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Low-smoke halogen-free flame-retardant crack-resistant cable material and preparation method thereof

A technology of anti-cracking and cable materials, which is applied in the direction of insulating cables, cables, circuits, etc., can solve the problems of easy cracking of low-smoke, halogen-free flame-retardant cable sheaths, etc., to improve environmental stress cracking resistance, improve flame-retardant performance, The effect of excellent mechanical properties

Inactive Publication Date: 2016-08-31
卢永杰
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The research and production of low-smoke, halogen-free and flame-retardant cable materials in my country has a history of more than ten years. Although with the continuous improvement of the material technology, the extrusion process of low-smoke, halogen-free, and flame-retardant cable The speed and speed have been greatly improved, but the problem of easy cracking of low-smoke, halogen-free and flame-retardant cable sheaths that has been plaguing the industry has not been solved.

Method used

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  • Low-smoke halogen-free flame-retardant crack-resistant cable material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A low-smoke, halogen-free, flame-retardant and anti-cracking cable material, which is prepared from the following raw materials in parts by weight (kg): high-density polyethylene 65, ethylene-vinyl acetate copolymer 30, alkyl phenyl sulfonate 7, diethanolamine Borate 4, Magnesium Dimethacrylate 3, Magnesium Hydroxide 8, Cresyl Diphenyl Phosphate 40, 3-Aminopropyltriethoxysilane 4, Trimethylsilyl Cage Polysilsesquioxane Alkane 7, organic antimony stabilizer 6, p-phenylenediamine 5, nano colemanite 30, omega mineral fiber 8, hexachlorocyclotriphosphazene 8, carnauba wax 6, polyarylether ether nitrile 10, zirconium carbide 7. Hemp knife ash 5. Calcium hypophosphite 4. High wear-resistant carbon black 8.

[0016] A method for preparing a low-smoke, halogen-free, flame-retardant and anti-cracking cable material, comprising the following steps:

[0017] (1) Magnesium hydroxide, 3-aminopropyltriethoxysilane, trimethylsilyl clathrate polysilsesquioxane, organic antimony stabil...

Embodiment 2

[0021] A low-smoke, halogen-free, flame-retardant and anti-cracking cable material, which is prepared from the following raw materials in parts by weight (kg): high-density polyethylene 70, ethylene-vinyl acetate copolymer 35, alkyl phenyl sulfonate 8, diethanolamine Borate 5, Magnesium Dimethacrylate 4, Magnesium Hydroxide 9, Cresyl Diphenyl Phosphate 45, 3-Aminopropyltriethoxysilane 5.5, Trimethylsilyl Cage Polysilsesquioxane Alkane 8, organic antimony stabilizer 7, p-phenylenediamine 6, nano colemanite 35, Omega mineral fiber 9, hexachlorocyclotriphosphazene 9, carnauba wax 7, polyarylether ether nitrile 11, zirconium carbide 7.5, hemp knife ash 6.5, calcium hypophosphite 5, high wear-resistant carbon black 10.

[0022] The preparation method is the same as in Example 1.

Embodiment 3

[0024] A low-smoke, halogen-free, flame-retardant and anti-cracking cable material, which is prepared from the following raw materials in parts by weight (kg): high-density polyethylene 75, ethylene-vinyl acetate copolymer 40, alkyl sulfonate phenyl ester, diethanolamine boron Ester 6, Magnesium Dimethacrylate 5, Magnesium Hydroxide 10, Cresyl Diphenyl Phosphate 50, 3-Aminopropyltriethoxysilane 7, Trimethylsilyl Cage Polysilsesquioxane 9. Organic antimony stabilizer 8, p-phenylenediamine 7, nano colemanite 40, omega mineral fiber 10, hexachlorocyclotriphosphazene 10, carnauba wax, polyarylether ether nitrile 12, zirconium carbide 8, Hemp knife ash 8, calcium hypophosphite 6, high wear-resistant carbon black 12.

[0025] The preparation method is the same as in Example 1.

[0026] The performance detection result of the cable material that above-mentioned embodiment 1-3 makes is shown in the table below:

[0027]

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Abstract

The invention discloses a low-smoke halogen-free flame-retardant crack-resistant cable material and a preparation method thereof. The low-smoke halogen-free flame-retardant crack-resistant cable material is prepared from the following raw materials in parts by weight: 65-75 parts of high-density polyethylene, 30-40 parts of ethylene-vinyl acetate copolymer, 7-9 parts of phenyl alkyl sulfonate, 4-6 parts of diethanolamine borate, 3-5 parts of magnesium dimethyl acrylate, 8-10 parts of magnesium hydroxide, 40-50 parts of tolyl diphenyl phosphate, 4-7 parts of 3-aminopropyltriethoxy silane, 7-9 parts of trimethylsilane-base cage-type polysilsesquioxane, 6-8 parts of organic antimony stabilizer, 5-7 parts of p-phenylenediamine, 30-40 parts of nano colemanite, 8-10 parts of Ome mineral fiber, 8-10 parts of hexachlorocyclotriphosphonitrile, 6-8 parts of carnauba wax, 10-12 parts of polyarylether ether nitrile, 7-8 parts of zirconium carbide, 5-8 parts of fibrous plaster, 4-6 parts of calcium hypophosphite and 8-12 parts of high-wear-resistance carbon black. The cable material has the advantages of favorable flame-retardant effect, less fuming and favorable cracking resistance.

Description

technical field [0001] The invention relates to a cable material, in particular to a low-smoke, halogen-free, flame-retardant, crack-resistant cable material and a preparation method thereof. Background technique [0002] In recent years, with the vigorous development of my country's 4G network, urban rail transit, railways, building construction and other projects, the demand for radio frequency cables such as mobile communication radio frequency cables, leaky cables, and railway signal cables has risen sharply, prompting low-smoke and halogen-free resistance The use of fuel cables is growing rapidly. The research and production of low-smoke, halogen-free and flame-retardant cable materials in my country has a history of more than ten years. Although with the continuous improvement of the material technology, the extrusion process of low-smoke, halogen-free, and flame-retardant cable The speed and speed have been greatly improved, but the problem of easy cracking of low-smok...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L23/08C08L71/10C08L91/06C08K13/04C08K3/22C08K3/32C08K5/523C08K5/5399H01B7/295
CPCC08L23/06C08K2201/011C08L2201/02C08L2201/22C08L2203/202C08L2205/035C08L2207/062H01B7/295C08L23/0853C08L71/00C08L91/06C08K13/04C08K2003/2224C08K3/32C08K5/523C08K5/5399
Inventor 卢永杰
Owner 卢永杰
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