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Prefabticated member for coal nozzle of cement kiln and preparation method thereof

A technology of coal injection nozzle and cement kiln, which is applied in the direction of combustion method, lighting and heating equipment, burner, etc. It can solve the problems of unstable strength at medium and low temperature, poor corrosion resistance, and inability to pre-heat treatment, etc., and achieves a small thermal expansion coefficient , Strong ability to resist acid and alkali erosion, reduce the effect of kiln shutdown time

Inactive Publication Date: 2012-08-01
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] It is worth noting that most of the refractory materials for coal injection nozzles are currently cast and cannot be pre-heated, and the temperature rises rapidly during the use of the rotary kiln, resulting in unstable strength at medium and low temperatures, and is easily corroded by atmospheres such as alkali, sulfur and chlorine.
Most of the existing technologies focus on how to solve the problems of poor thermal shock stability, poor wear resistance and poor corrosion resistance of refractory materials for coal injection nozzles, but none of them have achieved the desired effect. Even if the performance is better, the production process It is very complicated, and the labor cost increases accordingly. For example, the patented technology of "Clinker Kiln Wear-resistant Coal Injection Nozzle Combustion Device" (ZL200820096358.9) adopts the method of filling the castable between the inner casing and the outer casing to improve the overall wear resistance. However, it is too complicated to weld the grapple inside the outer casing and use two layers of casing to realize the pouring process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A prefabricated part for a cement kiln coal injection nozzle and a preparation method thereof. The raw materials and their percentages are: 55~60wt% tabular alumina particles, 8~10wt% silicon carbide particles, 7~8wt% tabular corundum fine powder, 8~10wt% α-Al 2 o 3 Micropowder, 8~10wt% of pure calcium aluminate cement, 4~5wt% of silicon carbide fine powder, 2~3wt% of elemental silicon powder; plus 1~1.5wt% of the raw material stainless steel fiber and 0.1~ 0.15wt% polycarboxylate water reducer.

[0016] The preparation method of this example is: according to the raw materials and their percentages, first prepare the plate-shaped corundum fine powder, α-Al 2 o 3 Micropowder, pure calcium aluminate cement, silicon carbide fine powder, elemental silicon powder, stainless steel fiber and polycarboxylate water reducer are mixed for 3 to 5 minutes to make premixed powder; then plate-shaped corundum particles and silicon carbide Mix the granules for 3~5 minutes, pour into...

Embodiment 2

[0019] A prefabricated part for a cement kiln coal injection nozzle and a preparation method thereof. The raw materials and their percentages are: 55~60wt% tabular alumina particles, 5~8wt% silicon carbide particles, 7~8wt% tabular corundum fine powder, 8~10wt% α-Al 2 o 3 Micropowder, 10~15wt% pure calcium aluminate cement, 3~4wt% silicon carbide fine powder, 3~4wt% elemental silicon powder; plus 1.5~2wt% stainless steel fiber and 0.15~0.2wt% raw material wt% polycarboxylate water reducer.

[0020] The preparation method of this embodiment is: except that the final temperature is raised to 1300~1400°C, the others are the same as in Example 1.

[0021] The normal temperature compressive strength of the preform prepared in this example is 125~146MPa, the room temperature flexural strength is 17~23MPa, the thermal shock stability is good, and the corrosion resistance to alkali, chlorine and sulfur atmosphere is excellent.

Embodiment 3

[0023] A prefabricated part for a cement kiln coal injection nozzle and a preparation method thereof. The raw materials and their percentages are: 60~65wt% tabular alumina particles, 5~8wt% silicon carbide particles, 6~8wt% tabular corundum fine powder, 5~9wt% α-Al 2 o 3 Micropowder, 8~10wt% pure calcium aluminate cement, 3~4wt% silicon carbide fine powder, 2~3wt% elemental silicon powder; plus 1.5~2wt% stainless steel fiber and 0.15~0.2 wt% polycarboxylate water reducer.

[0024] The preparation method of this embodiment is: except that the final temperature is raised to 1400~1500°C, the others are the same as in Example 1.

[0025] The normal temperature compressive strength of the prefabricated part prepared in this example is 138~149MPa, the room temperature flexural strength is 20~24MPa, the thermal shock stability is good, and the corrosion resistance of alkali, chlorine and sulfur atmosphere is excellent.

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Abstract

The invention relates to a prefabticated member for a coal nozzle of a cement kiln and a preparation method thereof. The prefabticated member is prepared from the following raw materials in percentage by weight: 55 to 70 percent of plate type corundum particle, 5 to 10 percent of silicon carbide particle, 5 to 8 percent of corundum fine powder, 5 to 10 percent of alpha-Al2O3 micro powder, 8 to 15 percent of pure calcium aluminate cement, 3 to 5 percent of silicon carbide fine powder, 2 to 4 percent of simple substance silicon powder, 1 to 2 percent of stainless steel fiber and 0.1 to 0.2 percent of polycarboxylate water reducing agent. The preparation method comprises the following steps of: mixing the corundum fine powder, the alpha-Al2O3 micro powder, the pure calcium aluminate cement, the silicon carbide fine powder, the simple substance silicon powder, the stainless steel fiber and the polycarboxylate water reducing agent; mixing the plate type corundum particle and the silicon carbide particle, and mixing together; adding 5-6wt% of water, uniformly mixing, forming and drying; and raising the temperature to 1,200-1,500 DEG C, and performing heat preservation for 2 to 4 hours. The process is simple; the intensity of a product is high; the thermal shock stability is high; the erosion resistance is excellent; and the abrasion resistance is good.

Description

technical field [0001] The invention belongs to the technical field of refractory materials for kiln burners, and in particular relates to a prefabricated part for a cement kiln coal injection nozzle and a preparation method thereof. Background technique [0002] The refractories for coal injection nozzles in cement kilns are one of the key factors to ensure the normal operation of cement kilns. At present, the service time is generally 3 to 4 months, and the service conditions are becoming more and more harsh. Generally, the damage methods of castables for coal injection nozzles mainly include: the radiant heat of the cement kiln during use and the thermal shock caused by the cold air used to cool the parts cause cracks and peeling of the material; Volatilization and condensation cause cyclic enrichment and intensify the erosion of refractory materials used for coal injection nozzles; during the production process, hot steam and cement dust cause wear and erosion of coal in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66F23D1/00
Inventor 李亚伟廖宁桑绍柏范泳常庆明罗会信
Owner WUHAN UNIV OF SCI & TECH
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