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Improved biodegradable shopping bag and preparation method thereof

A biodegradable and shopping bag technology is applied in the field of improved biodegradable shopping bags and their preparation, which can solve the problems of many consumables, inconvenience in large-scale production and processing, uneven degradation of degradable shopping bags, etc., so as to improve the urban landscape environment, comprehensively Low cost of use, uniform and complete degradation

Active Publication Date: 2017-01-18
新疆康润洁环保科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The currently developed aromatic polyesters such as polyethylene terephthalate (PET), polybutylene terephthalate (PBT), polytrimethylene terephthalate (PTT), etc. Strong water resistance, resistant to bacterial erosion, etc., cannot be biodegraded under natural conditions
Aliphatic polyesters such as poly 3-hydroxyalkanoate (PHA), polybutylene succinate (PBS), etc., such aliphatic polyesters are known for their good biocompatibility, biodegradability, etc. Its characteristics are attracting more and more attention, and it is applied in the fields of biomedical materials and injection molding products, but there are also some shortcomings in the process of practical application: such as relatively expensive price, too fast biodegradation rate, poor thermal stability, relatively poor mechanical properties, Easy hydrolysis, easy aging, high impurity content and other shortcomings, which limit the application of this type of polyester material in some fields
[0008] 1. The manufactured masterbatch cannot be restructured with polyethylene resin, but only physically mixed and filled. It is a form of encapsulation and cannot form a network bridging structure with a 'knot' effect, resulting in uneven degradation of the degraded shopping bag. , Incomplete, forming residual fragments or powder, causing secondary pollution to the land;
[0009] 2. Due to the low crystallinity, low branching degree, and large and uneven particle size of the produced masterbatch, the blown shopping bags are thicker, more consumables, and higher cost, which is not convenient for large-scale production and processing
It adopts the preparation method of adding fillers and silane modifiers simultaneously, but we have found through experiments that this method has a certain effect on the improvement of mechanical properties, but there is still room for improvement
It has also been reported that two kinds of silane modifiers are used to improve the filler, but this improvement in the performance of the final product is also limited

Method used

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  • Improved biodegradable shopping bag and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Mix 5Kg polylactic acid, 4.4Kg PBS, 0.03Kg antioxidant 1010, 0.5Kg modified filler, 0.05Kg UV-326, 0.02Kg lubricant EBS in a high mixer, and then blow the film Blowing is carried out in the machine to obtain biodegradable shopping bags.

[0042] The preparation method of modified filler is as follows:

[0043] (1) Calcium carbonate is dispersed in deionized water, and stirred evenly under ultrasonic;

[0044] (2) Mix ammonia water, silane modifier, absolute ethanol, and deionized water according to a certain volume ratio, stir evenly at room temperature to obtain a mixed solution, heat the mixed solution to 100°C and keep it for 5-8 hours before drying Cool, add absolute ethanol, disperse evenly after ultrasonication, and cool to -5°C for storage to obtain a sol solution for use in the next step;

[0045] (3) Mix the dispersion obtained in step (1) and the sol solution obtained in step (2) according to a certain volume ratio, and stir evenly at room temperature to obt...

Embodiment 2

[0052] The molar ratio of ethyl orthosilicate, APTMS, and vinyl siloxane is 1:2:3, and the others are the same as in Example 1. As a result, it was found that the biodegradability was basically the same as that of Example 1, the nominal load was 9.0Kg, and the sealing strength was 15.5N / 15mm.

Embodiment 3

[0054] The molar ratio of ethyl orthosilicate, APTMS, and vinyl siloxane is 1:2:2, and the others are the same as in Example 1. As a result, it was found that the biodegradability was basically the same as that of Example 1, the nominal load was 8.8Kg, and the sealing strength was 15.6N / 15mm.

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Abstract

The invention relates to an improved biodegradable shopping bag which comprises polylactic acid serving as a main component, one or more of PBAT (poly-butyleneadipate-co-terephthalate) or PBS (poly-butylene succinate) or polyhydroxyalkanoate serving as another main component, and a modified inorganic filler serving as a secondary component. The shopping bag prepared by the method provided by the invention eliminates white pollution and improves urban ecological environment.

Description

technical field [0001] The invention relates to an improved biodegradable shopping bag and a preparation method thereof. Background technique [0002] Shopping bags provide great convenience to people in daily life, and are essential items for people to go shopping. The shopping bags currently available on the market mainly include: plastic shopping bags, non-woven shopping bags, paper shopping bags, cotton and linen shopping bags, etc. Plastic shopping bags include ordinary plastic shopping bags, starch-based plastic shopping bags and degradable plastic shopping bags. Among them, ordinary plastic shopping bags are difficult to degrade. Starch-based plastic shopping bags rely on food, so the prospects are not good. The country has been widely promoted, but its high cost makes it difficult to promote it on a large scale in the country in a short period of time. Non-woven shopping bags are non-woven fabrics made of plastics such as polypropylene or polyethylene terephthalate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L67/02C08K13/06C08K9/06C08K3/26C08K5/134C08K5/3475
CPCC08J5/18C08J2367/04C08J2467/02C08K2201/003C08K2201/014C08L67/04C08L2201/06C08L2203/16C08L2205/02C08L67/02C08K13/06C08K9/06C08K2003/265C08K5/1345C08K5/3475
Inventor 孔立明
Owner 新疆康润洁环保科技股份有限公司
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