Pour the sol into a container placed in a roll of polyester non-woven fabric and fully immerse it. Seal and let stand for 24h, wait for gel. After gelation, unwind and rewind the whole wet gel into absolute ethanol for 36h aging, after aging, transfer the wet gel into a mixed modification solution containing 30L hexamethyldisilazane and 300L absolute ethanol , Modified for 24h. After the modification, the wet gel is taken out and dried by supercritical fluid to obtain a silica aerogel and polyester non-woven fabric composite material.

[...

Embodiment 2

[0033] Example 2: 0.1mm polyester non-woven fabric ultra-thin aerogel material

[0034] Place a 100m long, 0.5m wide, and 0.1mm thick polyester non-woven fabric in a roll form in a suitable container.

[0035] Take 2.5kg, 6kg, 0.8kg, 10g, 5g of ethyl orthosilicate, ethanol, water, 2mol / L ammonia water, 0.2mol / L ammonium fluoride sulfuric acid solution, respectively, into a stainless steel mixing tank and mix well, and stir for 10-20 Minutes later, pour the sol into a container placed in a roll of polyester non-woven fabric and fully impregnate it. Seal and let stand for 24h, wait for gel. After gelation, put the whole wet gel in absolute ethanol to age for 36h. After aging, transfer the wet gel into a mixed modification solution containing 0.5L of hexamethyldisilazane and 5L of absolute ethanol. 24h. After the modification, the wet gel is taken out, dried by supercritical fluid and then unwinded and rewinded to obtain a silica aerogel and polyester non-woven fabric composite mat...

Embodiment 3

[0037] Example 3: 0.2mm glass fiber surface felt ultra-thin aerogel material

[0038] Cut 100 pieces of 30cm long, 20cm wide, and 0.2mm thick glass fiber surface mat, stack them neatly in a suitable container, take ethyl orthosilicate, ethanol, water, 2mol / L ammonia, 0.2mol / L 2.5kg, 6kg, 0.8kg, 10g, and 5g of ammonium fluoride sulfuric acid solution were added into a stainless steel stirring tank and mixed uniformly. After stirring for 10-20 minutes, the sol was poured into a container on which glass fiber surface felt was placed and fully immersed. Seal and let stand for 24h, wait for gel. After aging, transfer the wet gel into a mixed modification solution containing 1L of dimethyldiethoxysilane, 10L of absolute ethanol and catalyst, and modify for 48h. After the modification, the wet gel is taken out, dried by supercritical fluid, and then unwound and rewinded to obtain a silica aerogel and glass fiber surface mat composite material.

[0039] The prepared silica aerogel and gl...

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Abstract

The invention discloses an ultrathin aerogel composite material and a method for preparing the same. Organic cloth or inorganic fiber surface felt is used as reinforcement, composition is carried out on the reinforcement and silicon dioxide aerogel to obtain the ultrathin aerogel coiled material or sheet, the organic heat conduction coefficient is lower than or equal to 0.018 w / mk, hydrophobic angles are larger than 150 degrees, the thickness of the ultrathin aerogel composite material with the organic cloth is 0.05-2 mm, and the thickness of the ultrathin aerogel composite material with the inorganic fiber surface felt is 0.1-1.5 mm. The ultrathin aerogel composite material and the method have the advantages that the ultrathin aerogel composite material prepared by the aid of the method is thin, the optimal thickness of the ultrathin aerogel composite material can reach 0.05 mm, the problems in the aspect of methods for preparing aerogel materials with the thicknesses lower than 0.3 mm and the qualification rates of products can be solved, the conventional thickness ranges of aerogel can be expanded, and the ultrathin aerogel composite material and the method can be applied to the field of electronic products with high requirements on thicknesses.

Description

Technical field [0001] The invention belongs to the field of aerogel materials, and particularly relates to an ultra-thin aerogel material prepared by using organic cloth and inorganic fiber surface felt as reinforcements. Background technique [0002] Aerogel super thermal insulation material is a new type of inorganic nano thermal insulation material, the main component is silica, and the nanometer-scale ultrafine particles aggregate each other to form a nanoporous network structure, and the network pores are filled with light weight of gaseous dispersion medium Nano solid materials. In terms of heat, the aerogel’s nanoporous structure can effectively inhibit solid heat conduction and gas heat transfer, and has excellent thermal insulation properties. It is currently recognized as the solid material with the lowest thermal conductivity (as low as 0.013W / (m·K at room temperature) )). [0003] The unique structure of aerogel gives it excellent thermal insulation performance, but ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B30/02C04B38/00D06M11/79D06M13/513C04B14/06C04B14/42C04B111/27D06M101/32
CPCC04B30/02C04B2111/27C04B2201/20C04B2201/32D06M11/79D06M13/513D06M2101/32C04B14/064C04B14/42C04B24/42C04B38/0045C04B38/0054C04B38/0074C04B38/0067
Inventor 吴锦源刘天时崔恒律许斌殷龙盘秦德勇刘斌
Owner 航天海鹰(镇江)特种材料有限公司
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