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Preparation method for polyester fiber with compound ultraviolet ray resisting, aging resisting, moisture absorbing and quick drying functions

An anti-ultraviolet, moisture-absorbing and quick-drying technology, applied in the direction of one-component polyester rayon, can solve the problems of poor anti-ultraviolet performance, easy to generate static electricity, need to be improved, etc., achieve good dispersion effect, reduce volatilization, and reduce residence time effect of time

Active Publication Date: 2012-05-09
JIANGSU GUOWANG HIGH TECH FIBER CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, compared with various natural fibers, polyester fiber still has many shortcomings: hard hand feeling, poor hygroscopicity, poor UV resistance, easy to generate static electricity, easy to pilling, difficult to dye, etc.
The disadvantage of this method is: benzotriazole is an organic phenolic compound, which exists as a protonic acid under high temperature conditions, which can destroy the inorganic nano-powder TiO 2 and Al 2 o 3 or SiO 2 Surface organic treatment agent, leading to the agglomeration of inorganic nanopowders in the pre-aggregation process
[0008] In summary, the existing technologies mainly rely on the huge specific surface area of ​​inorganic nanopowders to diffusely scatter ultraviolet rays to produce an anti-ultraviolet effect. The stability and efficiency of the anti-ultraviolet effect need to be improved, which requires an anti-ultraviolet mechanism Start to prepare polyester with better UV resistance and good spinnability

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Preparation method for polyester fiber with compound ultraviolet ray resisting, aging resisting, moisture absorbing and quick drying functions
  • Preparation method for polyester fiber with compound ultraviolet ray resisting, aging resisting, moisture absorbing and quick drying functions
  • Preparation method for polyester fiber with compound ultraviolet ray resisting, aging resisting, moisture absorbing and quick drying functions

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] This embodiment provides a method for preparing an anti-ultraviolet, anti-aging polyester chip, which comprises the following steps:

[0032] (1), Esterification process: Take 18kg of purified terephthalic acid (PTA), 0.45kg of isophthalic acid, 0.05kg of neopentyl glycol, and 7.05kg of ethylene glycol (EG) into a 70-liter esterification reaction kettle , after stirring evenly, start to heat up and pressurize to 0.3Mpa to carry out esterification. The esterification temperature is controlled at 250°C-265°C.

[0033] (2), polymerization reaction process: after esterification is finished, at first add titanium dioxide matting agent, add-on is 1.5% of polyester chip weight, then add polymerization catalyst, and add 1.125g composite light stabilizer (Tinuvin 788 and 119FL mixed in a weight ratio of 1:1), 3.375g of composite antioxidant (Irganox 1076 and Irganox 1010 mixed in a weight ratio of 1:3). After stirring evenly, send it to the pre-polymerization tank to heat up a...

Embodiment 2

[0035] This embodiment provides a method for preparing an anti-ultraviolet, anti-aging polyester chip, which comprises the following steps:

[0036] (1), esterification reaction process: get 18kg purified terephthalic acid (PTA), 0.45kg1,4-cyclohexanedicarboxylic acid, 0.05kg neopentyl glycol, 7.05kg ethylene glycol (EG) and add 70 liters of ester After stirring evenly in the reaction kettle, start to heat up and pressurize to 0.3Mpa to carry out esterification. The esterification temperature is controlled at 250°C to 265°C. After the esterification is completed, return to normal pressure and complete the reaction to obtain polymerized monomers.

[0037] (2), polymerization reaction process: after esterification is finished, at first add titanium dioxide matting agent, add-on is 1.5% of polyester chip weight, then add polymerization catalyst, and add 1.125g composite light stabilizer (Tinuvin 788 and 119FL mixed in a weight ratio of 1:1), 3.375g of composite antioxidant (Irga...

Embodiment 3

[0039] This embodiment provides a method for preparing an anti-ultraviolet, anti-aging polyester chip, which comprises the following steps:

[0040] (1), esterification reaction process: get 18kg purified terephthalic acid (PTA), 0.45kg isophthalic acid, 0.05kg neopentyl glycol, 7.05kg ethylene glycol (EG) add 70 liters of esterification reactors, After stirring evenly, start to raise the temperature and pressurize to 0.3Mpa to carry out esterification. The esterification temperature is controlled at 250°C to 265°C. After the esterification is completed, return to normal pressure and complete the reaction to obtain polymerized monomers.

[0041](2), polymerization reaction process: after esterification is finished, at first add titanium dioxide matting agent, add-on is 1.5% of polyester chip weight, then add polymerization catalyst, and add 1.125g composite light stabilizer (Tinuvin 788 and 119FL mixed in a weight ratio of 1:1), 3.375g of composite antioxidant (Irganox 1076 a...

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Abstract

The invention relates to a preparation method for a polyester fiber with compound ultraviolet ray resisting, aging resisting, moisture absorbing and quick drying functions. The method comprises an esterification reaction process, a polymerization reaction process and a spinning process in sequence, and comprises the following specific steps of: in an esterification reaction, introducing a third monomer with relatively large steric hindrance; after the esterification reaction and before a pre-polymerization reaction, adding titanium dioxide serving as a high-content delustering agent, a hindered amine light stabilizer and a hindered phenol antioxidant; after the pre-polymerization of polymerization reaction process and before final polymerization, adding an ultraviolet absorber; and beforethe spinning process, pre-crystallizing and drying polyester slices obtained in the polymerization reaction process, and designing a special-shaped section for the fiber. The polyester fiber obtainedby using the method has superior ultraviolet ray resisting, aging resisting, moisture absorbing and quick drying functions. As provided by testing, relevant technical indexes are that: the ultraviolet transmission is less than or equal to 5.0 percent, the wicking height is more than or equal to 120 millimeters, and the evaporation rate is more than or equal to 0.20g / hr after the polyester fiber is woven into a knitted fabric and a woven fabric.

Description

technical field [0001] The invention relates to a preparation method of polyester fiber, in particular to a preparation method of polyester fiber with anti-ultraviolet, anti-aging, moisture-absorbing and quick-drying composite functions. Background technique [0002] Since the advent of polyester fiber, it has been widely used in clothing textiles due to its good strength, excellent wrinkle resistance, drape performance and washable wearability. After decades of rapid development, PET polyester fiber has become the world's most It is the synthetic polyester variety with the largest output and widest application range. However, compared with various natural fibers, polyester fiber still has many shortcomings: hard hand feeling, poor hygroscopicity, poor UV resistance, easy to generate static electricity, easy to pilling, difficult to dye, etc. Although natural fibers such as cotton, silk, wool, hemp, etc. have good dyeing properties, fabrics have air permeability, good sweat...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/92C08G63/183C08G63/181C08G63/18C08G63/78C08K3/22
Inventor 边树昌
Owner JIANGSU GUOWANG HIGH TECH FIBER CO LTD
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