Oil-resistant anti-corrosion PVC (polyvinyl chloride) cable material and preparation method thereof

An anti-corrosion and cable material technology, applied in the direction of insulating cables, cables, circuits, etc., can solve the problems of easy short circuit leakage, fire, easy aging, etc., and achieve good aging resistance, low production cost, and good oil resistance.

Inactive Publication Date: 2022-05-27
昆山德斯源机电设备有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Cables for locomotives and vehicles have been working in harsh environments such as high temperature and oil pollution for a long time. The problems of traditional cable materials such as corrosion, aging, short-circuit leakage and fire in oil pollution have become increasingly prominent, resulting in an increasingly urgent demand for high-performance cable materials. Therefore, research In addition to meeting the most basic flame retardancy and electrical properties, a cable material that must also have good mechanical properties, oil resistance and corrosion resistance has very important practical significance

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  • Oil-resistant anti-corrosion PVC (polyvinyl chloride) cable material and preparation method thereof
  • Oil-resistant anti-corrosion PVC (polyvinyl chloride) cable material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0047] An oil-resistant and anti-corrosion PVC cable material is composed of the following raw materials in parts by weight:

[0048] 85 parts by weight of PVC resin, 26 parts by weight of nitrile rubber, 3 parts by weight of butyl stearate, 2 parts by weight of lanthanum cyanurate, 44 parts by weight of plasticizer, 5 parts by weight of tris(2-chloroethyl) phosphate , 35 parts by weight filler.

[0049] The plasticizer is acetyl tributyl citrate.

[0050] The filler is calcined clay.

[0051] The nitrile rubber is solid nitrile rubber.

[0052] The preparation method of the solid nitrile rubber is as follows: the nitrile latex is added to a 20wt% calcium chloride aqueous solution, stirred for 20 min at a rotating speed of 1500 rpm, and the precipitate is taken out and freeze-dried to obtain the solid nitrile rubber; wherein the nitrile latex and The mass ratio of the 20wt% calcium chloride aqueous solution is 10:3.

[0053] The preparation method of the oil-resistant and ...

Embodiment 2

[0058] An oil-resistant and anti-corrosion PVC cable material is composed of the following raw materials in parts by weight:

[0059] 85 parts by weight of PVC resin, 26 parts by weight of nitrile rubber, 3 parts by weight of butyl stearate, 2 parts by weight of lanthanum cyanurate, 44 parts by weight of plasticizer, 5 parts by weight of tris(2-chloroethyl) phosphate , 35 parts by weight filler.

[0060] The plasticizer is acetyl tributyl citrate.

[0061] The filler is calcined clay.

[0062] The nitrile rubber is modified nitrile rubber.

[0063] The preparation method of the modified nitrile rubber is as follows:

[0064] 28 parts by weight of nitrile latex was added to 200 parts by weight of dichloromethane, stirred at 800 rpm and condensed and refluxed at 40°C for 3 hours, and then added 50 parts by weight of absolute ethanol, 7 parts by weight of hydroxylamine hydrochloride and 20 parts by weight of 50 parts by weight of anhydrous ethanol, 7 parts by weight of hydrox...

Embodiment 3

[0070] An oil-resistant and anti-corrosion PVC cable material is composed of the following raw materials in parts by weight:

[0071] 85 parts by weight of PVC resin, 26 parts by weight of nitrile rubber, 3 parts by weight of butyl stearate, 2 parts by weight of lanthanum cyanurate, 44 parts by weight of plasticizer, 5 parts by weight of tris(2-chloroethyl) phosphate , 35 parts by weight filler.

[0072] The plasticizer is acetyl tributyl citrate.

[0073] The filler is calcined clay.

[0074] The nitrile rubber is graft-modified nitrile rubber.

[0075] The preparation method of described graft-modified nitrile rubber is as follows:

[0076] S1, adding 28 parts by weight of nitrile latex to 200 parts by weight of methylene chloride, stirring at a rotating speed of 800 rpm and condensing and refluxing at 40 ° C for 3h, then adding 50 parts by weight of absolute ethanol, 7 parts by weight of hydroxylamine hydrochloride and 20 parts by weight of sodium carbonate, continue to...

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Abstract

The invention discloses an oil-resistant anti-corrosion PVC (polyvinyl chloride) cable material and a preparation method thereof. The oil-resistant anti-corrosion PVC cable material is prepared from the following raw materials in parts by weight: 85 parts of PVC resin, 10-35 parts of nitrile rubber, 2-5 parts of butyl stearate, 1-3 parts of lanthanum cyanurate, 30-50 parts of plasticizer, 3-8 parts of tris (2-chloroethyl) phosphate and 20-40 parts of filler. The raw materials are simple, the production cost is low, and the prepared oil-resistant and corrosion-resistant PVC cable material not only has good oil-resistant and corrosion-resistant performance, but also is excellent in mechanical performance and good in aging resistance, and can meet the requirements of cable materials in different use environments.

Description

technical field [0001] The invention relates to the technical field of cable material preparation, in particular to an oil-resistant and anti-corrosion PVC cable material and a preparation method thereof. Background technique [0002] PVC is a high molecular polymer obtained from vinyl chloride (VC) monomer through free radical addition polymerization. PVC and its products have many excellent properties, not only low price, mature processing technology, acid and alkali resistance, chemical resistance, wear resistance, but also high strength, good flame retardancy, electrical insulation and good transparency. It is used in many fields, such as profiles, films, flexible products and packaging materials. [0003] The common internal structure of cables includes core wire, insulating layer, shielding layer and sheath layer, among which the insulating layer and sheath layer are mostly PVC products. The formulation of PVC cable material contains a variety of ingredients, in addi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L9/02H01B7/28H01B7/02H01B3/44H01B3/28
CPCC08L27/06H01B7/2806H01B7/28H01B7/02H01B3/441H01B3/28C08L2203/202C08L9/02Y02A30/14
Inventor 胡素琼
Owner 昆山德斯源机电设备有限公司
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