Antisludging agent for low-phosphorous reverse osmosis membrane and preparation method of antisludging agent
A technology of reverse osmosis membrane and scale inhibitor, applied in the field of low phosphorus reverse osmosis membrane scale inhibitor and its preparation, can solve the problems of poor scale inhibition stability, poor corrosion inhibition effect, poor temperature resistance, etc. Low dosage and long shelf life
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Embodiment 1
[0024] Add tolyltriazole and deionized water into a four-necked flask equipped with an electric stirrer, dropping funnel, thermometer and reflux condenser, heat to 30°C, stir for 20min, add dropwise 2-butane phosphonate- 1,2,4-tricarboxylic acid and polyepoxysuccinic acid were heated to 40°C and reacted for 1 hour.
[0025] Add ethylenediamine, benzotriazole, sodium polyacrylate and ferrous sulfate, raise the temperature to 70°C, react for 0.5h, raise the temperature to 100°C, add the remaining raw materials, and stir for 70min to obtain the low phosphorus reverse osmosis membrane scale inhibitor.
[0026] Used in a wide pH range of feed water, it can effectively control calcium carbonate, calcium sulfate, barium sulfate, silicon dioxide and other deposited scales, and the corrosion inhibition rate is 0.01mm / a; compared with conventional phosphorus-containing scale inhibitors and dispersants , reduce the hidden dangers of biological pollution and bacteria exceeding the standar...
Embodiment 2
[0029] Add tolyltriazole and deionized water into a four-necked flask equipped with an electric stirrer, dropping funnel, thermometer and reflux condenser, heat to 50°C, stir for 40min, and dropwise add 2-butane phosphonate- 1,2,4-Tricarboxylic acid and polyepoxysuccinic acid were heated to 60°C and reacted for 1.5 hours.
[0030] Add ethylenediamine, benzotriazole, sodium polyacrylate and ferrous sulfate, raise the temperature to 90°C, react for 1 hour, raise the temperature to 120°C, add the remaining raw materials, and stir for 90 minutes to obtain the low phosphorus reverse osmosis membrane scale inhibitor.
[0031] Used in a wide pH range of feed water, it can effectively control calcium carbonate, calcium sulfate, barium sulfate, silicon dioxide and other deposited scales, with a corrosion inhibition rate of 0.008mm / a; compared with conventional phosphorus-containing scale inhibitors and dispersants , reduce the hidden dangers of biological pollution and bacteria exceedi...
Embodiment 3
[0034] Add tolyltriazole and deionized water into a four-neck flask equipped with an electric stirrer, dropping funnel, thermometer and reflux condenser, heat to 30°C, stir for 20min, add 2-butane phosphonate- 1,2,4-tricarboxylic acid and polyepoxysuccinic acid were heated to 40°C and reacted for 1 hour.
[0035] Add ethylenediamine, benzotriazole, sodium polyacrylate and ferrous sulfate, raise the temperature to 70°C, react for 0.5h, raise the temperature to 100°C, add the remaining raw materials, and stir for 70min to obtain the low phosphorus reverse osmosis membrane scale inhibitor.
[0036] Used in a wide pH range of feed water, it can effectively control calcium carbonate, calcium sulfate, barium sulfate, silicon dioxide and other deposited scales, with a corrosion inhibition rate of 0.005mm / a; compared with conventional phosphorus-containing scale inhibitors and dispersants , reduce the hidden dangers of biological pollution and bacteria exceeding the standard in the me...
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