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Seamless PET (polyester) laser transfer membrane and preparation method thereof

A technology of laser transfer and seamless plate seam, which is applied in chemical instruments and methods, ink transfer from original manuscripts, coatings, etc., can solve problems such as bad odor, and achieve good corona retention, good wear resistance and scratch resistance, and weather resistance The effect of excellent performance

Active Publication Date: 2013-09-25
HAINAN SHINER IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Water-based resin is added to the water-based transfer coating, that is, the blend system of water-based acrylic acid and cellulose acetate butyrate; the water-based acrylic acid has high gloss under the condition of ensuring various unique properties of the acrylate coating, and removes most of the organic volatile solvents. Substitute for water, so as to achieve the purpose of greatly reducing air pollution, and completely solve the problem of bad smell and light reflection caused by solvent-based coatings; while cellulose acetate butyrate has good storage stability, UV resistance, cold resistance, flexibility, Transparent, electrical insulation and other properties

Method used

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  • Seamless PET (polyester) laser transfer membrane and preparation method thereof
  • Seamless PET (polyester) laser transfer membrane and preparation method thereof
  • Seamless PET (polyester) laser transfer membrane and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] (1) Mixing transfer coating: Add 14kg of water-based acrylic acid and cellulose acetate butyrate system, 10kg of sodium methallyl sulfonate, 4kg of polyethylene glycol, 3kg of ethyl acetate, and 68kg of deionized water into a stainless steel container in sequence Inside, stir evenly, the stirring speed is 500 rpm, and the stirring temperature is 50°C. After stirring evenly, add 1 kg of ammonia water to adjust the pH value to 8.0 to make a transfer coating.

[0043] (2) Coating: apply the mixed transfer coating to the PET base film 1 with a thickness of 9 μm through a clean and wear-free anilox roller, and dry it continuously at a temperature of 90°C for 6 seconds to form a protective film. Layer 2. The anilox roller is made of ceramics, the number of lines is 90 mesh, and the depth is 35μ. The length of the oven is 18m, and the temperature is low and high. The oven temperature is set at 80°C, 100°C, 120°C, 140°C, and 80°C.

[0044] (3) Molding:

[0045] Described mo...

Embodiment 2

[0051] (1) Mixing transfer coating: Add 80kg of water-based acrylic acid and cellulose acetate butyrate system, 12kg of sodium styrene sulfonate, 8kg of polyethylene glycol, 14kg of ethyl acetate, and 80kg of deionized water into the stainless steel container in sequence, and evenly Stirring, the stirring speed is 700 rpm, and the stirring temperature is 55°C. After stirring evenly, add 6kg of ammonia water, adjust the pH value to 8.0, and make the transfer coating.

[0052] (2) Coating: Apply the mixed transfer coating to the PET base film 1 with a thickness of 12 μm through a clean and non-abrasive anilox roller, and dry it continuously at 120°C for 10s to form a protective film. Layer 2. The anilox roll is electro-engraved, the number of lines is 110 mesh, and the depth is 40μ. The length of the oven is 22m, and the temperature is low and high. The oven temperature is set at 80°C, 100°C, 120°C, 140°C, and 80°C. The transfer coating coating amount is 1.4g / m 2 .

[0053]...

Embodiment 3

[0060] (1) Mixing transfer coating: Add 40kg of water-based acrylic acid and cellulose acetate butyrate system, 16kg of sodium methallyl sulfonate, 12kg of polyethylene glycol, 14kg of ethyl acetate, and 108kg of deionized water into a stainless steel container in sequence Inside, stir evenly, the stirring speed is 800 rpm, and the stirring temperature is 65°C. After stirring evenly, add 10kg of ammonia water, adjust the pH value to 9.0, and make the transfer coating.

[0061] (2) Coating: apply the mixed transfer coating onto the PET base film 1 with a thickness of 24 μm through a clean and non-abrasive anilox roller, and dry it continuously at 100°C for 12s to form a protective film. Layer 2. The anilox roll is a squeeze roll with a thread count of 130 mesh and a depth of 40μ. The length of the oven is 20m, and the temperature is low and high. The oven temperature is set at 80°C, 100°C, 120°C, 140°C, and 80°C. The coating amount of the transfer coating is 1.2g / m 2 .

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Abstract

The invention relates to a seamless PET (polyester) laser transfer membrane which comprises a carrier PET base membrane, a protection layer, an imaging layer and an aluminum layer, wherein the protection layer is a transfer coating layer, a transfer coating is prepared by adopting raw materials by weight percent: 12-40 percent of water-based resin system, 6-10 percent of ionic copolymerization monomer, 3-7 percent of a diluent, 40-68 percent of dispersion medium, 1-5 percent of a pH modifier and 4-8 percent of a crosslinking agent. The invention also relates to a preparation method of the seamless PET laser transfer membrane. The seamless PET laser transfer membrane provided by the invention is strong in metal luster and excellent in mechanical property, moisture prevention and weather resistance. The surface of the seamless PET laser transfer membrane adapts to various printing processes, and thus various artistic designs can be printed.

Description

technical field [0001] The invention relates to a seamless PET laser transfer film and a preparation method thereof, belonging to the field of new polymer materials. Background technique [0002] Since the laser packaging material was put into the market, its application in the fields of food, medicine, daily chemical products, tobacco and wine has been rapidly promoted, and its organic combination with color printing technology has become the most cutting-edge technology product in the world's printing and packaging industry. With the development of the world's green environmental protection requirements, the environment-friendly laser transfer film mainly using BOPP and PET as the carrier base film gradually replaces the traditional aluminum foil or plastic composite materials. But in contrast, the overall performance of BOPP transfer film is not as excellent as that of PET transfer film, and the recycling rate is not as high as the latter. Therefore, PET transfer film has...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B41M5/025B32B27/08B32B27/20C09D4/00C09D4/02C09D4/06C09D7/12
Inventor 洪景利赵晓娟胡连芹邢青涛
Owner HAINAN SHINER IND
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