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Formula and preparation method of peelable photocuring glass coating

A glass coating and light-curing technology, applied in epoxy resin coatings, polyurea/polyurethane coatings, coatings, etc., can solve the problems of easy damage to processing tool heads, lack of energy saving and environmental protection, and very high requirements. Mechanical processing, good protection, good peeling performance

Active Publication Date: 2016-08-03
FOSHAN CITY GREEND CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Using the above method of protecting ink, although it can have a good protective effect on the surface of the glass, there are several obvious problems: (1) The lye cleaning steps are relatively cumbersome, and often need to include alkali cleaning, pickling neutralization, and clear water Washing, ultrasonic cleaning and other steps, often need to be heated during alkaline cleaning, which brings certain safety hazards and the problem that the waste liquid generated is difficult to handle, and lacks energy saving and environmental protection; (2) The alkaline cleaning step in the process The requirements are very high to prevent damage to the glass surface and other components of the product; (3) Alkali-soluble protective inks often have high hardness after film formation, which has an impact on subsequent mechanical processing and is easy to damage processing tools such as CNC cutter heads

Method used

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  • Formula and preparation method of peelable photocuring glass coating
  • Formula and preparation method of peelable photocuring glass coating

Examples

Experimental program
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Embodiment Construction

[0036] The content of the present invention is further described below by way of examples.

[0037] 1. Preparation of phosphorus-containing polyurethane acrylate

[0038] (1) The first step: Synthesis of polyurethane acrylic acid

[0039] Using a protective atmosphere of nitrogen, mix polypropylene glycol and isophorone diisocyanate at a molar ratio of 1:2.15, stir evenly and then heat up to 55°C, add dibutyltin dilaurate and hydroquinone at a mass ratio of 1:0.5 The mixture is used as a catalyst, and the amount of catalyst is small, just drop 15-20 drops with a dropper, then raise the temperature to 80°C, and react for 5 hours, until the content of isocyanate groups in the reaction system is reduced by 60%, add additional For hydroxyethyl acrylate with the same quality as polypropylene glycol, keep warm and continue to react for 2.5 hours.

[0040] (2) The second step: Synthesis of phosphorus-containing polyurethane acrylate

[0041] Under the protective atmosphere of nitr...

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PUM

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Abstract

The invention discloses a peelable photocuring glass coating in which phosphorus-containing urethane acrylate, epoxy acrylate and ethyl acetate are used together as main body resin, and active monomers, photoinitiator, filling agents and other additives are also added. When glass is coated with the peelable photocuring glass coating, not only is a good protection function achieved for the glass, but also a good peeling property is achieved. Meanwhile, a preparation method and a use method of the coating are both energy-saving and environment-friendly, the cost of a procedure of glass surface protection can be effectively lowered, a soft film can be formed, and the machining process is not affected.

Description

technical field [0001] The invention relates to a light-curing glass coating, in particular to a formula of a strippable and easy-peeling light-curing glass coating, a preparation method and a use method thereof. Background technique [0002] In high-end consumer products such as 3C products and decorations, glass parts are often used as display screens and exterior decorations, and are a very important part of product appearance. However, in the process of deep processing of finished products, glass products are very easy to be scratched, resulting in a low yield rate of finished glass products and increased costs. At present, in many glass processing processes, a layer of protective ink is coated on the surface of the glass before mechanical processing. Ink removal, restore the appearance of glass, such as the alkali-washable UV paint provided in the patent named "A kind of alkali-washable UV paint for mobile phone glass bottles and its preparation method" with applicatio...

Claims

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Application Information

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IPC IPC(8): C09D175/14C09D163/10C09D5/20C09D7/12C08G18/83C08G18/75C08G18/67C08G18/48
CPCC08G18/4825C08G18/672C08G18/755C08G18/836C09D5/20C09D7/61C09D7/65C09D175/14C08L63/10C08K3/346C08K2003/2227
Inventor 区锦泉
Owner FOSHAN CITY GREEND CHEM
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