Measuring method for current carrier concentration in solar energy level monocrystal silicon
A carrier concentration, solar-level technology, applied in the direction of measuring devices, single semiconductor device testing, instruments, etc., can solve the problem of carrier mobility decline and other issues
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Embodiment 1
[0051] (1) Select a series of p-type electronic grade single crystal silicon as standard samples, the resistivity of the standard samples is 0.05-50Ω.cm, and the resistivity of the standard samples is evenly distributed within the range of each resistivity magnitude. The standard sample has a uniform thickness of 1-2mm.
[0052] (2) After the standard sample is cleaned by the standard cleaning process, the resistivity of each sample is measured at room temperature according to the national standard "Method for Determination of Resistivity of Silicon Single Crystal" (GB / T1551-2009), and the resistivity is calculated by formula (5) Converted to the corresponding carrier concentration.
[0053] (3) The standard sample is chemically polished to make the two surfaces mirror, and after being cleaned by a standard cleaning process, the infrared transmission coefficient of each sample is measured by a Fourier transform infrared spectrometer (FTIR), and converted into an infrared trans...
Embodiment 2
[0061] Steps (1)~(3) are the same as in Example 1, and the (α λ1 -α λ2 ) / (λ 1 2 -λ 2 2 ) and ρp 2 The standard curve of , where: λ 1 = 1 / 400cm, λ 2 = 1 / 1150cm, α λ1 with alpha λ2 are the wavelength λ 1 , lambda 2 The infrared absorption coefficient of the standard sample, such as Figure 4 As shown, its expression is: (α λ1 -α λ2 ) / (λ 1 2 -λ 2 2 )=(α 1 / 400 -α 1 / 1150 ) / (λ 2 1 / 400 - / λ 2 1 / 1150 )=7.9×10 -27 ρp (9)
[0062] For a certain boron-phosphorus compensation type solar-grade monocrystalline silicon sample to be tested in Example 1, its carrier concentration is calculated according to formula (9) to be 2.63×10 16 cm -3 . As a preferred method, the result is more accurate than Example 1.
[0063] It can be seen that the carrier concentration in solar-grade monocrystalline silicon can be measured more accurately by using the method of the present invention.
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