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Photovoltaic packaging adhesive film

An encapsulation film and photovoltaic technology, applied in photovoltaic power generation, adhesives, grafted polymer adhesives, etc., can solve the problems of affecting the reflection performance, reducing the wettability of inorganic materials, and rough contact surfaces, so as to ensure safety. and reliability, excellent bonding properties, good anti-aging properties

Active Publication Date: 2017-02-01
乐凯胶片股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technology of high-reflective packaging film is mainly to add a certain proportion of reflective pigments to the transparent packaging film, so that the reflectivity can reach more than 70%, but there are still lamination appearance problems in practical applications, such as, When the module is laminated, the adhesive film foams to make the surface rough and wrinkled, which will greatly affect its reflection performance, and a small amount of overflow of the lower adhesive film will block the edge of the cell, resulting in power loss of the module
[0006] Patent document CN102361043A discloses a high-reflection EVA packaging adhesive film and its preparation method. The specific measure is to add titanium dioxide powder to the EVA adhesive film. Both belong to EVA, the polarity is not much different, and it is easy to cross and fuse during the lamination process, resulting in rough contact surface, wrinkles, poor reflection effect, and even the high reflection filler in the lower film overflows and blocks and contaminates the cell. , The condition of the welding strip seriously affects the appearance of the component and causes the power loss of the component
Patent document CN104497899 A discloses a high-reflection encapsulation film with pre-crosslinked surface. The specific measure is to add a photoinitiator to the encapsulation film, extrude the film and irradiate the surface to pre-crosslink the surface. 0.05mm~0.1mm, the crosslinking degree of the pre-crosslinked layer is greater than 75%, so as to improve the reflectivity and solve the apparent problems such as overflow of the packaging film. Wrinkles appear, and the high degree of cross-linking on the surface of the adhesive film will lead to a decrease in wettability to inorganic materials and a significant decrease in adhesion, which poses a safety hazard when used in double-glass modules

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] 1.2g of anti-aging agent (containing 0.3g of 2,2'-dihydroxy-4-methoxybenzophenone as a UV absorber, 0.5g of Lowilite-62 and Lowilite-94 with a weight ratio of 1:1 Mixture as light stabilizer, 0.4g tetrakis [methyl-β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester as antioxidant) and 5g zinc sulfide reflective pigment, 20g ethylene-octene random copolymer (ENGAGE 8130 of Dow Chemical, Tg-59°C) was mixed to obtain white masterbatch after granulation and drying by twin-screw extruder, then white masterbatch, 10g low Density polyethylene (COSMOTHENE F410-1 of Singapore polyolefin, melting peak temperature 111 ℃), 30g silane grafted ethylene-octene copolymer H-1 (laboratory preparation, grafting rate 1.8%, at 190 ℃, 2.16kg The melt index under test conditions is 3.3g / 10min), 70g silane grafted ethylene-propylene copolymer H-2 (laboratory preparation, grafting rate 1.6%, the melt index under 190 ℃, 2.16kg test conditions is 1.2 g / 10min, melting peak tem...

Embodiment 2

[0066] 0.05g of anti-aging agent (containing 0.01g of 2,2'-dihydroxy-4-methoxybenzophenone as a UV absorber, 0.02g of Lowilite-62 and Lowilite-94 with a weight ratio of 1:1 The mixture is used as light stabilizer, 0.02g tetrakis [methyl-β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester as antioxidant) and 12g zinc oxide reflective pigment, 5g of ethylene butene copolymer (ENR 7447 of Dow Chemical, Tg-57°C) was mixed and then granulated and dried by twin-screw extruder to obtain white masterbatch, then white masterbatch, 5g low density polyethylene (Taiju's LINATHENE LL110, the melting peak temperature is 122°C, and the melt flow rate measured under the condition of 190°C 2.16kg is 1g / 10min), 50g of silane grafted ethylene-octene copolymer H-1 (prepared in the laboratory, Grafting rate 1.0%, the melt index under 190 ℃, 2.16KG test conditions is 7.0g / 10min), 50g silane grafted 4-methyl-1-pentene homopolymer H-2 (prepared in laboratory, grafted branch rate ...

Embodiment 3

[0068] 2.0g of anti-aging agent (containing 0.3g of 2,2'-dihydroxy-4-methoxybenzophenone as a UV absorber, 1.0g of Lowilite-62 and Lowilite-94 with a weight ratio of 1:1 The mixture is used as a light stabilizer, 0.7 g of tetrakis [methyl-β- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester as an antioxidant) and 8 g of boron nitride reflective pigment , 30g of propylene ethylene copolymer (VERSIFY 3401 of Dow Chemical, glass transition temperature -32°C) was mixed and granulated and dried by a twin-screw extruder to obtain a white masterbatch, and then the white masterbatch, 10g of linear low-density polymer Ethylene (UNITENE LH503 from Taiju, melting peak temperature 130°C), 40g of silane-grafted ethylene-1-pentene copolymer H-1 (prepared in the laboratory, grafting rate 2.0%, under the test conditions of 190°C and 2.16kg The melt index is 2.2g / 10min), 70g silane grafted low-density polyethylene H-2 (prepared in the laboratory, grafting rate 1.6%, the me...

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Abstract

The invention provides a photovoltaic packaging adhesive film. The packaging adhesive film has a uniform crosslinking degree which is 5-30%. The packaging adhesive film comprises, by mass, 80-120 parts of silane grafted olefin polymer, 10-50 parts of olefin polymer, 2-15 parts of reflective pigment and 0.05-2 parts of anti-ageing agent, wherein the silane grafting rate of the silane grafted olefin polymer is 0.5-3%. The adhesive film guarantees lamination performance of an assembly and is higher in assembly yield compared with the prior art. The reflectivity of the adhesive film is improved, the anti-ageing performance is better, safety and reliability of the photovoltaic assembly are ensured, bubbles and other defects in the assembly lamination process can be reduced or avoided, and the assembly yield is further increased.

Description

technical field [0001] The invention relates to the technical field of photovoltaic cells, in particular to a technology for packaging photovoltaic modules. Background technique [0002] With the development of photovoltaic modules to the present, an increase in power generation efficiency of 1% or even less is a major technological advancement. However, the improvement of power generation efficiency is not limited to the cells themselves. Packaging materials, as an important part of photovoltaic modules, also contribute to the improvement of power generation efficiency, which is worth digging into. [0003] In order to improve the power generation efficiency of photovoltaic modules, the back packaging surface of photovoltaic modules should have a high reflectivity. When the sunlight irradiated into the cell gap reaches the surface of the cell through multiple reflections between the back packaging material and the glass, it is conducive to the full use of sunlight. . Some...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J151/06C09J123/08C09J123/06C09J11/06C09J11/04H01L31/048
CPCY02E10/50C09J151/06C08K2201/019C08L2201/08C08L2203/206C08L2205/02C08L2205/025C08L2205/035C08L2207/066C09J11/04C09J11/06H01L31/0481C08L51/06C08L23/0815C08L23/06C08K13/02C08K5/1345
Inventor 樊仔欣范云峰徐晓龙孟丹白玉清
Owner 乐凯胶片股份有限公司
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