Method for compounding natural protein fiber powder on surfaces of polymer filaments
A protein fiber and surface composite technology, which is applied in the direction of plant fiber, fiber type, fiber treatment, etc., can solve the problems of single choice of matrix material, poor temperature resistance of natural protein fiber powder, low content of natural protein fiber powder, etc.
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[0032] A Preparation of blend solution
[0033] According to the following mass percentage:
[0034] Natural protein fiber powder 1-16%
[0035] Protein Compatible Polymer 1-12%
[0036] Polar solvents 72-98%
[0037] Wool fiber powder or cashmere fiber powder or silk fiber powder or down fiber powder or rabbit hair fiber powder or camel hair fiber powder or human hair fiber powder or mohair fiber powder or yak fiber powder with an average particle size of ≤2 μm One of the wool fiber powders is put into soft water or 8% acetic acid aqueous solution or dimethylformamide or dimethylacetamide or dimethyl sulfoxide or 1,4-dioxane, and ultrasonically disperses 1- After 3 hours, add one of polyurethane or polyvinyl alcohol or polyacrylonitrile or gelatin or chitosan with a number average molecular weight of 8000-100000, and use mechanical stirring to make the protein phase at a temperature of 25-98 ° C. Allow the polymer to dissolve, and after dissolving for 3-5 hours, obtain a ...
Embodiment 1
[0046] A Put 1 g of wool fiber powder with an average particle size of 2 μm into 98 g of dimethylformamide, and after ultrasonic dispersion for 1 h, add 1 g of polyurethane with a number average molecular weight of 8000, and use Mechanical stirring makes polyurethane dissolve, after dissolving 3h, obtain blend solution through static vacuum degassing, the viscosity of blend solution is 100 mPa s, and static vacuum degassing temperature is 25 DEG C;
[0047] B Warm up the blended solution prepared in step A to 25°C under ultrasonic vibration, pass the polyester with a denier of 1 denier and 1 root through the blended solution and the thickness control mold at a speed of 50 m / min The diameter of the upper hole is 25 μm, and the length of the hole is a guide wire hole of 5 mm to obtain a polyester with a thickness of 10 μm on the surface of the composite blend solution, and the distance of the polyester through the blend solution is 2 cm;
[0048] C is after the terylene of the s...
Embodiment 2
[0051] A Put 2 g of cashmere fiber powder with an average particle size of 1.5 μm into 97 g of demineralized water, and after ultrasonic dispersion for 2 hours, add 1 g of polyvinyl alcohol with a number-average molecular weight of 10,000. Stir to make the polyvinyl alcohol dissolve, after dissolving for 4h, obtain the blended solution through static vacuum degassing, the viscosity of the blended solution is 250 mPa s, and the static vacuum degassing temperature is 30 °C;
[0052] B The blending solution prepared in step A is heated up to 85°C under ultrasonic vibration, and the denier is 10 deniers, and the polyamide fibers with 4 roots pass through the blending solution and the thickness control mold at a speed of 80 m / min The diameter of the upper hole is 50 μm, and the length of the hole is 10 mm. The nylon fiber with a surface composite blend solution thickness of 12 μm is obtained, and the distance of the nylon fiber through the blend solution is 4 cm;
[0053] C is afte...
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