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Manufacturing method of high-temperature resistant and corrosion-resistant polyphenyl thioether composite tube

A polyphenylene sulfide and composite pipe technology, which is applied in the direction of tubular objects, other household appliances, household appliances, etc., can solve the problem of affecting mechanical properties, reducing the bending impact strength and tensile strength of composite pipes made of polyphenylene sulfide composite materials, and the effect Unsatisfactory and other issues

Active Publication Date: 2010-12-15
德阳科吉高新材料有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the effect of using polyphenylene sulfide pure resin is not ideal, because the polyphenylene sulfide resin composite pipe produced at this process level is relatively fragile, which directly affects the mechanical properties
[0004] In Chinese patent application 200710027360.0, a manufacturing method of inserting composite pipes with polyamide compounds, inorganic fillers and polyphenylene sulfide (PPS) composite materials is introduced, the purpose of which is to use composite materials to extrude plastic composite pipes into inserts , so as to provide a polyphenylene sulfide composite pipe with good processing performance and high mechanical strength. Although it is easy to extrude after adding polyamide compounds and other filler materials, it reduces the polyphenylene sulfide composite material. The flexural impact strength and tensile strength of composite pipes have inherent defects in chemical corrosion resistance when used in chemical and petrochemical fields

Method used

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  • Manufacturing method of high-temperature resistant and corrosion-resistant polyphenyl thioether composite tube
  • Manufacturing method of high-temperature resistant and corrosion-resistant polyphenyl thioether composite tube
  • Manufacturing method of high-temperature resistant and corrosion-resistant polyphenyl thioether composite tube

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Polyphenylene sulfide resin, add 10% 0.1mm silicon carbide fiber, 0.5% N-stearyl lysine zinc salt, 3% KHT-108 compatibilizer, ETPU elastomer 10%wt mixed in a high-speed mixer 100% polyphenylene sulfide compound, the obtained polyphenylene sulfide resin premix is ​​mixed and extruded by a twin-screw extruder and introduced into a single-screw extruder, and the 3-layer basalt fiber and heated Modified aramid fiber III (that is, polyaramid containing aromatic heterocycle) fiber cloth and polyphenylene sulfide after stretching treatment are extruded through the tubular die of the head of the extruder. Gas-cooled and formed to obtain polyphenylene sulfide composite pipes. And the fiber cloth accounts for 30%wt of the polyphenylene sulfide premix. Cylindrical basalt fiber and modified aramid III (that is, polyaramid containing aromatic heterocycle) fiber cloth is made of 30% basalt long fiber and 70% modified aramid III (that is, containing aromatic heterocycle) Heterocycli...

Embodiment 2

[0029] Polyphenylene sulfide resin, add 11% 5 nanometer grade titanium dioxide, 0.7% N-stearyl lysine magnesium salt, 3.1% KHT-201 compatibilizer, ETPU elastomer 11%wt mixed in a high-speed mixer to 100% The polyphenylene sulfide compound, the obtained polyphenylene sulfide resin premix is ​​mixed and extruded by the twin-screw extruder and introduced into the single-screw extruder, and the 4-layer basalt fiber and the heat-stretching treatment The final modified aramid III (that is, polyaramid containing aromatic heterocycle) fiber cloth and polyphenylene sulfide composite melt extruder head extruded through a tubular die, and the drawn tube is cooled by helium at a temperature of -20°C Shaped to obtain a polyphenylene sulfide composite pipe. And the fiber cloth accounts for 31%wt of the polyphenylene sulfide premix. Cylindrical basalt fiber and modified aramid III (that is, polyaramid containing aromatic heterocycle) fiber cloth is made of 35% basalt long fiber and 65% modi...

Embodiment 3

[0032] Polyphenylene sulfide resin, add 13% of 0.2mm silicon carbide fiber, 1.1% N-stearyl lysine magnesium salt, 3% KHT-303 compatibilizer, ETPU elastomer 12%wt and mix it in a high-speed mixer 100% polyphenylene sulfide compound, the obtained polyphenylene sulfide resin premix is ​​mixed and extruded by a twin-screw extruder and introduced into a single-screw extruder, and the 5-layer basalt fiber and heated The modified aramid fiber III (that is, polyarylamide containing aromatic heterocycle) fiber cloth and polyphenylene sulfide composite melt extruder after stretching treatment is extruded through a tubular die, and the tube is drawn with helium at a temperature of -22°C. Gas-cooled and formed to obtain polyphenylene sulfide composite pipes. And the fiber cloth accounts for 35%wt of the polyphenylene sulfide premix. Cylindrical basalt fiber and modified aramid III (that is, polyaramid containing aromatic heterocycle) fiber cloth is made of 40% basalt long fiber and 60% m...

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Abstract

The invention discloses a manufacturing method of a high-temperature resistant and corrosion-resistant polyphenyl thioether composite tube. The manufacturing method comprises the following steps of: adding fillers such as a thermal stabilizer, an inorganic filler and the like into polyphenyl thioether resin, and then mixing the materials fully and uniformly in a high-speed stirring machine to obtain a polyphenyl thioether resin premix compound; mixing and extruding the premix compound through a first-stage twin-screw extruder and introducing the premix compound into a single-screw extruder; extruding 3 to 6 layers of a fiber cloth formed by mix-twisting knitting a cylindrical basalt fiber and modified aramid fiber III after thermal expansion and contraction and a polyphenyl thioether composite fusant out of a tubular die on the head section of the extruder by the single-screw extruder; and cooling a pull tube into the polyphenyl thioether composite tube. The polyphenyl thioether composite tube manufactured by the method has the advantages of high thermal denaturation stability, corrosion resistance and high air tightness, and can be widely used in the fields of chemical industry, petrochemical industry, water supply and sewerage works, special industries and the like.

Description

Technical field [0001] The invention belongs to the application field of special polymer materials Background technique [0002] Polyphenylene sulfide (PPS) has excellent thermal stability, excellent high temperature resistance, corrosion resistance, and a melting point of 285°C. PPS composite pellets have excellent injection molding performance and can be processed into various specifications and shapes. PPS materials or composite products are used in more demanding fields, and people are still pursuing the goal of exploring, discovering and applying PPS resins and PPS composite materials with better performance. [0003] In U.S. Patent NO: 5151235, a method for manufacturing polyphenylene sulfide composite pipes made of phenylene sulfide and diphenyl sulfide copolymer resin is introduced, the purpose of which is to improve the polyphenylene sulfide copolymer resin during extrusion molding. Thermal stability and toughness and surface finish of molded materials. However, t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C47/06B29K81/00B29L23/00
Inventor 陈逊
Owner 德阳科吉高新材料有限责任公司
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