Compounds taking xanthone as core and application of compounds
A compound, xanthone technology, applied in organic chemistry, chemical instruments and methods, electrical components, etc., can solve problems such as performance differences
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Embodiment 1
[0066] The synthesis of embodiment 1 compound 1:
[0067]
[0068] Add 0.01mol of intermediate D-1 and 0.012mol of raw material E-1 to 150mL of toluene:ethanol=2:1 mixed solvent, add 0.02mol of potassium carbonate, add 0.0002mol of Pd(PPh 3 ) 4 , reacted at 110°C for 24 hours under a nitrogen atmosphere, took a sample and spotted the plate, and after the reactants were completely reacted, cooled and filtered, the filtrate was rotary evaporated to remove the solvent, and the crude product was passed through a silica gel column to obtain compound 1; HPLC purity 98.86%, yield Yield 77.5%; element analysis structure (C 46 h 29 NO 3 ) Theoretical value: C, 85.83; H, 4.54; N, 2.18; Tested value: C, 85.84; H, 4.55; N, 2.19. HRMS (EI): theoretical value: 643.21, found value: 643.23.
[0069] Repeat the preparation process of Example 1 to synthesize the following target compounds; the reaction conditions are the same, except that intermediate D and raw material E listed in the ...
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