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Bi-component halogen-free flame-retardant acrylate structural adhesive and preparation method thereof

An acrylate and acrylate technology, applied in the field of two-component halogen-free flame retardant acrylate structural adhesive and its preparation, can solve problems such as limitations, and achieve excellent flame retardant performance, good extrudability and thixotropy, and stability. Excellent effect

Pending Publication Date: 2021-10-19
南京博新新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, acrylate copolymers are flammable polymers composed of three elements: carbon, hydrogen, and oxygen, which are greatly limited in applications that need to meet flame retardant requirements.
[0003] Especially with the increasing demand for flame retardancy in shipbuilding and other fields, acrylic structural adhesive products need better flame retardancy while maintaining the original strength and toughness, which cannot be fully met by existing products.

Method used

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  • Bi-component halogen-free flame-retardant acrylate structural adhesive and preparation method thereof
  • Bi-component halogen-free flame-retardant acrylate structural adhesive and preparation method thereof
  • Bi-component halogen-free flame-retardant acrylate structural adhesive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] Example 1, a halogen-free flame-retardant acrylate structural adhesive, which is composed of two components A and B, and the volume ratio of the A and B components is 10:1.

[0047] The acrylic type monomer of component A is selected from methyl methacrylate, lauric acid methacrylate, and polyethylene glycol dimethacrylate; the halogen-free flame retardant is selected from tricumyl phosphate; The toughening agent is selected from MBS resin; the stabilizer is selected from hydroquinone and disodium edetate; the accelerator is selected from triphenylphosphine; the coupling agent is selected from gamma-glycidoxypropyl trisodium Methylsilane. The specific component contents are shown in Table 1.

[0048] Table 1

[0049] A component raw material Weight ratio Methyl methacrylate 20 Lauric acid methacrylate 20 polyethylene glycol dimethacrylate 20 tricumyl phosphate 20 MBS resin 15 Quinol 2.5 Disodium edetate 2.5 Tri...

Embodiment 2

[0058] Example 2, a halogen-free flame-retardant acrylate structural adhesive, which is composed of two components A and B, and the volume ratio of the A and B components is 10:1.

[0059] The acrylic monomers of component A are selected from acrylate stearate, isodecyl acrylate, and polyurethane acrylate; the halogen-free flame retardant is selected from cyclic phosphate; the toughening agent is selected from ABS resin; the stable The agent selects p-benzoquinone and tetrasodium edetate; the accelerator selects triethylamine; the coupling agent selects ν-aminopropyltriethoxysilane. The specific component contents are shown in Table 3.

[0060] table 3

[0061] A component raw material Weight ratio Acrylic Stearate 15 Isodecyl acrylate 15 urethane acrylate 15 Cyclic Phosphates 15 ABS resin 15 Benzoquinone 2 Tetrasodium EDTA 2 Triethylamine 2 ν-Aminopropyltriethoxysilane 1.5

[0062] The acrylic type monomer...

Embodiment 3

[0070] A halogen-free acrylate structural adhesive, consisting of two components A and B, the volume ratio of the A and B components is 10:1.

[0071] The acrylic type monomer of A component selects lauryl methacrylate, triethylene glycol dimethacrylate, polyester acrylate; Described halogen-free flame retardant selects bisphenol A bis(diphenyl phosphate); The toughening agent is selected from SBS resin; the stabilizer is selected from p-hydroxyanisole, disodium edetate; the accelerator is selected from dimethylaniline; Oxysilane. The specific component contents are shown in Table 5.

[0072] table 5

[0073] A component raw material Weight ratio lauryl methacrylate 16 Triethylene glycol dimethacrylate 16 polyester acrylate 16 Bisphenol A bis(diphenyl phosphate) 16 SBS resin 16 p-Hydroxyanisole 2 Disodium edetate 2 Dimethylaniline 5 Triaminofunctional Propyltrimethoxysilane 1.8

[0074] The acrylic monomer...

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Abstract

The invention discloses a bi-component halogen-free flame-retardant acrylate structural adhesive, which comprises a component A and a component B, wherein the volume ratio of the component A to the component B is 10:1, the component A comprises the following raw materials in parts by weight: 20-60 parts of an acrylate monomers, 5-20 parts of a halogen-free flame retardant, 5-20 parts of a toughening agent, 1-5 parts of a stabilizer, 0.5-2 parts of a coupling agent and 0.1-5 parts of an accelerant, and the component B is prepared from the following raw materials in parts by weight: 10 to 30 parts of an acrylate monomer, 10 to 50 parts of a plasticizers, 3 to 10 parts of an oxidizing agent and 0.1 to 0.5 part of a polymerization inhibitor. The invention discloses a preparation method of the bi-component halogen-free flame-retardant acrylate structural adhesive. The invention relates to the technical field of adhesives, and particularly provides a bi-component halogen-free flame-retardant acrylate structural adhesive which is excellent in flame retardant property, high in stability, good in extrudability and thixotropy and excellent in mechanical property and a preparation method of the bi-component halogen-free flame-retardant acrylate structural adhesive.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to a two-component halogen-free flame-retardant acrylate structural adhesive and a preparation method thereof. Background technique [0002] Acrylic structural adhesives are widely used in electronics, aerospace, vehicles, ships and other fields due to their high bonding strength, rapid curing at room temperature, excellent weather resistance and stability, and good comprehensive performance. However, acrylate copolymers are flammable polymers composed of three elements: carbon, hydrogen, and oxygen, and their applications in fields that need to meet flame retardant requirements are greatly limited. [0003] Especially with the ever-increasing demand for flame retardancy in shipbuilding and other fields, acrylic structural adhesive products need better flame retardancy while maintaining the original strength and toughness, which cannot be fully met by existing products. Contents...

Claims

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Application Information

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IPC IPC(8): C09J171/02C09J175/14C09J167/06C09J11/06C09J11/08
CPCC09J171/02C09J175/14C09J167/06C09J11/06C09J11/08C08L2201/02C08L51/04C08K5/523C08L55/02C08K5/527C08L53/02
Inventor 许林利
Owner 南京博新新材料有限公司
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