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A kind of organic particle filled gas permeable membrane and preparation method thereof

A technology of organic particles and breathable film, applied in the field of organic particle filled breathable film and its preparation, can solve the problems of difficulty in controlling the size of inorganic particle filler, increased probability of mechanical failure, unsatisfactory effect, etc., and achieves uniform force and flatness. Good, easy-to-process results

Inactive Publication Date: 2015-08-26
陈忱
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Surface modification improves the compatibility of inorganic particles and resin volume to some extent, but the effect is only unsatisfactory
[0009] In addition, the size of inorganic particle fillers is relatively difficult to control, especially it inevitably contains many particles with a particle size smaller than the average particle size (D50)
When filling the resin matrix with filler particles, when the size of the filler particles decreases, the presence of small particle size fillers may cause die drool and smoke due to the increasingly difficult processing of the filled resin
Small particle size fillers caused by uneven particle size control increase the viscosity of the resin when mixing is too high, which increases the probability of mechanical failure of the equipment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] The gas-permeable membrane filled with organic particles provided in this embodiment includes the following raw materials in weight percentage: polyethylene: 50%; organic particle filler: 45%; processing aid: 5%. The organic particle filler is polystyrene cross-linked divinylbenzene, the CAS number of the polystyrene cross-linked divinylbenzene is 69011-14-9, and the manufacturer is Guangzhou Weber Chemical Co., Ltd. Wherein said processing aid is a mixture of lubricant, antioxidant, color masterbatch and wax, and the lubricant used is the lubricant of CP-333, and the manufacturer is: Shanghai Zirun Chemical Auxiliary Co., Ltd.; The brand of antioxidant is Clariant's antioxidant, and the manufacturer is: Shanghai Kaiyin Chemical Co., Ltd.; the brand of color masterbatch is Clariant's color masterbatch, and the manufacturer is: Ganzhou Yongfeng Plastic Technology Co., Ltd.; the use of wax It is the wax whose model is NNO, and the manufacturer is: Changzhou Jubao Chem...

Embodiment 2

[0041] The gas-permeable membrane filled with organic particles provided in this embodiment includes the following raw materials in weight percentage: polyethylene: 45%; organic particle filler: 53%; processing aid: 2%. Wherein the organic particle filler is formed by mixing styrene cross-linked ethylene glycol dimethacrylate and styrene cross-linked dicyclopentadiene, wherein styrene cross-linked ethylene glycol dimethacrylate consists of the following weight percent Raw materials: 40% styrene, 2.4% ethylene glycol dimethacrylate, 2% potassium oleate, 0.5% sodium hydrogen phosphate, 54.7% distilled water, 0.4% potassium persulfate. The preparation method of styrene cross-linked ethylene glycol dimethacrylate comprises the steps: first raw material styrene, potassium oleate, ethylene glycol dimethacrylate, sodium hydrogen phosphate, distilled water are added in the reactor in proportion Emulsify, leave a part of the emulsion in the reactor, add 1 / 4-1 / 2 of the prescription amou...

Embodiment 3

[0048] The gas-permeable membrane filled with organic particles provided in this embodiment includes the following raw materials in weight percentage: polyethylene: 55%; organic particle filler: 37%; processing aid: 8%. Wherein the organic particle filler adopts polystyrene cross-linked divinylbenzene, styrene cross-linked ethylene glycol dimethacrylate, styrene cross-linked dicyclopentadiene, styrene cross-linked triallyl isocyanurate

[0049] Mixed, the CAS number of the polystyrene cross-linked divinylbenzene used is 69011-14-9, and the manufacturer is: Guangzhou Weber Chemical Co., Ltd.

[0050] Among them, styrene cross-linked ethylene glycol dimethacrylate is prepared from the following raw materials in weight percentage: styrene 40%, ethylene glycol dimethacrylate 2.4%, potassium oleate 2%, sodium hydrogen phosphate 0.5% , distilled water 54.7%, potassium persulfate 0.4%. The preparation method of styrene cross-linked ethylene glycol dimethacrylate comprises the steps:...

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Abstract

The invention discloses an organic particle filled breathable film, which comprises the following raw materials by weight: 35%-60% of polyethylene, 35%-55% of an organic particle filler, and 1%-10% of a processing aid, wherein the organic particle filler employs a highly cross-linked polymer. The invention provides the organic particle filled breathable film and the preparation method thereof. The organic particle filler used to substitute an inorganic particle filler has advantages of a controllable size, high degree of spheroidization, good compatibility with a resin matrix, easy processing, and no requirement of surface modification process; the prepared breathable membrane surface has uniform force and good flatness; at the same time, the hydrophobic organic particle filler is employed to substitute the hydrophilic inorganic particle filler, so as to endow the breathable film with better waterproofness and air permeability.

Description

technical field [0001] The invention relates to a gas-permeable membrane filled with organic particles and a preparation method thereof. Background technique [0002] In the preparation of polyethylene (PE) breathable membrane material, because the resin matrix is ​​relatively soft, it is often filled with inorganic particles to increase its strength. In actual production, the resin matrix, inorganic particle fillers and processing aids are often blended and granulated by a twin-screw extruder to prepare a breathable film masterbatch, and then the masterbatch is made into a film base by calendering, casting or blow molding. material, and then stretched to become a breathable membrane material with a certain number of pores, so that it has the special performance of waterproof and breathable. [0003] At present, the particle fillers in polyethylene breathable membrane materials are mostly inorganic particle fillers, mainly calcium carbonate, talc powder, magnesium carbonate...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/06C08L25/08B29C47/92B29C48/92
CPCB29C47/92B29C2947/92514B29C2947/92895B29C2947/92704B29C48/40B29C48/92B29C2948/92514B29C2948/92704B29C2948/92895
Inventor 金华江王建黎张诚李安安
Owner 陈忱
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