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Fluorescence labeling tracer and preparation method thereof

A fluorescent labeling and tracer technology, applied in fluorescence/phosphorescence, chemical instruments and methods, luminescent materials, etc., can solve the problems of difficult to greatly increase the concentration ratio, system corrosion, complex instruments, etc., and achieve less sample requirements. , easy to accept the environment, high sensitivity effect

Inactive Publication Date: 2012-07-04
SHANGHAI RUIJING ENVIRONMENT TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the concentration ratio of the system is increased or the load is reduced and the dosing amount needs to be reduced, it cannot be automatically reduced, resulting in excessive dosing and waste of medicine
Conversely, when the concentration ratio decreases or the load increases, the discharge increases, and the dose needs to be increased. However, when the amount of the dose should be increased, artificial or conventional mechanical dosing remains unchanged, which often makes the system insufficient. causing system corrosion or fouling
Secondly, even if the metering pump is used to adjust the dosing amount and dosing continuously, due to the hysteresis of the adjustment after detection, when there is a sudden change in the system, such as the increase in the sewage discharge due to the leakage of the system process medium or the addition of water Reduction, the chemical concentration in the system will decrease or increase correspondingly, which will inevitably lead to an increase in scaling or corrosion or a waste of chemical agents
And because the components and inspection methods of various corrosion and scale inhibitors in different circulating cooling water systems are different, more complicated and expensive instruments are required, plus the degradation or decomposition of chemicals, changes in water volume, and interference and error
It makes it difficult to implement the online monitoring of the effective concentration of the medicament, the automatic replenishment of the dosing is useless, and the level of process operation management is difficult to improve. The dosing of most domestic factories is basically in an impact type, which seriously affects the effect of water treatment. Difficult to greatly improve

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] 1.1 Synthesis of acrylic acid-acrylamide copolymer matrix

[0020] Add 120 g (109 mL) of isopropanol to a 1000 mL four-necked flask equipped with a stirrer, dropping funnel, condenser and thermometer. Add acrylic acid 116g (109ml) + acrylamide (38.3g) + 92g water to the dropping bottle. Stir and heat up to 80±2°C. 0.15 g sodium sulfite and 5 g water were added. Add 1 / 3 (9.24g potassium persulfate + 130g water) to the flask. Raise the temperature to 80±2°C, and reflux for about 0.5h. Add the remaining agents in ② and ④ dropwise. It will be finished in about 1 to 1.5 hours. Raise the temperature to 85°C, reflux and keep stirring for about 0.5 to 1 hour. Distill, distill off isopropanol and add a corresponding amount of pure water to obtain the matrix of acrylic acid-acrylamide copolymer.

[0021] 1.2 Synthesis of fluorescent tracers

[0022] Put the acrylic acid-acrylamide copolymer matrix and sodium p-aminobenzenesulfonate into a high-pressure reactor, and react a...

Embodiment 2

[0027] Using 4PPM acrylic acid-acrylamide copolymer (sample 1) and 4PPM sodium p-aminobenzenesulfonate-acrylic acid-acrylamide copolymer (sample 2), the scale inhibition performance test was carried out as follows, and the results are shown in Table 2.

[0028] 2.1 Test principle

[0029] Add the scale inhibitor to be evaluated according to the aqueous solution with a calcium carbonate concentration of 300PPM at the end of the test without adding scale inhibitor, and after standing at constant temperature for 16 hours, analyze and measure the calcium content in the supernatant by EDTA method. To evaluate the antiscalant performance of antiscalant.

[0030] 2.2 test solution

[0031] ① Calcium salt preparation solution: use reagent grade anhydrous calcium chloride to prepare an aqueous solution containing calcium chloride 16.65g / l, and the solution contains Ca15.0mg / ml. (calculated as calcium carbonate).

[0032] ② Carbonate preparation solution: use reagent grade anhydrous s...

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PUM

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Abstract

The invention relates to a fluorescence labeling tracer and a preparation method thereof. The fluorescence labeling tracer is a product which is obtained by reacting a polymer of acrylic acid-hydroxy-propyl acrylate copolymer or acrylic acid-acrylamide copolymer and an organic fluorescence derivating agent of L-tryptophan, tyrosine, sulfanilic acid or sodium sulfanilate. The fluorescence labeling tracer is high in sensitivity and selectivity. When used for detecting the concentration of a water treatment agent in an industrial water system, the fluorescence labeling tracer is quick and convenient, and high in repeatability, samples can be taken easily, the required amount of samples is small, and the fluorescence labeling tracer can be used for directly and continuously detecting the running condition of a circulating water system.

Description

technical field [0001] The invention relates to a tracer, in particular to a fluorescent label tracer and a preparation method thereof. Background technique [0002] When the circulating cooling water system is in operation, various substances will be deposited on the surface of the heat exchange tubes, and these substances are collectively referred to as deposits. When anti-corrosion measures are not taken properly, rust tumors often adhere to the surface of the heat exchange tube of the heat exchanger. The deposits formed by these rust-like corrosion products, in addition to affecting heat transfer, will more seriously promote the reproduction of certain bacteria, and eventually lead to corrosion and perforation of the pipe wall and leakage. [0003] In order to solve these problems, a series of water treatment chemicals are usually added to eliminate or slow down the harm caused by corrosion, scaling, sludge and microorganisms, etc., so as to ensure the stable and reliab...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K11/06C08F220/06C08F220/56C08F220/28C08F8/34G01N21/64
Inventor 魏能姜
Owner SHANGHAI RUIJING ENVIRONMENT TECH DEV
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