Long-carbon-chain semi-aromatic polyamide and synthetic method thereof

A semi-aromatic and synthetic method technology, applied in the field of materials, can solve the problems of restricting the large-scale promotion of solid-phase polymerization, accelerating the discharge of by-product small molecules, and many solid-phase polymerization production processes, so as to achieve excellent processing performance, increase productivity, The effect of reducing the process

Active Publication Date: 2016-02-03
ZHONGBEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since solid-phase polymerization is generally carried out at 15-30°C below the melting point of the prepolymer, the reaction rate is slow and the reaction time is long, and the production process of solid-phase polymerization is complicated and the process is complicated. The requirements for equipment parameters are high, and the reaction is slow. It is necessary to ensure that the ratio of functional groups is close to 1:1, and the viscosity-increasing stage requires vacuum or air flow to accelerate the discharge of small molecules of by-products, thereby increasing the molecular weight of polycondensation products. Therefore, the above conditions limit the large-scale promotion of solid-phase polymerization

Method used

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  • Long-carbon-chain semi-aromatic polyamide and synthetic method thereof
  • Long-carbon-chain semi-aromatic polyamide and synthetic method thereof
  • Long-carbon-chain semi-aromatic polyamide and synthetic method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0080] The raw material composition and synthetic steps of the polyester amide used in the present embodiment are as follows:

[0081] (1) Vacuum-dried monomer 2: 1006.6g (5mol) 11-aminoundecanoic acid, 456.6g (4mol) 6-caprolactone, 270.3g (1.25mol) 2,2'-(1,3 -Phenylene)-bisoxazoline was added to the stirred polymerization reactor, and tetrabutyl titanate (17.3 g) of 1% of the total weight of monomer 2 was added as a catalyst, and 500 mL of water was added as a mass transfer and heat transfer Then vacuumize for 5 minutes, pass nitrogen for 5 minutes, and circulate like this for 6 times, so that the reactant exists in the environment under nitrogen protection, and the system pressure in the stirred polymerization reactor is controlled to be 0.2MPa;

[0082] (2) within 2.5 hours, heat the stirred polymerization reactor to 250°C at a uniform speed, and adjust the stirring speed of the stirred polymerization reactor to 40r / min, wherein, when the temperature of the stirred polymeri...

Embodiment 2

[0087] The raw material composition and synthesis steps of the polyester amide used in this example are the same as those in Example 1.

[0088] The synthetic method of a kind of long carbon chain semi-aromatic polyamide of the present embodiment comprises the following steps:

[0089] (1) Add monomer 1 after vacuum drying: 172.3g (1mol) decane diamine, 116.3g (0.7mol) terephthalic acid, 69.1g (0.3mol) dodecanedioic acid to the stirred polymerization reactor 8% (28.6g) of polyester amide, 8% (28.6g) of organic montmorillonite, 3% (10.7g) of benzoic acid, 0.3% (1.1g) of N ,N`-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,3-phthalamide, add 100mL water as the medium for mass transfer and heat transfer; then vacuumize for 5min, pass Nitrogen for 5 minutes, so circulated 6 times, so that the reactant exists in the environment under the protection of nitrogen, and the system pressure in the control stirred polymerization reactor is 0.2MPa;

[0090] (2) within 2 hours, heat the stirred...

Embodiment 3

[0092] The raw material composition and synthesis steps of the polyester amide used in this example are the same as those in Example 1.

[0093] The synthetic method of a kind of long carbon chain semi-aromatic polyamide of the present embodiment comprises the following steps:

[0094] (1) Add monomer 1 after vacuum drying: 172.3g (1mol) decane diamine, 149.5g (0.9mol) terephthalic acid, 23.0g (0.1mol) dodecanedioic acid to the stirred polymerization reactor 2% (6.9g) of polyesteramide, 0.5% (1.7g) of organic montmorillonite, 0.5% (1.7g) of benzoic acid, 0.2% (0.7g) of N ,N`-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,3-phthalamide, add 100mL water as the medium for mass transfer and heat transfer; then vacuumize for 5min, pass Nitrogen for 5 minutes, so circulated 6 times, so that the reactant exists in the environment under the protection of nitrogen, and the system pressure in the control stirred polymerization reactor is 0.3MPa;

[0095] (2) within 3.5 hours, heat the stirr...

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Abstract

The invention relates to long-carbon-chain semi-aromatic polyamide and a synthetic method thereof. Long-carbon-chain semi-aromatic polyamide has a structure in a formula I (as shown in the specification), wherein a is equal to 10-100, b is equal to 10-200, c is equal to 10-100, d is equal to 10-100, and R represents polyesteramide. Long-carbon-chain semi-aromatic polyamide has the characteristics of relatively high mechanical property and heat resistance, low water absorption rate, excellent processing performance and biogenetic derivation and can be applied to the fields of electronics, LEDs, automobiles, aerospace, war industry and the like.

Description

technical field [0001] The invention relates to the field of materials, in particular to a long carbon chain semi-aromatic polyamide and a synthesis method thereof. Background technique [0002] In recent years, in order to meet the higher performance requirements in the fields of electronics, electrical appliances, automobiles, etc., especially with the development of Surface Mount Technology (SMT), ordinary high-temperature-resistant engineering plastics polyphenylene sulfide (PPS) and The heat resistance of liquid crystal polymer (LCP) can no longer fully meet its requirements, so it is necessary to develop engineering plastics with higher heat resistance. [0003] Semi-aromatic polyamides are usually prepared by polycondensation of aliphatic diamines or diacids and diacids or diamines with aromatic rings. Due to the introduction of aromatic rings into the main chain of the polyamide molecule, its heat resistance And the mechanical properties have been improved, and the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G69/26C08G69/28C08G69/44
Inventor 胡国胜王忠强张静婷石哲平师文博方春晖刘冰肖许和伟
Owner ZHONGBEI UNIV
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