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High-dielectric-constant resin composition and application thereof

A technology of high dielectric constant and resin composition, applied in the field of antenna substrate, high dielectric constant composite material and prepreg and copper clad laminate made of the same, and high dielectric constant resin composition, can solve the problem. E-type glass fiber cloth has low dielectric constant, low glass transition temperature, and large dielectric loss of the cured product.

Inactive Publication Date: 2013-10-16
GUANGDONG SHENGYI SCI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This patent uses active ester as curing agent, although the cured product has lower dielectric loss, but the glass transition temperature is lower
[0005] Chinese patent CN101974205 discloses a high dielectric constant resin composition, including epoxy resin, at least one phenolic resin or terminal carboxyl nitrile rubber, biphenyl type phenolic resin or tea type phenolic resin, high dielectric constant filler, Although the cured product has a higher dielectric constant, a higher glass transition temperature (T g up to 156°C), but the dielectric loss of the cured product is too large, as high as 0.038
[0006] In high dielectric constant copper clad laminates, in order to make the dielectric constant higher, the content of high dielectric constant fillers is very high, so that the peel strength of copper clad laminates is reduced
At the same time, in high dielectric constant copper-clad laminates, E-type glass fiber cloth is usually used as a reinforcing material, but the dielectric constant of E-type glass fiber cloth is low, and it is difficult to make high-dielectric constant copper-clad laminates The dielectric constant value reaches a higher

Method used

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  • High-dielectric-constant resin composition and application thereof
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  • High-dielectric-constant resin composition and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0115] Take a suitable container, add 10 parts by mass of flexible epoxy resin EXA-4816, 30 parts by mass of dicyclopentadiene type novolac epoxy resin HP-7200L, 15 parts by mass of brominated epoxy resin EPICLON153-60M, 10 parts by mass Parts of phenolic novolac epoxy resin PNE177, 25 parts by mass of dicyclopentadiene type cyanate resin XU-71787, 26.8 parts by mass of active ester resin, and an appropriate amount of solvent to stir for a certain period of time, and then add an appropriate amount of accelerator Zinc octanoate and 4-dimethylaminopyridine, continue to stir evenly, and finally add 415 parts by mass of barium titanate high dielectric constant filler BT-300, fully stir, emulsify and disperse to form a glue. Immerse the above glue with high dielectric constant glass fiber cloth, and control it to a suitable thickness (control the mass content of high dielectric constant glass fiber cloth to be 10%), and then dry to remove the solvent to obtain a prepreg. The prepre...

Embodiment 2

[0117] Take a suitable container, add 10 parts by mass of flexible epoxy resin EXA-4822, 30 parts by mass of dicyclopentadiene type novolac epoxy resin HP-7200L, 15 parts by mass of brominated epoxy resin EPICLON153-60M, 10 parts by mass EPPN-501H of three phenolic methane type epoxy resins, 25 mass parts of dicyclopentadiene type cyanate resin XU-71787, 27.3 mass parts of active ester resins, and an appropriate amount of solvent are stirred for a certain period of time, and then Add an appropriate amount of accelerator zinc octoate and 4-dimethylaminopyridine, continue to stir evenly, and finally add 416 parts by mass of barium titanate high dielectric constant filler BT-300, fully stir, and emulsify and disperse to form a glue. Use high dielectric constant glass fiber cloth to impregnate the above glue solution, and control it to a suitable thickness (control the mass content of high dielectric constant glass fiber cloth to be 40%), and then dry to remove the solvent to obtai...

Embodiment 3

[0119]Take a suitable container, add 10 parts by mass of flexible epoxy resin EXA-4816, 30 parts by mass of dicyclopentadiene type novolac epoxy resin HP-7200L, 15 parts by mass of brominated epoxy resin EPICLON153-60M, 10 parts by mass Parts of tetraphenol ethane type epoxy resin EPON1031, 25 parts by mass of dicyclopentadiene type cyanate resin XU-71787, active ester resin of 25.8 parts by mass, and an appropriate amount of solvent are stirred for a certain period of time, and then added Appropriate amount of accelerator zinc octoate and 4-dimethylaminopyridine, continue to stir evenly, and finally add 411 parts by mass of barium titanate high dielectric constant filler BT-300, fully stir, and emulsify and disperse to form a glue. Use high dielectric constant glass fiber cloth to impregnate the above glue solution, and control it to a suitable thickness (control the mass content of high dielectric constant glass fiber cloth to be 20%), and then dry to remove the solvent to ob...

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Abstract

The invention relates to a high-dielectric-constant resin composition, as well as a prepreg and a copper-clad laminate (CCL) which are manufactured thereby. The prepreg manufactured by the high-dielectric-constant resin composition comprises high-dielectric-constant glass fiber fabric and a high-dielectric-constant resin composition subjected to impregnation drying and then attached to the high-dielectric-constant glass fiber fabric. The CCL manufactured by the high-dielectric-constant resin composition comprises at least one overlapped prepreg and copper foils pressed and coated on both sides of the overlapped prepregs. The CCL manufactured by the high-dielectric-constant resin composition has the performances of high dielectric constant, low dielectric loss, high glass transition temperature, high peel strength and the like and can meet the performance requirement of the high-dielectric-constant antenna substrate.

Description

technical field [0001] The invention belongs to the technical field of electronic materials, and relates to a resin composition and its application, in particular to a high dielectric constant resin composition and its application, and more specifically to a high dielectric constant composite material and its use. Prepreg and copper-clad laminate, the prepreg and copper-clad laminate made of the high dielectric constant composite material can be applied to antenna substrates. Background technique [0002] With the development of emerging micro-processing technologies such as microelectronics and micro-mechanics, not only digital and baseband circuit modules, but even radio frequency modules have successfully achieved miniaturization and chip design and production. As an important RF front-end device, the antenna has increasingly stringent requirements for its indicators. Miniaturization, built-in, multi-band, and intelligent are the development trends of small antennas for m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/04C08L63/00C08L79/04C08G59/42C08K3/24C08K7/00C08K7/14B32B27/04B32B15/092
Inventor 颜善银刘潜发苏民社殷卫峰许永静张江陵
Owner GUANGDONG SHENGYI SCI TECH
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