Germanium-free silicate waveguide composition for enhanced-L-band and S-band emission and method for its manufacture
A waveguide, silicon oxide technology, applied in glass manufacturing equipment, manufacturing tools, glass molding, etc., can solve the problems of non-silicate glass not easy to fiberize, not easy to transmit optical fiber splicing, and commercial application restrictions.
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[0069] Example 1 is used to extend the L-band, containing three kinds of substrates with four kinds of Er / Tm ratios
[0070] Erbium-thulium co-doped silicate glass beads were prepared with three types of substrates and four contents of Er / Tm. To prepare, combine in a vessel 2.16M partially hydrolyzed silica stock solution, 1.0M aluminum chloride hydrate in methanol, 0.5M lanthanum nitrate hydrate in methanol, 0.1M erbium chloride hydrate in methanol, and 0.1M Thulium nitrate hydrate in methanol. Each reagent was stirred, and the resulting solution produced a gel with the composition (mol%) shown in Table 1.
[0071] sample
Er / Tm
SiO 2
AlO 1.5
LaO 1.5
ErO 1.5
TmO 1.5
1
10 / 20
92.86
6.14
0.55
0.15
0.03
2
10 / 2
92.96
6.04
0.82
0.15
0.30
3
3 / 20
92.90
6.10
0.65
0.045
0.03
4
3 / 2
93.01
...
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