Polarizing film with adhesive layer and image display device
An adhesive layer, polarizing film technology, applied in the direction of adhesive type, ester copolymer adhesive, film/sheet adhesive, etc., to prevent abnormal appearance
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[0128] The following examples illustrate the present invention in detail, but the present invention is not limited by these examples. In addition, the parts and % in each example are based on weight.
[0129]
[0130] The weight-average molecular weight of the hydroxyl group-containing (meth)acrylic polymer (A) is measured by GPC (gel permeation chromatography).
[0131] ・Analyzer: HLC-8120GPC manufactured by Tosoh Corporation
[0132] ・Pillar: Made by Tosoh Corporation, G7000H XL +GMH XL +GMH XL
[0133] ・Column size: 7.8mmφ×30cm each, 90cm in total
[0134] ·Column temperature: 40℃
[0135] ·Flow: 0.8ml / min
[0136] ·Injection volume: 100μl
[0137] ·Eluent: tetrahydrofuran
[0138] Detector: Differential refractometer (RI)
[0139] ·Standard sample: polystyrene
[0140]
[0141]In order to produce a thin polarizer, first, a laminate having a 9 μm-thick PVA layer formed on an amorphous PET substrate is subjected to in-air auxiliary stretching at a stretching t...
manufacture example 1
[0151]
[0152] In a reaction vessel equipped with a condenser tube, a nitrogen gas introduction tube, a thermometer, and a stirring device, 99 parts of butyl acrylate, 1 part of 4-hydroxybutyl acrylate (HBA), and 1 part of 4-hydroxybutyl acrylate (HBA), and ) 100 parts of AIBN as an initiator was reacted at 60°C for 7 hours under a nitrogen stream, and then ethyl acetate was added to the reaction solution to obtain a hydroxyl-containing (methyl ) acrylic polymer (A-1) (solid content concentration: 30% by weight). Table 2 shows the composition and molecular weight of the (meth)acrylic polymer (A-1).
manufacture example 2
[0154]
[0155] In Production Example 1, except that a monomer mixture containing 99 parts of butyl acrylate and 1 part of 2-hydroxyethyl acrylate (HEA) was used as the monomer mixture, the weight average molecular weight was prepared in the same manner as in Production Example 1. 1.6 million solution of (meth)acrylic polymer (A-2). Table 2 shows the composition and molecular weight of the (meth)acrylic polymer (A-2).
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