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High-performance rubber cracking preventing agent

A technology of anti-cracking agent and anti-agent, which is applied in the field of anti-cracking agent, can solve the problems of high price, low service life, lack of rubber protection mechanism and in-depth research on the root of precipitation, etc., and achieves low cost, long effective effect, and improved heat elastic effect

Inactive Publication Date: 2017-05-31
JIANGSU KAOU CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In the rubber industry, especially the tire industry, there were many misunderstandings in the selection of rubber crack preventers in the past, and ordinary paraffin was generally used instead, which has little effect on improving product quality, preventing crack aging, and prolonging the service life of rubber products. Manufacturers of rubber cracking preventive agents mainly include British Astor Company, German Tehal Company, Rhine Company, etc., with a production scale of more than 10,000 tons and many varieties, but their prices are relatively expensive. At present, China Petrochemical Co., Ltd. The company's Fushun Petrochemical Research Institute and Jingmen Branch have successfully developed rubber cracking preventive agents, with a total production of about 3.5kt / a. However, compared with foreign products, my country's rubber cracking preventive agents mainly focus on rubber Developed on the basis of paraffin, there is a lack of in-depth research on the protective mechanism of rubber and the origin of precipitation. No matter in terms of variety or quality, it needs to be further developed and improved. From the perspective of development trends, Asia will be the leader in radial tires in the next 5 to 10 years. Hot production areas, my country's auto tire radialization will enter a period of rapid growth

Method used

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] This embodiment provides a high-efficiency rubber cracking inhibitor, which includes the following components in parts by weight: No. 58 fully refined paraffin wax: 20 parts, No. 58 semi-refined paraffin wax: 15 parts, and No. 70 microcrystalline wax: 22 parts, No. 85 microcrystalline wax: 18 parts, oxidized polyethylene wax: 4 parts, polyethylene wax: 2 parts.

[0044] The preparation process of this preventive agent is specifically carried out according to the following steps:

[0045] Step (1): put No. 85 microcrystalline wax into the reactor, heat and stir;

[0046] Step (2): when the temperature of the material in the reaction kettle rises to 90°C in step (1), put in No. 70 microcrystalline wax, keep stirring for 5min;

[0047] Step (3): heating up, when the temperature of the material in the reaction kettle reaches 110 ° C, put in all the oxidized polyethylene wax and polyethylene wax, then keep the temperature at 110 ° C and stir for 20 min to obtain a modified ...

Embodiment 2

[0053] This embodiment provides a high-efficiency rubber cracking inhibitor, which includes the following components in parts by weight: No. 58 fully refined paraffin wax: 30 parts, No. 58 semi-refined paraffin wax: 25 parts, and No. 70 microcrystalline wax: 34 parts, microcrystalline wax No. 85: 30 parts, oxidized polyethylene wax: 8 parts, polyethylene wax: 5 parts.

[0054] The preparation process of this preventive agent is specifically carried out according to the following steps:

[0055] Step (1): put No. 85 microcrystalline wax into the reactor, heat and stir;

[0056] Step (2): when the temperature of the material in the reaction kettle rises to 100°C in step (1), put in No. 70 microcrystalline wax, keep stirring for 5-8min;

[0057] Step (3): heating up, when the temperature of the material in the reaction kettle reaches 110 ° C, put all the oxidized polyethylene wax and polyethylene wax into it, then keep the temperature at 120 ° C and stir for 30 min to obtain a m...

Embodiment 3

[0063] This embodiment provides a high-efficiency rubber crack preventing agent, which includes the following components in parts by weight: No. 58 fully refined paraffin wax: 25 parts, No. 58 semi-refined paraffin wax: 19 parts, and No. 70 microcrystalline wax: 27 parts, No. 85 microcrystalline wax: 22 parts, oxidized polyethylene wax: 6 parts, polyethylene wax: 4 parts.

[0064] The preparation process of this preventive agent is specifically carried out according to the following steps:

[0065] Step (1): put No. 85 microcrystalline wax into the reactor, heat and stir;

[0066] Step (2): when the temperature of the material in the reaction kettle rises to 95°C in step (1), put in No. 70 microcrystalline wax, keep stirring for 7min;

[0067] Step (3): heating up, when the temperature of the material in the reaction kettle reaches 110 ° C, put all the oxidized polyethylene wax and polyethylene wax into it, then keep the temperature at 115 ° C and stir for 25 min to obtain a ...

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Abstract

The invention discloses a high-performance rubber cracking preventing agent. The preventing agent is prepared from the following components in parts by weight: 20 to 30 parts of Number-58 completely-refined paraffin, 15 to 25 parts of number-58 semi-refined paraffin; 22 to 34 parts of number-70 microcrystalline wax, 18 to 30 parts of number-85 microcrystalline wax, 4 to 8 parts of oxidized polyethylene wax, and 2 to 5 parts of polyethylene wax. The preventing agent is smooth in surface, uniform in thickness, good in leakproofness, compact in structure, high in flexibility, heat resistance, elasticity and adhesive force, uneasy to drop, capable of playing a barrier role in preventing rubber from contacting ozone gas, and capable of effectively delaying the oxidization effect, delaying the cracking and prolonging the service life.

Description

technical field [0001] The invention relates to a preventive agent, in particular to a high-efficiency rubber crack preventive agent. Background technique [0002] Rubber cracking, which is an aging phenomenon of rubber, refers to the gradual deterioration of the performance of polymer materials (including rubber, plastics, fibers, etc.) during processing, storage and use due to the combined effect of internal and external factors. , so that a large number of slight fine lines appear on the surface and inside, which will eventually lead to the loss of use value of the product. The cracking of rubber is a common problem of rubber products, mainly due to the weak points on the surface and interior of the structure or components that are easy to cause cracking, such as It has unsaturated double bonds, branched chains, carbonyl groups, hydroxyl groups at the ends, etc., and external or environmental factors are mainly sunlight, oxygen, ozone, heat, water, mechanical stress, high...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L91/06C08L23/30C08L23/06C08L51/08C08L83/04C08L71/02C08L1/28C08L75/04C08L29/04C08L33/26C08K5/18C08K5/12C08K3/34C08L21/00
CPCC08L91/06C08L21/00C08L2201/08C08L2205/025C08L2205/035C08L23/30C08L23/06C08L51/08C08L83/04C08L71/02C08L1/284C08L75/04C08L29/04C08L33/26C08K5/18C08K5/12C08K3/346
Inventor 高小刚徐立飞
Owner JIANGSU KAOU CHEM
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