Glaze for ultrathin ceramic rock plate and preparation method and application of glaze

A technology for ceramics and rock slabs, which is applied in the field of glazes for ultra-thin ceramic rock slabs and its preparation, and can solve problems such as high prices, limited digital glaze covering power, and easy penetration of green bodies

Active Publication Date: 2021-09-14
FOSHAN SANSHUI CREATE TIDE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the glaze used in the traditional bell jar glazing and spraying process is pure water glaze, and water easily penetrates the green body and seriously affects the strength of the green body of this type of rock slab products, resulting in easy cracking during the firing process or products in the later stage. It is easy to break during processing, so it is not suitable for glazing of this kind of slate products
However, the digital spray glazing process of digital glaze requires an expensive inkjet printer and nozzle, and compared with the traditional glazing process, the amount of glaze applied by the digital spray glazing process is limited, resulting in limited hiding power of the digital glaze, resulting in ultra-thin ceramic rock slabs The color of the product is poor, the wear resistance is poor, and the glaze is not fine enough, which leads to the poor texture of the ultra-thin ceramic rock plate product

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0072] A preparation method of a glaze for ultra-thin ceramic rock slabs of the present embodiment comprises the following steps:

[0073] Preparation of step S1 top glaze:

[0074] Step S11, add 13% ethylene glycol, 10% glycerin, 0.1% Surfynol 440, 0.1% Tego® Foamex 810, 0.3% BYK-410 and 3% self-made anhydrous polyacrylic acid dispersant into the vertical sand mill, Stir well to form a transparent solution 1.

[0075] Step S12, slowly add 20% albite, 9% dolomite, 5.5% bauxite, 5.5% zirconium silicate and 5% matte frit powder to transparent solution 1 (matte frit powder consists of 58% SiO 2 , 23% Al 2 o 3 , 5.6%K 2 O, 3.2% Na 2 O, 3% CaO, 5.2% MgO and 2% SrO), grind while stirring, the grinding medium is 1mm zirconia ball, grind to D 97 was 7.798 μm, and glaze suspension 1 was obtained.

[0076] Step S13, adding the remaining 18.5% ethylene glycol and 10% glycerin to the above glaze suspension 1 for performance adjustment, the adjusted glaze suspension 1 has a viscosi...

Embodiment 2

[0086] A preparation method of a glaze for ultra-thin ceramic rock slabs of the present embodiment comprises the following steps:

[0087] Preparation of step S1 top glaze:

[0088] Step S11, 9% ethylene glycol, 15% diethylene glycol, 0.15% Tego® Wet 505, 0.15% SN-Defoamer485, 0.5% Vok®-Keperrhevok-422 and 2.5% self-made anhydrous polyacrylic acid dispersant were added to In a vertical sand mill, stir evenly to form a transparent solution 1.

[0089] Step S12, slowly add 21% albite feldspar, 12% dolomite, 6% bauxite, 6% zirconium silicate and 3% matte frit powder to transparent solution 1 (matte frit powder consists of 63% SiO 2 , 20% Al 2 o 3 , 3%K 2 O, 4.2% Na 2 O, 4.2% CaO, 2% MgO and 3.6% SrO), grind while stirring, the grinding medium is 1mm zirconia ball, grind to D 97 was 9.237 μm, and glaze suspension 1 was obtained.

[0090] Step S13, adding the remaining 14.7% ethylene glycol and 10% diethylene glycol to the above glaze suspension 1 for performance adjustment...

Embodiment 3

[0100] A preparation method of a glaze for ultra-thin ceramic rock slabs of the present embodiment comprises the following steps:

[0101] Preparation of step S1 top glaze:

[0102] Step S11, mix 10% isopropanol, 14% glycerin, 5% diethylene glycol monobutyl ether, 0.15% Toynol® Superwet-300, 0.15% Tego® Foamex 810, 0.5% Vok®-Keperrhevok-422 and 3% Add the self-made anhydrous polyacrylic acid dispersant into a vertical sand mill, and stir evenly to form a transparent solution 1.

[0103] Step S12, slowly add 23% albite feldspar, 12% dolomite, 6% bauxite, 6% zirconium silicate and 5% matte frit powder to transparent solution 1 (matte frit powder consists of 62% SiO 2 , 21% Al 2 o 3 , 3%K 2 O, 3% Na 2 O, 4% CaO, 4% MgO and 3% SrO), grind while stirring, the grinding medium is 1mm zirconia ball, grind to D 97 was 7.337 μm, and glaze suspension 1 was obtained.

[0104] Step S13, adding the remaining 5.2% glycerin and 10% diethylene glycol monobutyl ether to the above-mentio...

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PUM

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Abstract

The invention relates to glaze for an ultrathin ceramic rock plate and a preparation method and application of the glaze. The glaze comprises a cover glaze and a protective glaze, and the cover glaze is composed of a cover glaze dry material, a water-soluble organic solvent, a wetting leveling agent, a defoaming agent, an anti-settling agent and a dispersing agent in specific content; the cover glaze dry material is prepared from albite, dolomite, high bauxite, zirconium silicate and matte frit powder with specific content; the protective glaze is prepared from the protective glaze dry material, the water-soluble organic solvent, the wetting leveling agent, the defoaming agent, the anti-settling agent and the dispersing agent with specific contents; the protective glaze dry material is prepared from wollastonite, albite, kaolin, calcined talc, calcined zinc oxide, calcined aluminum oxide and bright frit powder with specific content; the dispersing agent is a self-made anhydrous polyacrylic acid dispersing agent. The glaze is suitable for a high-pressure glaze spraying process, after the glaze is sprayed to the surface of the green body of the ultrathin ceramic rock plate with the thickness of 3 mm or below through the high-pressure glaze spraying process, the strength of the green body is not affected, the defect rate of a product after firing is effectively reduced, the glazing cost is low, and the product quality is high.

Description

technical field [0001] The invention relates to the technical field of glazes, in particular to a glaze for ultra-thin ceramic rock slabs and a preparation method and application thereof. Background technique [0002] In recent years, ceramic rock slabs are widely used as home decoration materials because they can withstand cutting, drilling, grinding and other processing processes. They can be used for background walls, cabinets, wardrobes, tea sets, bathroom cabinets, sinks, doors and Kitchen cooktop panels, etc. The rock slabs used for cabinets and wardrobes are generally required to use ultra-thin ceramic rock slabs with a thickness of 3mm, and the production of 3mm ultra-thin ceramic rock slabs is still a technical difficulty that needs to be overcome urgently in China. Only a few domestic companies can Most of the production is imported from Italy. The production difficulty of this kind of slate products is that the bricks are too thin and the strength is low. How to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C8/20C03C8/16C03C8/02C03C8/04C04B41/89C08F283/06C08F220/06C08F212/08
CPCC03C8/20C03C8/16C03C8/02C03C8/04C04B41/89C04B41/52C08F283/065C04B41/5022C04B41/4539C04B41/4543C08F220/06C08F212/08
Inventor 周军张天杰戴建斌刘腾邓佳平肖元成王衔雯
Owner FOSHAN SANSHUI CREATE TIDE
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