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Polyvinylidene fluoride (PVDF) agricultural plastic colored mulching film and manufacturing method thereof

A technology of polyvinylidene fluoride and vinylidene fluoride, which is applied to the manufacture of the above-mentioned polyvinylidene fluoride agricultural plastic colored mulch film, and the field of polyvinylidene fluoride agricultural plastic colored mulch film, which can solve the problem that it is difficult to exert benefits and the recycling cost is high , economic gains outweigh the losses, etc., to achieve excellent mechanical properties and weather resistance, increase yield and quality, and prevent insect fertilizer loss.

Inactive Publication Date: 2014-12-24
江苏昊华光伏科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The most serious of these is the so-called "white pollution", especially the fragments of agricultural film left in the soil will gradually accumulate and form a barrier layer, which seriously affects the normal growth of plant roots, destroys soil heat transfer and water drainage, and ultimately results in reduced production.
my country is a big agricultural country, but in my country's agricultural film market, PE film is the main product, some are PVC film and EVA film, and the agricultural mulch film used in my country is generally thin (the thickness of mulch film produced by Chinese enterprises is 6 μm, and the thickness of the film in the United States is 6 μm. 24μm, 20μm in South Korea, 15μm in Japan) low strength, poor weather resistance and anti-aging performance. Whether it is peeling off the film at the right time for crops or at the end of crop harvest, the film is easy to break when using mechanical operations for winding and recycling. Affect the continuous operation of the machine, making it difficult to exert benefits
Furthermore, such agricultural film has poor availability after recycling, and the recycling cost is relatively high, so the economic gain outweighs the loss

Method used

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  • Polyvinylidene fluoride (PVDF) agricultural plastic colored mulching film and manufacturing method thereof
  • Polyvinylidene fluoride (PVDF) agricultural plastic colored mulching film and manufacturing method thereof
  • Polyvinylidene fluoride (PVDF) agricultural plastic colored mulching film and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Contains the following mass percentage components: PVDF resin (VDF homopolymer, melt flow index 8 ~ 15g / 10min (230 ℃, 5Kg), obtained from domestic Sanaifu company) 54%, Plexiglas 7N (polymethacrylate Ester resin, melt flow index is 6g / 10min (230 ℃, 3.8Kg) obtains from Evonik Rohm company) 32%, R-960 (is the nanoscale rutile titanium dioxide, average particle size 500nm, the surface has been trioxide Aluminum and silica treatment, obtained from DuPont Company) 10%, composite light stabilizer (composition of UV absorber Tinuvin 1577, Tinuvin 327 and hindered amine Tinuvin 770, obtained from Ciba Refining Company) 2.6%, Irganox B 215 (composition of antioxidants Irgafos168 and Irganox1010, available from Ciba Fine Chemicals) 1.2%, dispersant EBS (N,N,-ethylenebisstearamide) 0.2%.

[0024] The above components were pre-dried and added to a high-speed mixer, stirred at a high speed of 90°C for 30 minutes, and then cooled to 45°C to obtain a special dry blend.

[0025] Extru...

Embodiment 2

[0028]Contains the following mass percentage components: PVDF resin (VDF homopolymer, melt flow index 8 ~ 15g / 10min (230 ℃, 5Kg), obtained from domestic Sanaifu company) 54%, Plexiglas 7N (polymethacrylate Ester resin, melt flow index is 6g / 10min (230 ℃, 3.8Kg) obtained from Evonik Rohm company) 20%, D320 (containing acrylate impact modifier: shell is PMMA, core is butyl acrylate / butadiene copolymer, obtained from Arkema company) 12%, R-960 (for nanoscale rutile titanium dioxide, average particle size 500nm, the surface has been treated with aluminum oxide and silicon dioxide, obtained from DuPont (DuPont) company ) 10%, composite light stabilizer (composition of UV absorber Tinuvin 1577, Tinuvin P and hindered amine Tinuvin 770, obtained from Ciba Refining Company) 2.6%, Irganox B 215 (composition of antioxidant Irgafos168 and Irganox1010, from Ciba Chemicals) 1.2%, dispersant EBS (N,N,-ethylenebisstearamide) 0.2%.

[0029] The above components were pre-dried and added to a...

Embodiment 3

[0033] Contains the following mass percentage components: PVDF resin (VDF homopolymer, melt flow index 8 ~ 15g / 10min (230 ℃, 5Kg), obtained from domestic Sanaifu company) 58%, Altuglas BS 580 (methyl methacrylate Copolymer of ester and methyl acrylate, the melt flow index is 4.5g / 10min (230 ℃, 3.8Kg) obtained from Arkema company) 35%, R-960 (for nano-scale rutile titanium dioxide, the average particle size is 500nm, the surface has been Aluminum oxide and silica treatment, obtained from DuPont Company) 0.1%, R330R (carbon black obtained from Cabot Company) 2.9%, composite light stabilizer (UV absorber Tinuvin 1577, Tinuvin 327 and hindered amine Tinuvin 770 Composition obtained from Ciba Chemical Company) 2.6%, Irganox B 215 (composition of antioxidant Irgafos168 and Irganox1010 obtained from Ciba Chemical Company) 1.2%, dispersant EBS (N,N,-ethylene bis stearamide) 0.2%.

[0034] The above components were pre-dried and added to a high-speed mixer, stirred at a high speed of ...

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Abstract

The invention discloses a polyvinylidene fluoride (PVDF) agricultural plastic colored mulching film. The PVDF agricultural plastic colored mulching film contains the following components in percentage by weight: 50%-80% of PVDF resin, 10%-40% of PMMA (polymethylmethacrylate) resin, 0.05%-15% of pigment, 0.1%-3% of light stabilizer, 0-3% of heat stabilizer and 0.05%-3% of dispersant. The manufacturing method of the mulching film comprises the following steps: (1) performing high-speed stirring on components after pre-drying treatment at the temperature of 80 DEG C-100 DEG C for 30min, and then cooling to 45 DEG C to obtain a special dry blend; (2) performing extrusion and granulation on the obtained dry blend by a twin-screw extruder at the temperature of 170 DEG C-210 DEG C; and (3) adding master batches into a single-screw extruder for plasticization and extrusion, performing tape casting on a melt by a clothes hanger type mold head for forming a film, and further cooling, drawing and coiling by double rollers to obtain the PVDF agricultural plastic colored mulching film. The mulching film has relatively good mechanical properties and weather resistance, and has the functions of controlling the growth of weeds in soil, realizing heat preservation, mulching, preservation of soil moisture, water conservation and insect prevention of crops, preventing the loss of a fertilizer, promoting early maturing of the crops and improving the yield and quality of the crops.

Description

technical field [0001] The invention relates to a mulch film, in particular to a polyvinylidene fluoride agricultural plastic colored mulch film, and the thickness of the film is 10 μm to 80 μm. The present invention also relates to a method for manufacturing the polyvinylidene fluoride agricultural plastic colored plastic film. Background technique [0002] Since the application of plastic film to agricultural production in my country, production practice has proved that the application of agricultural plastic film covering cultivation technology can not only promote crop growth, increase crop production, increase farmers' income, but also change my country's traditional agricultural production methods. Among them, plastic film mulching cultivation technology can play the role of heat preservation and mulching, antifreeze, moisture conservation, light adjustment, water saving, weed control, insect control and soil salinity control, which can promote early maturity of crops,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/16C08L33/12C08K13/06C08K3/22C08K3/26C08K3/04C08K3/36A01G13/02B29C47/92B29C48/92
Inventor 龚福根龚之雯
Owner 江苏昊华光伏科技有限公司
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