The invention relates to a xanthenes organic compound and application thereof to OLED (Organic Light Emitting Diode). According to the structure of the compound, xanthenes are connected with a carbazole cyclic structure through carbon-carbon bonds. Due to carbon-carbon connection, the chemical stability of a material is improved, living position exposure of branch chain groups is avoided, and the whole molecules are of a relatively large rigid structure, and a high triplet state energy stage (T1) is achieved; in addition, large steric hindrance is achieved, rotation is not easily caused, and a relatively stable three-dimensional structure is achieved, so that the compound has relatively high glass transition temperature and molecular thermal stability; in addition, distribution positions of HOMO (Highest Occupied Molecular Orbital ) and LUMO (Lowest Unoccupied Molecular Orbital) of the compound provided by the invention are separated from each other, so that appropriate HOMO and LUMO energy grades are achieved; therefore, after the compound provided by the invention is applied to an OLED device, the light emission efficiency of the device is improved, and the service life of the device is prolonged.