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Explosive mixtures containing readily gasified additives

a technology of additives and explosive materials, which is applied in the direction of explosives, textiles and papermaking, looms, etc., can solve the problems of periodic generation of toxic gases, limited control of detonation velocity (vod), and significant operating expenses of explosive materials, so as to reduce nox formation, reduce the velocity of detonation, and reduce the effect of cos

Inactive Publication Date: 2011-05-19
FENWICK ANDREW E +3
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0004]The present invention provides an AN-based explosive mixture, for example an ANFO- and / or emulsion-based explosive mixture, which has been modified with the incorporation of a readily gasified carbonaceous additive material. The present mixture is characterized by lower velocity of detonation, provides performance results similar to traditional explosives (specifically cast and fragmentation), has the ability to reduce NOx formation, and is less expensive and less subject to pricing fluctuations than presently available explosive compositions.

Problems solved by technology

Although ANFO and emulsions represent the vast majority of all explosives utilized globally, they have technical limitations, including limited control over velocities of detonation (VOD), potential for severe ground vibrations, periodic generation of toxic gases (NOx), etc.
It should also be noted that these explosive materials represent a significant portion of operating expenses, and are subject to supply shortages and sporadic pricing.

Method used

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  • Explosive mixtures containing readily gasified additives
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  • Explosive mixtures containing readily gasified additives

Examples

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example

[0065]Explosive mixtures containing varying concentrations of ammonium nitrate, fuel oil, emulsion, and the previously described carbonaceous additive have been successfully tested. As an illustrative example, an independent engineering firm was commissioned to complete a comprehensive study examining the effects of this additive in ANFO relative to standard ANFO (94% ammonium nitrate prill and 6% fuel oil). The field assessment program included six production blasts—three trials with approximately 25% (24%, 28%, & 33%) of the carbonaceous additive and three shots using standard ANFO. The shots alternated between the claimed mixture and standard ANFO to produce pairs of blasts in an attempt to compare similar geologic conditions (strata, depth, etc.) within each pairing. Among other metrics, the claimed mixture and ANFO shots were compared based on the following:[0066]Velocity of Detonation (VOD, described in more detail below).[0067]Seismic output in the far field (ground vibration...

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Abstract

A readily gasified additive has been added to AN (ammonium nitrate) based bulk explosives (ANFO, emulsions, and combinations thereof) with positive results, due to the time, temperature, and pressure conditions generated in a blasthole. The preferred final explosive mixture is primarily comprised of AN, fuel oil, and a carbonaceous additive material that is characterized as being readily gasified as indicated by its rapid release of volatile materials and char formation, the high internal porosity and surface area of the base material and its char, and the uniform distribution of catalytic mineral matter throughout the material. It is understood that other readily gasified additives may be similarly effective.

Description

FIELD OF THE INVENTION[0001]The present invention relates generally the field of explosive compositions and methods of formulating same. More particularly, the present invention relates to the incorporation of a non-explosive, carbonaceous additive into explosives, with the additive behaving as more than a diluent or filler, but rather imparting beneficial properties to a blast.BACKGROUND OF THE INVENTION[0002]Blasting operations in mining conventionally use ANFO (a stoichiometric mix of Ammonium Nitrate and Fuel Oil), AN- (ammonium nitrate) based emulsions, or mixes thereof, as their bulk explosives. Although ANFO and emulsions represent the vast majority of all explosives utilized globally, they have technical limitations, including limited control over velocities of detonation (VOD), potential for severe ground vibrations, periodic generation of toxic gases (NOx), etc. It should also be noted that these explosive materials represent a significant portion of operating expenses, an...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C06B31/30C06B43/00
CPCC06B31/30C06B31/285
Inventor FENWICK, ANDREW E.WILZBACHER, DENNIS R.SCHIELE, MICHAEL L.HARMAN, JOHN C.
Owner FENWICK ANDREW E
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