Composition for glass, alumina borosilicate glass, preparation method of alumina borosilicate glass and applications of composition for glass and alumina borosilicate glass
A technology of aluminoborosilicate and composition, which is applied in semiconductor/solid-state device manufacturing, electrical components, circuits, etc., to achieve the effects of good tempering effect, high thermal expansion coefficient, and high strain point
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Embodiment 1-8
[0077] Weigh each component according to the glass composition shown in Table 1, mix well, pour the mixture into a platinum crucible, then heat in a resistance furnace at 1430°C for 4 hours, and stir with a platinum rod to remove air bubbles. Pour the molten glass into a stainless steel cast iron mold to form a specified block glass product, then anneal the glass product in an annealing furnace for 2 hours, turn off the power and cool down to 25°C with the furnace. Cut, grind and polish the glass products, clean the surface of the polished 80*80*1mm glass products with deionized water and put them into molten KNO at 440°C 3 Treat for 3 hours in middle temperature, then take it out and cool it down to 25°C, wash it with deionized water and dry it to obtain a finished glass product. Various properties of each glass product were measured respectively, and the results are shown in Table 1.
[0078] Table 1
[0079]
[0080]
Embodiment 9-12、 comparative example 1-3
[0082] According to the method of Example 1, the difference is that the composition of the mixture (corresponding to the glass composition) and the performance measurement results of the obtained product are shown in Table 2.
[0083] Table 2
[0084]
[0085]
[0086] By comparing the data of embodiment 9 and embodiment 12 in table 2, it can be seen that in weight percentage, 02 o 3 / (Al 2 o 3 + Ga 2 o 3 )<0.6, the thermal stability, chemical strengthening properties, impact resistance and toughness of the glass can be further improved.
[0087] By comparing the data in Table 1-2, it can be seen that the method of the present invention utilizes SiO containing specific content 2 , B 2 o 3 、Al 2 o 3 、Na 2 O, K 2 O, MgO, CaO, ZnO and RE 2 o 3 The glass prepared from the composition for glass has an elastic modulus higher than 80GPa and a density lower than 2.5g / cm 3 , the coefficient of thermal expansion in the range of 50-350°C is less than 90×10 -7 / °C, th...
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