Adhesive agent and adhesive sheet
An adhesive, adhesive sheet technology, applied in the direction of adhesive, adhesive type, ester copolymer adhesive, etc., can solve the problems of corrosion of transparent conductive film, change of resistance value of transparent conductive film, influence on pattern visualization, etc., to achieve step difference Excellent followability and anti-corrosion effect
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[0078] (5) Preparation of adhesive composition
[0079] Prepare (meth)acrylate copolymer (A), and add crosslinking agent (B) to obtained (meth)acrylate copolymer (A), and add silane coupling agent (C), additives if necessary , so that the adhesive composition P can be prepared.
[0080] The (meth)acrylate copolymer (A) can be produced by superposing|polymerizing the mixture of the monomeric unit which comprises a polymer by a normal radical polymerization method. The (meth)acrylate copolymer (A) can be superposed|polymerized by the solution polymerization method etc. using a polymerization initiator as needed. As a polymerization solvent, ethyl acetate, n-butyl acetate, isobutyl acetate, toluene, acetone, hexane, methyl ethyl ketone, etc. are mentioned, for example, and 2 or more types may be used together.
[0081] As a polymerization initiator, an azo compound, an organic peroxide, etc. are mentioned, and 2 or more types may be used together. As azo compounds, for example...
Embodiment 1
[0133] 1. Preparation of (meth)acrylate copolymer
[0134] Copolymerize 30 parts by mass of butyl acrylate, 30 parts by mass of 2-ethylhexyl acrylate, 20 parts by mass of methyl methacrylate and 20 parts by mass of 2-hydroxyethyl acrylate to prepare a (meth)acrylate copolymer (A). When the molecular weight of this (meth)acrylate copolymer (A) was measured by the method mentioned later, the weight average molecular weight (Mw) was 600,000.
[0135] 2. Preparation of Adhesive Composition
[0136] 100 parts by mass of the (meth)acrylate copolymer (A) obtained in the above step (1) (value in terms of solid content; the same applies hereinafter), trimethylolpropane-modified toluene as a crosslinking agent (B) 0.25 parts by mass of diisocyanate (manufactured by Soken Chemical & Engineering Co., Ltd., product name "L-45"), 3-glycidyl ether propyl trimethoxysilane (Shin-Etsu Chemical Co., Ltd. ., product name "KBM-403") 0.2 parts by mass were mixed and fully stirred, and diluted wi...
Embodiment 2~24
[0156] [Examples 2-24, Comparative Examples 1-4]
[0157] The type, ratio, and polymerization average molecular weight (Mw) of each monomer constituting the (meth)acrylate copolymer (A), the type and amount of the crosslinking agent (B), and the amount of the silane coupling agent (C) Except having changed the addition amount as shown in Table 1, it carried out similarly to Example 1, and produced the adhesive sheet. Moreover, about Examples 7-9, the benzyl benzoate (made by Tokyo Chemical Industry Co., Ltd.) was further added as a refractive index adjuster to an adhesive composition. The amount added is shown in Table 1.
[0158] Here, the said weight average molecular weight (Mw) is the polystyrene equivalent weight average molecular weight measured by gel permeation chromatography (GPC) under the following conditions (GPC measurement).
[0159]
[0160] - GPC measurement device: HLC-8020 manufactured by Tosoh Corporation
[0161] · GPC column (passed in the following o...
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