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Silicon micropowder dispersing agent based on carboxylic acid monomer

A technology of carboxylic acid monomer and silicon micropowder, which is applied in the directions of transportation and packaging, dissolution, chemical instruments and methods, etc., can solve the problems of difficult dispersion and uniformity, and achieve uniform dispersant powder, good dispersion effect, and reduce the possibility of Effect

Pending Publication Date: 2022-04-15
WUHAN UNIV OF SCI & TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, it is difficult for microsilica powder to disperse evenly in the solution in practical applications. The morphology and surface structure of microsilica powder are related to many factors such as its internal structure, impurities, surface adsorption and chemical reaction, preparation process, and environmental conditions, which lead to the complexity and diversity of powder agglomeration and dispersion mechanisms.
There are few domestic records of dispersants for microsilica powder, therefore, it is necessary to develop a dispersant that solves the above problems

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] This embodiment provides a silicon micropowder dispersant based on carboxylic acid monomers. The dispersant components are: the carboxylic acid monomer is methacrylic acid, and the polyurethane-modified acrylate is monomethyl polyether (molecular weight: 1000-5000 ), polyethylene glycol (molecular weight 100-500), hydroxyethyl acrylate and TDi are polymerized according to the molar ratio of 1:1:2:8, and the long-chain monomer is composed of PEG (molecular weight 3500) and Mpeg- MAA (molecular weight 5000) is mixed according to the molar ratio of 4:1, and the sacrificial monomer is composed of 2-(trimethylsilylmethyl)allyl acetate and 3-(methacryloyloxy)propyltrimethoxy silane is mixed according to the molar ratio of 1:1, the molecular weight control agent is a mixture of 2-acrylamide-2-methylpropanesulfonic acid and mercaptoacetic acid, and the initiator is composed of potassium persulfate and AIBN according to the mass ratio of 3:1 Mixed, the slow-release powder has a ...

Embodiment 2

[0028] This embodiment provides a silicon micropowder dispersant based on carboxylic acid monomers, the dispersant components are: the carboxylic acid monomer is a mixture of maleic anhydride and fumaleic acid, and the polyurethane modified acrylate is monomethyl poly Ether (molecular weight 1000-5000), polyethylene glycol (molecular weight 100-500), hydroxyethyl acrylate and TDi are polymerized according to the molar ratio of 3:1:5:8, and the long-chain monomer is composed of PEG ( The molecular weight is 3500) and Mpeg-MAA (molecular weight is 5000) are mixed according to the molar ratio of 4:1, and the sacrificial monomer is composed of trimethylsilyl acrylate and 3-(methacryloyloxy)propyltrimethoxysilane It is mixed according to the molar ratio of 1:1, the molecular weight control agent is acrylic acid-1,3-sultone, the initiator is mixed with potassium persulfate and AIBN according to the mass ratio of 3:1, and the slow-release powder is Specific surface area 300m 2 / g of...

Embodiment 3

[0034] This embodiment provides a kind of silicon micropowder dispersant based on carboxylic acid monomer, and dispersant component is: carboxylic acid monomer is the mixture of methacrylic acid and acrylic acid, polyurethane modified acrylate is monomethyl polyether (molecular weight 1000-5000), polyethylene glycol (molecular weight 100-500), hydroxyethyl acrylate and TDi are polymerized according to the molar ratio of 2:1:3:8, and the long-chain monomer is composed of PEG (molecular weight 3500 ) and Mpeg-MAA (molecular weight of 5000) are mixed according to the molar ratio of 4:1, and the sacrificial monomer is composed of trimethylsilyl acrylate and 2-(trimethylsilyl) allyl acetate according to 1 :1 molar ratio, the molecular weight control agent is a mixture of acrylic acid-1,3-sultone and thioglycolic acid, the initiator is mixed with potassium persulfate and AIBN according to the mass ratio of 3:1, slow release The powder has a specific surface area of ​​200m 2 / g of f...

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Abstract

The invention provides a silicon micropowder dispersing agent based on a carboxylic acid monomer. The silicon micropowder dispersing agent is prepared by the following steps: firstly, weighing the following components in parts by weight: 500-700 parts of carboxylic acid monomer, 20-50 parts of polyurethane modified acrylate, 50-100 parts of long-chain monomer, 100-200 parts of sacrificial monomer, 50-70 parts of water, 1-5 parts of molecular weight control agent, 0.5-1.5 parts of initiator and 300-500 parts of slow-release powder; the preparation method comprises the following steps: adding a carboxylic acid monomer, water and a long-chain monomer into a reaction kettle, heating and stirring, adding a polyurethane modified acrylate macromonomer, a sacrificial monomer, an initiator and a molecular weight control agent after stirring, continuously stirring and preserving heat, putting into a granulator after heat preservation is finished, adding the slow-release powder, and discharging after granulation is finished. The dispersing agent overcomes the defects in the prior art, and has the advantages of being convenient to use and good in dispersing effect for inorganic material slurry with the high silica powder content.

Description

technical field [0001] The invention belongs to the field of dispersants, in particular to a silicon micropowder dispersant based on carboxylic acid monomers. Background technique [0002] Silica powder, also known as silica fume or silicon dioxide superfine powder, is mainly composed of natural quartz (SiO 2 ) or fused silica (natural quartz melted at high temperature and cooled amorphous SiO 2 ) Micropowder processed by multiple processes such as crushing, ball milling (or vibration, jet milling), flotation, pickling purification, high-purity water treatment, etc. Silica powder has pure appearance, white color, and balanced particles. It is a non-toxic, odorless, and pollution-free inorganic non-metallic material. In general, silica powder has good temperature resistance, acid and alkali corrosion resistance, poor thermal conductivity, high insulation, and low temperature. Excellent properties such as expansion, stable chemical properties, and high hardness. Silica powd...

Claims

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Application Information

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IPC IPC(8): C08F283/00C08F220/06C08F230/08C08F220/58C08F222/06C08F222/02C08F220/38C09K23/54C09K23/34
Inventor 张意
Owner WUHAN UNIV OF SCI & TECH
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