Biomass fuel oil and preparation method thereof
A fuel oil and biomass technology, applied in the field of biomass fuel oil and its preparation, can solve the problems of difficult source of biodiesel raw materials, large investment in equipment, complicated process, etc., and achieve the effects of low cost, low reaction temperature and simple process
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Embodiment 1
[0025] Add 200 kilograms of Xanthania sorbifolium oil, 400 kilograms of bioethanol, and 150 kilograms of methyl tert-butyl ether in a reaction kettle with a reflux device, stir well, add 3 kilograms of potassium hydroxide-magnesium oxide solid alkali catalysts, continue stirring, Form a suspension, heat up to 50-70°C, reflux through the condenser, stir and react for 40-45 minutes, cool to room temperature, filter off the catalyst, then add 150 kg of biodiesel, 50 kg of mixed fatty acids, 40 kg of acetone, sulfuric acid 3 kilograms of cerium ammonium, 2 kilograms of isopropyl hydroperoxide, and 2 kilograms of poly(ethylene butylene succinimide), and the stirring reaction was continued for 20 to 30 minutes to obtain the biomass fuel oil. According to the experimental results, the combustion value is 10685 kcal / kg, the flash point is 63°C, and the wear spot diameter of HFRR test method is 440mm.
Embodiment 2
[0027] Add 500 kg of catering industry waste oil, 100 kg of bio-butanol, and 150 kg of diethoxymethane into a reaction kettle with a reflux device, stir evenly, add 10 kg of potassium carbonate-magnesia solid alkali catalyst, and continue stirring to form Suspension, heated to 50-70°C, refluxed through the condenser, stirred and reacted for 70-75 minutes, cooled to room temperature, filtered to remove the catalyst, and then added 115 kg of commercially available biodiesel, 5 kg of stearic acid, and 100 kg of petroleum ether kg, 10 kg of ferrocene, 5 kg of hydrogen peroxide, and 5 kg of tert-amylamine, and continue to stir and react for 20 to 30 minutes to obtain the biomass fuel oil. According to the experimental results, the combustion value is 10482 kcal / kg, the flash point is 61°C, and the wear spot diameter of HFRR test method is 430mm.
Embodiment 3
[0029]Add 396 kg of catering industry waste oil, 400 kg of methanol, and 50 kg of methyl tert-butyl ether into a reaction kettle with a reflux device, stir evenly, add 1 kg of potassium hydroxide-calcium oxide solid alkali catalyst, and continue stirring to form Suspension, heated up to 50-70°C, refluxed through the condenser, stirred for 20-25 minutes, cooled to room temperature, filtered to remove the catalyst, and then sequentially added 150 kg of commercially available biodiesel, 1 kg of ferrocene, isopropyl 1 kg of hydrogen peroxide and 1 kg of poly(ethylene butylene succinimide) were stirred and reacted for 20 to 30 minutes to obtain the biomass fuel oil. According to the experimental results, the combustion value is 10546 kcal / kg, the flash point is 62°C, and the wear spot diameter of HFRR test method is 450mm.
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