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A kind of metal nail strip adhesive and preparation method thereof

An adhesive and metal technology, used in adhesives, adhesive additives, monocarboxylate copolymer adhesives, etc., can solve problems such as difficulty in meeting high-end manufacturing enterprises, reducing nail row production efficiency, and poor storage stability. Achieve the effect of shortening production cycle, fast drying speed and good compatibility

Active Publication Date: 2015-09-30
张志东
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

And the existing adhesive has the following problems: a. The peel strength is low or high. When the peel strength is low, when the glued row nails are cut off in the cutting process, or the manufactured row nails are packed, transported, etc. When the peeling strength is high, the nails are firmly bonded and cannot be driven out in a nail gun, which is difficult to meet the needs of high-end manufacturing companies; b. The drying speed is slow, which reduces the production efficiency of the nails; c. The storage stability is poor, and the storage period is generally about 6 months

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] An adhesive for metal nails, which is composed of the following mass percentages of raw materials: 8% carboxy vinyl resin with an average molecular weight of about 34000, 8% carboxy vinyl resin with an average molecular weight of about 27,000, and 4.5% nitrile rubber , Epoxy resin 5.5%, methyl hexahydrophthalic anhydride 3.3%, aluminum acetylacetonate 0.7%, methyl acetate 35%, acetone 35%; carboxyl vinyl acetate resin is vinyl chloride-vinyl acetate-maleic acid terpolymer resin; The epoxy resin is E44 epoxy resin; the acrylonitrile content of the nitrile rubber is 30-41wt%, and the Mooney viscosity is 50-70 ML100°C 1+4.

[0031] The preparation method of the metal row nail adhesive specifically includes the following steps:

[0032] A. Raw material pretreatment:

[0033] (1) Pre-reaction of epoxy resin: epoxy resin, methylhexahydrophthalic anhydride, and aluminum acetylacetonate are reacted at 45 degrees for 1 hour, ready for use;

[0034] (2) Pre-processing of nitrile rubber:...

Embodiment 2

[0042] An adhesive for metal nails, which is composed of the following mass percentages of raw materials: 10.99% carboxyl vinyl acetate resin with an average molecular weight of about 34000, 2% carboxyl vinyl acetate resin with an average molecular weight of about 27,000, and 3.5% nitrile rubber , Epoxy resin 4.5%, methyl hexahydrophthalic anhydride 2%, aluminum acetylacetonate 0.01%, acetone 77%; carboxyl vinyl acetate resin is vinyl chloride-vinyl acetate-maleic acid ternary copolymer resin; epoxy resin is E44 ring Oxygen resin; acrylonitrile content of nitrile rubber is 30-41wt%, Mooney viscosity is 50-70 ML100℃1+4.

[0043] The preparation method of the metal row nail adhesive specifically includes the following steps:

[0044] A. Raw material pretreatment:

[0045] (1) Pre-reaction of epoxy resin: epoxy resin, methylhexahydrophthalic anhydride, and aluminum acetylacetonate are reacted at 55°C for 1 hour, for later use;

[0046] (2) Pre-processing of nitrile rubber: the nitrile r...

Embodiment 3

[0054] An adhesive for metal nails, which is composed of the following mass percentages of raw materials: 12% carboxyl vinyl chloride resin with an average molecular weight of about 34000, 4% carboxyl vinyl chloride resin with an average molecular weight of about 27000, and 5.5% nitrile rubber , Epoxy resin 5%, methyl hexahydrophthalic anhydride 2.5%, aluminum acetylacetonate 1%, methyl acetate 40%, acetone 30%; carboxyl vinyl acetate resin is vinyl chloride-vinyl acetate-maleic acid terpolymer resin; The epoxy resin is E44 epoxy resin; the acrylonitrile content of the nitrile rubber is 30-41wt%, and the Mooney viscosity is 50-70 ML100°C 1+4.

[0055] The preparation method of the metal row nail adhesive specifically includes the following steps:

[0056] A. Raw material pretreatment:

[0057] (1) Pre-reaction of epoxy resin: epoxy resin, methylhexahydrophthalic anhydride, and aluminum acetylacetonate are reacted at 50°C for 1 hour, ready for use;

[0058] (2) Pre-processing of nitri...

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Abstract

The invention discloses a metal strip nail adhesive and a preparation method thereof, and relates to the technical field of adhesives based on resin. The metal strip nail adhesive comprises the following raw materials in percentage by weight: 8%-16% of carboxyl vinyl chloride-vinyl acetate resin with average molecular weight about 34000, 0%-8% of carboxyl vinyl chloride-vinyl acetate resin with the average molecular weight about 27000, 3.5%-5.5% of nitrile rubber, 4.5%-6.5% of epoxide resin, 2%-4% of methylhexahydrophthalic anhydride, 0.01%-1% of aluminium acetylacetonate, 0%-40% of methyl acetate and 30%-77% of acetone. The metal strip nail adhesive is prepared through pretreatment, mixing, heating and stirring. The metal strip nail adhesive disclosed by the invention has the characteristics of moderation in stripping strength, fast drying, stability in storage and easiness for operation; a strip nail adhered through the adhesive can not be cracked when being cut in a cutting procedure, or a manufactured strip nail can not be cracked when being encased and transported; and the strip nail is easy to shoot in a nail gun, high in nailing efficiency and increased in production efficiency.

Description

Technical field [0001] The invention relates to the technical field of resin-based adhesives. Background technique [0002] Row nails are a new type of woodworking nails that are used to bond regularly arranged single nails with adhesive or other methods. The row of nails is put into a special nail gun, powered by electricity or compressed air, and shot into wood, plastic, or other composite materials through impact. The nail gun is widely used in construction, decoration, furniture, packaging, advertising decoration, decoration, sofas, leather shoes, leather goods, etc. because of its high efficiency, uniform and consistent force of the nails, and convenient use. There is also a large demand for "bullet" row nails. It will replace small iron nails, artificial decoration, decoration and other aspects of nails. [0003] The general production process of the row of nails is as follows: the round wire is straightened and squashed by a flattening machine, and assembled on a certain ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J127/06C09J131/04C09J163/00C09J109/02C09J11/06
Inventor 张志东
Owner 张志东
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