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Resistance reducing agent for fracture and preparation method thereof

A drag reducing agent and fracturing technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of low clay swelling inhibition, slow dissolution rate of drag reducing agent, and low storage stability, etc. High swelling inhibition, low formation damage, good water solubility

Active Publication Date: 2015-10-14
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to overcome the defects of slow dissolution rate, low drag reduction rate, low storage stability, low clay expansion inhibition, poor shear resistance and high formation damage in the above-mentioned prior art, and provide a Preparation method of drag reducing agent for fracturing, and a drag reducing agent for fracturing prepared by the method

Method used

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  • Resistance reducing agent for fracture and preparation method thereof
  • Resistance reducing agent for fracture and preparation method thereof
  • Resistance reducing agent for fracture and preparation method thereof

Examples

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preparation example Construction

[0029] In one aspect, the present invention provides a method for preparing a drag reducing agent for fracturing, the method comprising:

[0030] (1) Mix acrylamide monomer, double bond-containing hydroxyl nonionic monomer, polyhydroxy nonionic polymer template, chelating agent, molecular weight regulator and water to obtain an aqueous solution;

[0031] (2) Contact the organic solvent with the emulsifier to obtain an oil solution;

[0032] (3) contacting the aqueous solution obtained in step (1) with the oil solution obtained in step (2) to obtain a water-in-oil emulsion;

[0033] (4) Under an inert atmosphere, contact the water-in-oil emulsion obtained in step (3) with an initiator in batches, and carry out a polymerization reaction, and then contact the mixture obtained by the polymerization reaction with a phase inversion agent;

[0034] Wherein, the hydrophilic-lipophilic balance value of the emulsifier is 4-6, the molecular weight of the polyhydroxy nonionic polymer tem...

Embodiment 1

[0071] This example is used to illustrate the drag reducing agent for fracturing of the present invention and its preparation method.

[0072] (1) At 15°C, mix 100g of acrylamide, 35g of 2-hydroxyethyl methacrylate, 2g of polyvinyl alcohol (type: 10-98, the molecular weight is 61,000), 0.1g disodium edetate, 0.05g sodium formate and 120g deionized water are mixed in a 1000mL beaker, stirred until completely dissolved to obtain an aqueous solution;

[0073] (2) Mix 10.5g Span-80 and 1.5g Tween-80 to obtain a mixed emulsifier, and calculate the hydrophilic-lipophilic balance value of the mixed emulsifier to be 5, then mix the mixed emulsifier with 120g white oil (boiling point distillation range 220-255°C, flash point 80°C) mixed in a 1500mL beaker until completely dissolved to obtain an oil solution;

[0074] (3) Add the aqueous solution obtained in step (1) to the oil solution obtained in step (2), and emulsify with a high-speed shear dispersing emulsifier for 1 min to obtai...

Embodiment 2

[0077] This example is used to illustrate the drag reducing agent for fracturing of the present invention and its preparation method.

[0078] (1) At 25°C, mix 100g of acrylamide, 30g of 2-hydroxyethyl methacrylate, and 5g of polyvinyl alcohol (type: 40-88, the molecular weight is 205,000), 0.2g disodium edetate, 0.1g sodium formate and 150g deionized water are mixed in a 1000mL beaker, stirred until completely dissolved to obtain an aqueous solution;

[0079] (2) Mix 10.5g Span-80 and 4.5g Tween-80 to obtain a mixed emulsifier, and calculate the hydrophilic-lipophilic balance value of the mixed emulsifier to be 6, then mix the mixed emulsifier with 150g white oil (boiling point distillation range 240-280°C, flash point 100°C) mixed in a 1500mL beaker until completely dissolved to obtain an oil solution;

[0080] (3) Add the aqueous solution obtained in step (1) to the oil solution obtained in step (2), and emulsify with a high-speed shear dispersing emulsifier for 1 min to ...

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Abstract

The invention relates to a preparation method of a resistance reducing agent for fracture. The preparation method includes the steps of: (1) mixing an acrylamide monomer, a nonionic-series monomer having a hydroxyl group and containing a double bond, a polyhydroxyl nonionic polymer template, a chelating agent and a molecular weight regulating agent with water to obtain a water solution; (2) contacting an organic solvent with an emulsification agent to obtain an oil solution; (3) contacting the water solution with the oil solution to obtain a water-in-oil emulsion; and (4) under an inert atmosphere, contacting the water-in-oil emulsion with an initiator in batches, performing a polymerization reaction to obtain a mixture, and contacting the mixture with a phase conversion agent. The emulsification agent is 4-6 in hydrophilic-lipophilic balance value, the molecular weight of the polyhydroxyl nonionic polymer template is less than 500000, and the structure formula of the polyhydroxyl nonionic polymer template is represented as the formula (I) or the formula (II). The invention also relates to the resistance reducing agent for fracture prepared through the method. The resistance reducing agent for fracture is high in resistance reducing rate, is high in inhibition on clay expansion, is good in water solubility and is low in formation damage property.

Description

technical field [0001] The invention relates to a drag reducing agent for fracturing and a preparation method of the drag reducing agent for fracturing. Background technique [0002] Shale gas reservoirs are characterized by low porosity and low permeability, and are difficult to exploit. At present, the slick water fracturing process is mainly used for exploitation. The fracturing fluid is pressurized by the high-pressure pump injection equipment, and then pumped into the formation at high speed through the pipe string , under high pressure and high speed conditions, the turbulence phenomenon is serious during the flow of fluid in the pipe, and there is a large frictional resistance between the fracturing fluid and the pipe wall. Energy loss increases. Therefore, it is necessary to add a drag reducing agent to the fluid to reduce the influence of frictional resistance and improve construction efficiency. [0003] The drag reducing agent is to add a small amount of high mo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/56C08F220/28C08F220/58C08F2/30C09K8/68
Inventor 张文龙刘希方昭林蔚然祝纶宇
Owner CHINA PETROLEUM & CHEM CORP
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