The invention belongs to the technical field of organic photoelectric materials, and particularly relates to
naphtha-five-membered ring-benzofused heterocycle organic compounds and application thereof. The organic compounds disclosed by the invention have a
parent structure of naphtho-five-membered ring-benzofused heterocycle, are high in interatomic
bond energy, present good
thermal stability, are beneficial for intermolecular
solid accumulation, and can be used as luminescent layer materials to effectively prolong the service life of materials. The compounds provided by the invention are derivatives of large conjugated fused heterocycles, are applied to light emitting
layers, have proper energy levels matched with adjacent
layers, facilitate injection of holes and electrons, can effectively reduce turn-on
voltage, and can realize good light emitting efficiency in a device due to a relatively high
exciton migration rate. The compounds disclosed by the invention have relatively large conjugate planes, are beneficial for molecular accumulation, show good thermodynamic stability and present long service life in devices. A preparation process of the derivatives is simple and feasible,raw materials are easy to obtain, and the derivatives are suitable for large-scale production.