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Water softener for low-pressure boiler and heat exchange system and use method thereof

A technology of heat exchange system and low-pressure boiler, which is applied in descaling and water softening, chemical instruments and methods, water/sludge/sewage treatment, etc. It can solve the problems of not having corrosion inhibition performance and not being suitable for boiler water softening treatment, etc. , to achieve the effect of accelerating the removal rate of calcium and magnesium, strong adaptability, and no secondary pollution

Inactive Publication Date: 2011-09-14
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The Chinese patent with the application number 95104277.7 discloses a new type of scale inhibitor and dispersant for water treatment. The disadvantage is that it does not have corrosion inhibition performance. To achieve scale and corrosion inhibition effects, it must be used in combination with other corrosion inhibitors; the application number is The Chinese patent of 200410043694.3 discloses the preparation method of super hard water resistant sodium / potassium humate, but the disadvantage is that it is not suitable for the softening treatment of boiler water; Water treatment method, using a combination of chemical and physical treatment, the disadvantage is the need for additional investment in equipment
At present, there is no water softener for low-pressure boilers and heat exchange systems that has the functions of scale inhibition, scale removal and corrosion inhibition in China.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0009] The central heating heat exchange system uses water in winter, and the terminal heat exchanger is composed of radiators made of various materials such as carbon steel and aluminum alloy. The medium-hard surface water with permanent hardness as the main source is used as the water source, and the main ion content in the raw water (g / m 3 ): Calcium ion 80~120, magnesium ion 50~70, sulfate ion 150~200, chloride ion 80~120, bicarbonate ion 20~50; the technical requirements for the system water: temperature 80~110℃, not required Calcium and magnesium are removed, and the inner wall of the system does not scale and does not corrode; the mass fraction of each component in the water softener is: phytic acid 300, potassium hydroxide 300, accelerator 25, and water 300; the preparation method of the water softener: first Dissolve phytic acid in water, then slowly add potassium hydroxide and accelerator under stirring condition, stir evenly and cool to room temperature to obtain wa...

Embodiment 2

[0011] Low-pressure hot water boiler and heat exchange system use water, and the system material is carbon steel. The medium-hard surface water with permanent hardness as the main source is used as the water source, and the main ion content in the raw water (g / m 3 ): Calcium ions 60-80, magnesium ions 30-50, sulfate ions 100-120, chloride ions 50-70; The removal rate is 30-40%, and the inner wall of the system does not scale and corrode; the mass fraction of each component in the water softener is: phytic acid 500, sodium hydroxide 550, sodium carbonate 100, potassium carbonate 120, sodium sulfite 120, Hydrazine 20, water 500; the preparation method of water softener: first dissolve phytic acid in water, then slowly add sodium hydroxide, sodium carbonate, potassium carbonate, sodium sulfite and hydrazine under stirring conditions, stir evenly and cool to Water softener can be obtained at room temperature; the amount of water softener added is 80-90g / m 3 Water, control the pH...

Embodiment 3

[0013] Low-pressure hot water boiler and heat exchange system use water, and the system material is carbon steel. The high hardness water with temporary hardness is used as the water source, and the main ion content in the raw water (g / m 3 ): Calcium ions 180-200, magnesium ions 60-70, bicarbonate ions 180-240, chloride ions 50-70; the technical requirements for the water used in the system: temperature 110-130°C, total removal rate of calcium and magnesium 80- 90%, the inner wall of the system does not scale and does not corrode; the mass fraction of each component in the water softener is: Phytic acid 400, Sodium hydroxide 140, Potassium hydroxide 220, Polyacrylamide 40, Sodium nitrite 180, Water 400 ; The preparation method of water softener: first dissolve phytic acid in water, then slowly add sodium hydroxide, potassium hydroxide, polyacrylamide and sodium nitrite under stirring conditions, stir evenly and cool to room temperature to obtain water softening agent; the amo...

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Abstract

The invention belongs to a water treatment technique, and relates to a water softener for a low-pressure boiler and a heat exchange system and a use method thereof. The softener is an aqueous solution consisting of phytic acid, caustic alkali, carbonate, a deoxidant, a flocculant and an accelerator and comprises the following components in mass fraction: 300-500 of phytic acid, 220-550 of caustic alkali, 0-300 of carbonate, 0-30 of accelerator, 0-50 of flocculant, 0-200 of deoxidant and 300-500 of water. The preparation method of the softener comprises the following steps: firstly dissolving the phytic acid in the water; then slowly adding the caustic alkali, the carbonate, the accelerator, the deoxidant and the flocculant while stirring; and stirring evenly and cooling to room temperature, so as to obtain the water softener. The adding amount of the softener is 30-100g / m<3> water, and the pH of the water is controlled at 8.0-10.0. The water softener has descaling, antiscaling and corrosion-inhibiting functions and wide adaptability; and used raw materials have no secondary pollution on environment.

Description

technical field [0001] The invention belongs to water treatment technology, in particular to a water softener for low-pressure boilers and heat exchange systems and its application method. Background technique [0002] The hardness of hard water is divided into temporary hardness and permanent hardness. Temporary hardness is mainly caused by calcium bicarbonate or magnesium bicarbonate, while permanent hardness is caused by sulfate or chloride of calcium and magnesium. Although hard water does not cause direct harm to health, it can cause great harm or even danger in industry. It can easily lead to scaling in the heat exchange system, corrosion of base metal, and deterioration of steam quality, which directly affects the heat transfer effect of the boiler and heat exchange system. , reduce efficiency, and even cause a pipe burst accident in severe cases. In order to prevent fouling, salt accumulation and corrosion of the boiler and heat exchange system, the hardness of the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/10C02F5/12
Inventor 管从胜刘士明
Owner SHANDONG UNIV
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