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A kind of drag reducing agent for fracturing and preparation method thereof

A drag-reducing agent and fracturing technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of low clay expansion inhibition, low drag-reducing rate of drag-reducing agent, poor shear resistance, etc. To achieve the effects of clay expansion inhibition, improved drag reduction performance, non-combustible and explosive effects

Active Publication Date: 2017-04-26
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The purpose of the present invention is to overcome the defects of low drag reduction rate, low storage stability, low clay expansion inhibition, poor shear resistance and high formation damage of the drag reducer in the prior art, and to provide a drag reducer for fracturing. Preparation method of resistance agent, and a drag reducing agent for fracturing prepared by the method

Method used

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  • A kind of drag reducing agent for fracturing and preparation method thereof
  • A kind of drag reducing agent for fracturing and preparation method thereof
  • A kind of drag reducing agent for fracturing and preparation method thereof

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preparation example Construction

[0031] In one aspect, the present invention provides a method for preparing a drag reducing agent for fracturing, the method comprising:

[0032] (1) mixing acrylamide-based monomers, double bond-containing anionic monomers, cationic polymer templates, dispersants, molecular weight regulators, inorganic salts and water and adjusting the pH value to obtain an aqueous solution with a pH value of 4-7;

[0033] (2) Under an inert atmosphere, the aqueous solution obtained in step (1) is contacted in batches with an initiator, and a polymerization reaction is carried out;

[0034] Wherein, the molecular weight of the cationic polymer template is less than 1 million, and the structural formula of the cationic polymer template is as shown in formula (I):

[0035]

[0036] R 1 is hydrogen or methyl;

[0037] A is O or NH;

[0038] R 2 is C 1 -C 6 the alkylene group;

[0039] R 3 , R 4 , R 5 is C 1 -C 6 the alkyl group;

[0040] Z is chlorine, bromine or iodine.

[0041...

Embodiment 1

[0065] This example is used to illustrate the drag reducing agent for fracturing of the present invention and its preparation method.

[0066] (1) At 15°C, add 523.3g of deionized water to a 1000mL polymerization reactor equipped with a condenser, thermometer, nitrogen inlet and agitator, then add 250g of ammonium sulfate to the polymerization reactor, and stir until completely dissolved Then, add 4.0g polymethacryloxyethyltrimethylammonium chloride (molecular weight: 200,000) to the polymerization reactor, stir until completely dissolved, then add 100g acrylamide, 30g sodium acrylate, After 8 g of sodium polyacrylate (molecular weight is 500,000), 0.5 g of sodium formate, stir until completely dissolved, and finally slowly add 1% by weight of NaOH aqueous solution to the solution obtained above, adjust the pH to 5, and obtain an aqueous solution with a pH of 5;

[0067] (2) under the condition of 16 DEG C, first add the ammonium persulfate aqueous solution of 10g 2% by weight...

Embodiment 2

[0069] This example is used to illustrate the drag reducing agent for fracturing of the present invention and its preparation method.

[0070] (1) At 20°C, add 536.9g of deionized water to a 1000mL polymerization reactor equipped with a condenser, thermometer, nitrogen inlet and agitator, then add 297g of ammonium sulfate to the polymerization reactor, and stir until completely dissolved , then add 5.0g polymethacryloxyethyltrimethylammonium chloride (molecular weight is 10,000) to the polymerization reactor, stir until completely dissolved, then add 100g acrylamide, 30g sodium acrylate, 5g 2 - After sodium acrylamido-2-methylpropanesulfonate and 0.1 g of sodium formate, stir until completely dissolved, and finally slowly add 1% by weight of NaOH aqueous solution to the solution obtained above, adjust the pH to 7, and obtain a solution with a pH of 7. aqueous solution;

[0071] (2) under the condition of 21 DEG C, first add the ammonium persulfate aqueous solution of 5g 2% by...

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Abstract

The invention relates to a preparation method of a resistance reducing agent for fracture. The preparation method includes the steps of: (1) mixing an acrylamide-series monomer, an anionic monomer containing a double bond, a cationic polymer template, a dispersing agent, a molecular weight regulating agent and inorganic salts with water with pH value being regulated to obtain a water solution of which the pH value is 4-7; and (2) under an inert atmosphere, contacting the water solution with an initiator in batches and performing a polymerization reaction. The molecular weight of the cationic polymer template is less than 1000000, and the structure formula of the cationic polymer template is represented as the formula (I). The invention also relates to the resistance reducing agent for fracture prepared through the method. The resistance reducing agent for fracture is high in resistance reducing rate, is low in formation damage property, is high in inhibition on clay expansion, is good in water solubility and is green and environment-friendly.

Description

technical field [0001] The invention relates to a drag reducing agent for fracturing and a preparation method of the drag reducing agent for fracturing. Background technique [0002] Hydraulic fracturing of oil and gas layers, referred to as fracturing, is a technology developed in the 1940s to modify the seepage characteristics of oil and gas layers, and is an important technological measure for increasing production of oil and gas wells and increasing injection of water injection wells. Fracturing fluid is an important medium in the fracturing process. Commonly used fracturing fluids include water-based fracturing fluid, oil-based fracturing fluid, emulsified fracturing fluid, and foam fracturing fluid. Shale gas reservoirs are characterized by low porosity and low permeability, and are difficult to exploit. At present, the slick water fracturing process is mainly used for exploitation. The fracturing fluid is pressurized by the high-pressure pump injection equipment, and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F220/56C08F220/06C08F220/58C09K8/68
Inventor 张文龙黄凤兴伊卓赵方园刘希
Owner CHINA PETROLEUM & CHEM CORP
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