Functional fiber having photocatalyst activity and fiber structure containing the same
A technology of functional fibers and photocatalysts, applied in the field of antifouling fiber structures and deodorizing fiber structures, can solve the problems of the processing stage, the difficulty of the spinning processability of porous fibers and other problems, and achieve the goal of inhibiting adhesion, Excellent workability
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Embodiment A1
[0094]Spinning dope (AI) containing acrylonitrile copolymer containing acrylonitrile, methyl acrylate, and sodium methallyl sulfonate with an acrylonitrile content of 90% by weight and acrylonitrile, methyl acrylate, Allyl sodium sulfonate has an acrylonitrile content of 88% by weight and a spinning stock solution (AII) containing an acrylonitrile copolymer and titanium oxide particles (TK522 manufactured by Teika Co., Ltd.) with an average primary particle diameter of 15 nm at a ratio of 1:1. Proportionally supply ISG Mixer (theoretical stock solution layer number is 432) for multilayer mixing to make wet spinning yarn. Here, a sodium thiocyanate aqueous solution was used as a solvent for the acrylonitrile-based copolymer. In addition, titanium oxide fine particles were adjusted to be 5% by weight relative to 100 parts by weight of the acrylonitrile polymer in the spinning stock solution (AII).
[0095] As the coagulation liquid, a 12% by weight aqueous solution of sodium th...
Embodiment A2
[0110] A functional fiber for evaluation was obtained in the same manner as in Example A1 except that sodium thiocyanate at a concentration of 12% by weight at 5° C. was used as the coagulation solution.
Embodiment A3
[0112] A functional fiber for evaluation was obtained in the same manner as in Example A1, except that titanium oxide microparticles (Titanium Oxide AMT100 manufactured by Teika Co., Ltd.) with an average primary particle diameter of 5 nm was used instead of titanium oxide TK522 manufactured by Teika Co., Ltd. used in Example A1. .
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Abstract
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