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Flame-retardant modified, anti-static and toughened PBT master batch

A toughening masterbatch, antistatic technology, applied in the field of PBT flame retardant modified antistatic toughening masterbatch, can solve the problems of poor notched impact strength, flammable antistatic, strength, stiffness reduction, etc., to improve toughness , optimistic social and economic benefits, good heat resistance

Inactive Publication Date: 2014-04-09
QINGDAO XINZHAN PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, pure PBT has disadvantages such as poor notched impact strength, low toughness, flammability, and insufficient antistatic properties. Therefore, PBT should usually be applied after modification. Common modifications include toughening enhancement, flame retardancy, and antistatic properties. sex
Previous studies have shown that elastomers can effectively toughen, but cause a large decrease in strength and stiffness; inorganic fillers can effectively enhance, but often cause a significant decrease in impact toughness; mix elastomers, inorganic fillers with PBT and additives. Extrusion and granulation have a good modification effect on the strength and toughness of the material. The blending of elastomers and inorganic fillers has become an important and effective means of toughening and strengthening PBT.
However, adding various additives (such as flame retardants, antistatic agents, etc.) During the process, the powder is flying and it is not conducive to clean production. At the same time, it will also lead to cumbersome production process and low efficiency.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A PBT flame retardant modified antistatic toughening masterbatch, its components are proportioned by mass percentage: PBT carrier 15%, phosphate ester flame retardant 30%, micron calcium carbonate 20%, EPDM rubber-matrix Toric anhydride graft (EPDM-g-MAH) 20%, bis(2-hydroxyethyl) octylmethyl ammonium bis-p-toluenesulfonate 10%, polysiloxane 2%, silane coupling agent 1.5%, 1% compound of hindered phenol antioxidant 1076 and phosphite antioxidant 168, 0.5% of triacetone amine stabilizer, among which, the PBT carrier is polybutylene terephthalate, and the average particle size of micron calcium carbonate The diameter is between 0.1 μm and 10 μm.

[0022] Preparation method: (1) Weigh each component according to the weight ratio for use; (2) Mix PBT carrier, phosphate ester flame retardant, micron calcium carbonate, EPDM rubber-maleic anhydride graft (EPDM -g-MAH), bis(2-hydroxyethyl)octylmethyl ammonium bis-p-toluenesulfonate, polysiloxane, silane coupling agent, hindered...

Embodiment 2

[0024] A PBT flame-retardant modified anti-static toughening masterbatch, the components of which are proportioned by mass percentage: 12% of PBT carrier, 40% of phosphite flame retardant, 20% of micron calcium carbonate, maleic anhydride post ethylene - Octene copolymer (POE-g-MAH) 10%, glyceryl monostearate (GMS) 15%, polyethylene wax 1%, calcium stearate coupling agent 1%, hindered phenol antioxidant 1076 and 0.5% compound of phosphite antioxidant 168, 0.5% benzotriazole stabilizer, among which, the PBT carrier is polybutylene terephthalate, and the average particle size of micron calcium carbonate is 0.1 μm to 10 μm between.

[0025] Preparation method: (1) Weigh each component according to the weight ratio for use; (2) Mix PBT carrier, phosphite flame retardant, micron calcium carbonate, maleic anhydride grafted ethylene-octene copolymer (POE -g-MAH), glyceryl monostearate (GMS), polyethylene wax, calcium stearate coupling agent, compound of hindered phenol antioxidant 1...

Embodiment 3

[0027] A PBT flame retardant modified antistatic toughening masterbatch, its components are proportioned by mass percentage: PBT carrier 12%, phosphonate flame retardant 25%, micron calcium carbonate 25%, ethylene-methyl acrylate- Glycidyl methacrylate terpolymer (E-MA-GMA) 25%, nanoscale antimony-doped tin oxide (ATO) 8%, OP wax 1.5%, calcium stearate coupling agent 2%, hindered phenolic The compound of oxygen agent 1076 and phosphite antioxidant 168 is 1%, and hindered amine stabilizer is 0.5%. Among them, the PBT carrier is polybutylene terephthalate, and the average particle size of micron calcium carbonate is 0.1μm ~10μm.

[0028] Preparation method: (1) weigh each component according to the weight ratio for use; (2) mix PBT carrier, phosphonate flame retardant, micron calcium carbonate, ethylene-methyl acrylate-glycidyl methacrylate Compound of meta-copolymer (E-MA-GMA), nanoscale antimony-doped tin oxide (ATO), OP wax, calcium stearate coupling agent, hindered phenol a...

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Abstract

The invention discloses a flame-retardant modified, anti-static and toughened PBT master batch. The master batch comprises the following components by mass: 10%-15% of a PBT carrier, 25%-40% of a halogen-free flame retardant, 10%-30% of micrometer calcium carbonate, 10%-30% of a grafting elastomer, 5%-15% of an antistatic agent, 1%-3% of a lubrication dispersant, 0.5%-2% of a coupling agent, 0.5%-1.5% of an antioxidant and 0.5%-1% of a stabilizing agent. The flame-retardant modified, anti-static and toughened PBT master batch has the beneficial effects that the prepared master batch has the characteristics of high concentration, multifunction, low cost and convenient use; by adopting the grafting elastomer, the master batch has significantly increased toughness and good compatibility; the micrometer calcium carbonate can greatly increase toughness, rigidity and heat resistance and can keep good impact strength; the halogen-free flame retardant has safe, smoke-suppressing, non-toxic and environment-friendly high flame retardant performance; and the anti-static agent make surface resistivity reduce to between 10<8> and 10<10> ohms.cm while guaranteeing the anti-static function.

Description

technical field [0001] The invention relates to a master batch, in particular to a PBT flame-retardant modified antistatic toughened master batch. Background technique [0002] Polybutylene terephthalate (PBT) is a crystalline linear saturated polyester resin, which has been widely used in electronic appliances, home appliances, automobile industry, mechanical equipment and other industries. However, pure PBT has disadvantages such as poor notched impact strength, low toughness, flammability, and insufficient antistatic properties. Therefore, PBT should usually be applied after modification. Common modifications include toughening enhancement, flame retardancy, and antistatic properties. sex. Previous studies have shown that elastomers can effectively toughen, but cause a large decrease in strength and stiffness; inorganic fillers can effectively enhance, but often cause a significant decrease in impact toughness; mix elastomers, inorganic fillers with PBT and additives. E...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L51/00C08L51/06C08L67/00C08K13/02C08K3/26C08K5/42C08K5/19C08K5/103C08K3/22C08K3/08C08J3/22
Inventor 不公告发明人
Owner QINGDAO XINZHAN PLASTIC
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