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Methods for producing biodiesel

a biodiesel and biofuel technology, applied in biofuels, fatty acid chemical modification, fuels, etc., can solve the problems of destroying the carbon deposits of the engine, plant oil properties, animal oil properties, etc., and not being a direct replacement for petroleum diesel in the diesel engine of today

Inactive Publication Date: 2005-12-15
CARNEGIE MELLON UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0017]FIG. 9 shows a chart of an effect of velocity using a heterogeneous base catalyst.
[0018]FIG. 10 shows a chart of a microwave effect with heterogeneous base catalyst at 0.104 m/s and a 6:1 (molar) methanol to SBO feed rate.
[0019

Problems solved by technology

However, plant oil properties, as well as animal oil properties, are not sufficient to be a direct replacement for petroleum diesel in the diesel engines of today.
The oils' viscosities are too high and do not burn clean enough, leaving damaging carbon deposits on the engine.

Method used

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  • Methods for producing biodiesel
  • Methods for producing biodiesel
  • Methods for producing biodiesel

Examples

Experimental program
Comparison scheme
Effect test

example 1

Effect of Increasing Feed Velocity, with Fixed Bed Reactor, on Alkaline Heterogeneous Transesterification

[0094] A fixed bed reactor was set up to operate with microwave power as shown in FIG. 6. The illustrated system includes a cylinder, a high-shear gear pump, and a return line that maintain the reactants as a mixed emulsion. The reactants are maintained as an emulsion by passing the reactants through the high shear gear pump at ambient temperature and pressure and returning the emulsion to the holding cylinder.

[0095] A valve V2, a second pump, and a backpressure regulator control the flow rate of the emulsified reactants through the catalyst bed, contained in the microwave flow-through reactor system. The microwave generating system comprises a 0 through 25 Watt microwave source (Sairem, GMM.25.2450), power meter (Anritsu, ML2438A), BNC to WR284 waveguide adapter (Lectronic Research Labs), EH tuner (FXR Inc, S312B), dual directional coupler (Mac, 31145B-50), and associated micr...

example 2

Demonstration of Heterogeneous Transesterification

[0107] Using the CSB system described in FIG. 7, 10 cc of heterogeneous base catalyst, namely, sodium silicate catalyst was placed into the reactor. The feed was soybean oil mixed with methanol (Acros, UN1230) in a 6:1 molar ratio. A charge of 300 cc was used. The operating temperature was 60° C. and the pressure was 50 psig above autogeneous conditions. The velocity ranged from 0.26 and 0.31 m / s. 10 watts of microwave power (1 W / cc) was applied to the catalyst bed as the feed / product mixture flowed. After 30 minutes a sample was collected and centrifuged. The top layer was then analyzed using the GC.

[0108]FIG. 8 presents the GC plots of the feed soybean oil and the microwave process product, which is biodiesel. The GC indicated 100% conversion of the soybean oil triglycerides.

example 3

Effect of High Feed Velocity and Heterogeneous Catalyst on Heterogeneous Transesterification

[0109] Using the CSB system illustrated in FIG. 7, 10 cc of heterogeneous base catalyst (sodium silicate) was placed into the reactor. A 4:1 (molar) methanol to soybean oil (SBO) mixture feed was used. The operating temperature was 80° C.

[0110]FIG. 9 shows the TG conversion as a function of time. The graph shows that as the velocity increased from 0.052 m / s (Test 1) to 0.208 mi / s (Test 2), the rate of conversion increased. The TG conversion more than doubled from 45% at 0.052 m / s to 100% at 0.208 m / s at 30 minutes or a LHSV of 60. This data also demonstrates that, contrary to the prior art; lower methanol to SBO ratios can be used to obtain 100% conversion with a heterogeneous base catalyst.

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Abstract

Transesterification, esterification, and esterification-transesterification (both one-step and two-step) for producing biofuels. The process may be enhanced by one or more of the following: 1) applying microwave or RF energy; 2) passing reactants over a heterogeneous catalyst at sufficiently high velocity to achieve high shear conditions; 3) emulsifying reactants with a homogeneous catalyst; or 4) maintaining the reaction at a pressure at or above autogeneous pressure. Enhanced processes using one or more of these steps can result in higher process rates, higher conversion levels, or both.

Description

BACKGROUND OF THE INVENTION [0001] The use of plant oils for transportation fuel has been known for over 100 years with the use of peanut oil to power the first diesel engines. However, plant oil properties, as well as animal oil properties, are not sufficient to be a direct replacement for petroleum diesel in the diesel engines of today. The oils' viscosities are too high and do not burn clean enough, leaving damaging carbon deposits on the engine. As a result, transesterification and esterification of plant oils have been used to produce a less viscous fuel referred to as biodiesel fuel. [0002] Significant improvements have been made over the years to the transesterification and esterification processes. However, enhancements and improvements to increase yield and reduce reaction time over existing biodiesel transesterification and esterification techniques are desired. SUMMARY OF THE INVENTION [0003] In one aspect, the invention may provide a method of converting feedstock having...

Claims

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Application Information

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IPC IPC(8): C10L1/02C10L5/00C11C3/00C11C3/10
CPCC07C67/08C10L1/026C11C3/003C11C3/10Y02E50/13C07C69/24C07C69/52Y02E50/10C07C67/03C11C3/00C10L1/02
Inventor PORTNOFF, MARC A.PURTA, DAVID A.NASTA, MARGARET A.ZHANG, JINGFENGPOURARIAN, FAIZ
Owner CARNEGIE MELLON UNIV
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