A method for synthesizing microporous conductive polymer material with nanoreactor

Abstract

The present invention relates to a method for synthesizing a microporous conductive polymer material with a nanoreactor. The method for synthesizing a microporous conductive polymer material with a nanoreactor first synthesizes an organic-inorganic hybrid nanoreactor; and utilizes Scanning electron microscopy is used to characterize its microscopic appearance, and its structure is also characterized by X-ray diffractometer; secondly, the present invention uses the nanoreactor as a template, and synthesizes a nanoreactor with a regular pore structure by an electrochemical method inside it. Polythiophene with a three-dimensional structure has reversible redox cyclic voltammetry properties and a conductivity of 0.1S / cm. It is a microporous conductive polymer material. The invention first uses the nano-reactor as a template to synthesize the conductive macromolecular material with the microporous structure, thereby obtaining the novel polythiophene with the microporous structure.

Description

technical field [0001] The invention relates to the technical field of synthesizing conductive polymer materials with a microporous structure, in particular to a method for synthesizing microporous conductive polymer materials with a nano-reactor. Background technique [0002] In the past few years, research groups around the world have consciously increased their efforts to design and develop new materials to prepare porous organic frameworks (POFs) with specific functions in the size range from a few nanometers to hundreds of nanometers, including covalent organic frameworks. (COFs), metal-organic frameworks (MOFs) and microporous conjugated polymers (CMPs). Recently, porous organic frameworks with unique electronic and optoelectronic properties have aroused great interest among scientists. Due to the great potential of organic-based conductive porous materials in photovoltaic applications, more and more efforts have been devoted to the research of such materials. Such m...

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Problems solved by technology

Two-dimensional (2D) porous polymers based on conjugated organic ligands have also been synthesized, such as electroactive organic frameworks (EOFs), CMPs, and COFs. induced electrical properties, but its conductivity is very low, which may come from inefficient stacking of p-systems

MOFs membrane materials have been widely studied as a new class of functional materials with wide applications in gas storage, gas separation, carbon capture, catalysis, sensing, etc. However, summarizing all the literature on the use of MOFs materials we found that, Most of these literatures are reporting the application of MOFs materials in gas-liquid separation, gas adsorption and storage, and optics, but there are still very few electrochemical applications.

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