Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Graphene-modified hard alloy and application thereof

A technology of graphene modification and cemented carbide, which is applied in the field of cemented carbide and its preparation process, can solve the problem of large density difference between carbon powder and cemented carbide, uneven distribution of carbon content in sintered body, large particle size of original carbon powder, etc. Problems, achieve uniform carbon content, overcome poor uniformity of addition, super high mechanical strength and flexibility

Active Publication Date: 2014-05-14
SUZHOU OUMEIKE CARBIDE TOOL
View PDF1 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the carbon content in cemented carbide is mainly mixed directly into cemented carbide powder in the form of direct carbon powder addition, and good mixing and dispersion with cemented carbide powder can be achieved through ball milling. However, due to the large difference in density between carbon powder and cemented carbide, And the particle size of the original carbon powder is large, which is easy to cause segregation, resulting in uneven distribution of carbon content in the final sintered body
The existing industrial route generally requires long-time ball milling to achieve uniform mixing of the two, but the cost is high and the working hours are long

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Graphene-modified hard alloy and application thereof
  • Graphene-modified hard alloy and application thereof
  • Graphene-modified hard alloy and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Example 1: Graphene oxide, which accounts for 0.5% of the weight of the cemented carbide powder, is dispersed in ethanol by ultrasonic, then the YG8 cemented carbide powder is added and mixed, ball milled in a planetary ball mill at 200 rpm for 24 hours, then vacuum-dried and mixed with 3wt % polyvinyl alcohol binder granulation, 350 MPa compression molding, 0.5 ℃ / min heating to 350 ℃ degreasing for 3 hours, 1350 ℃ vacuum sintering densification, obtained graphene modified cemented carbide, its structure and mechanical properties see performance figure 2 and Table 1.

Embodiment 2

[0037] Example 2: The difference between this embodiment and embodiment 1 is that the amount of graphene oxide added is 0.25% of the weight of the cemented carbide powder, and its structure and mechanical properties refer to image 3 and Table 1.

Embodiment 3

[0038] Example 3: The difference between this example and Example 1 is that the amount of graphene oxide added is 0.75% of the weight of the cemented carbide powder, and its mechanical properties are shown in Table 1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a grapheme-modified hard alloy, a preparation technology and an application thereof. The preparation technology comprises the steps of: uniformly dispersing a graphene material, especially uniformly dispersing graphene oxide into an inorganic solvent and / or organic solvent to form graphene dispersing liquid, and then mixing with hard alloy powder, and ball-milling, drying, pelleting, pressing and molding, degreasing and sintering in sequence to prepare a target product. The graphene oxide has good dispersibility in the solvent, so that the graphene oxide can be well wrapped on the surface of the hard alloy powder due to a huge surface area, and can be well dispersed and combined with the hard alloy in the subsequent molding process; meanwhile, the carbon content of the hard alloy can be adjusted by adding the high-activity graphene oxide, and mechanical enhancement of the graphene oxide on the hard alloy can be achieved. The preparation technology disclosed by the invention can be integrated with the conventional industrial preparation route of the hard alloy and is suitable for industrial production, and the overall performance of the hard alloy is obviously improved.

Description

technical field [0001] The invention relates to a cemented carbide and a preparation process thereof, in particular to a graphene-modified cemented carbide and a preparation method and application thereof. Background technique [0002] Cemented carbide is known as "industrial teeth". It is a cermet composite material sintered from carbide hard phase and metal bonding phase. It has excellent characteristics such as high hardness, high strength, good wear resistance, and high red hardness. Key materials in machining, mining drilling, industrial equipment and other fields. At present, the carbon content in cemented carbide is mainly mixed directly into cemented carbide powder in the form of direct carbon powder addition, and good mixing and dispersion with cemented carbide powder can be achieved through ball milling. However, due to the large difference in density between carbon powder and cemented carbide, Moreover, the particle size of the original carbon powder is large, wh...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C22C29/00C22C1/05C22C1/10
Inventor 王永富陈名海
Owner SUZHOU OUMEIKE CARBIDE TOOL
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products