Fluorescence labeling tracer and preparation method thereof
A fluorescent labeling and tracer technology, applied in fluorescence/phosphorescence, chemical instruments and methods, luminescent materials, etc., can solve the problems of difficult to greatly increase the concentration ratio, system corrosion, complex instruments, etc., and achieve less sample requirements. , easy to accept the environment, high sensitivity effect
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Embodiment 1
[0019] 1.1 Synthesis of acrylic acid-acrylamide copolymer matrix
[0020] Add 120 g (109 mL) of isopropanol to a 1000 mL four-necked flask equipped with a stirrer, dropping funnel, condenser and thermometer. Add acrylic acid 116g (109ml) + acrylamide (38.3g) + 92g water to the dropping bottle. Stir and heat up to 80±2°C. 0.15 g sodium sulfite and 5 g water were added. Add 1 / 3 (9.24g potassium persulfate + 130g water) to the flask. Raise the temperature to 80±2°C, and reflux for about 0.5h. Add the remaining agents in ② and ④ dropwise. It will be finished in about 1 to 1.5 hours. Raise the temperature to 85°C, reflux and keep stirring for about 0.5 to 1 hour. Distill, distill off isopropanol and add a corresponding amount of pure water to obtain the matrix of acrylic acid-acrylamide copolymer.
[0021] 1.2 Synthesis of fluorescent tracers
[0022] Put the acrylic acid-acrylamide copolymer matrix and sodium p-aminobenzenesulfonate into a high-pressure reactor, and react a...
Embodiment 2
[0027] Using 4PPM acrylic acid-acrylamide copolymer (sample 1) and 4PPM sodium p-aminobenzenesulfonate-acrylic acid-acrylamide copolymer (sample 2), the scale inhibition performance test was carried out as follows, and the results are shown in Table 2.
[0028] 2.1 Test principle
[0029] Add the scale inhibitor to be evaluated according to the aqueous solution with a calcium carbonate concentration of 300PPM at the end of the test without adding scale inhibitor, and after standing at constant temperature for 16 hours, analyze and measure the calcium content in the supernatant by EDTA method. To evaluate the antiscalant performance of antiscalant.
[0030] 2.2 test solution
[0031] ① Calcium salt preparation solution: use reagent grade anhydrous calcium chloride to prepare an aqueous solution containing calcium chloride 16.65g / l, and the solution contains Ca15.0mg / ml. (calculated as calcium carbonate).
[0032] ② Carbonate preparation solution: use reagent grade anhydrous s...
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