Preparation method of quick-setting hot-melt marking coating

A marking paint, hot-melt technology, applied in fireproof paint, luminous paint, epoxy resin paint, etc., can solve the problems of not being able to warn at night, easy reunion of raw materials, short fluorescence quenching time, etc., to achieve Good performance, good thermal stability, good wear resistance

Pending Publication Date: 2021-08-31
天途路业集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Road marking paint is referred to as marking paint for short. It is divided into two types: hot-melt type and solvent type. Most roads in Japan use hot-melt type paint, and countries such as Europe and the United States gradually increase the amount of use. Hot-melt type marking paint on the market is often used Titanium dioxide is used as a pigment, and titanium dioxide will fade and become unclear in the long-term sunshine process, and when using it, the construction personnel also found that the raw materials are prone to agglomeration during use, which is inconvenient to use. At the same time, they also found that Some luminescent paints on the market at night will also add calcium carbonate, titanium dioxide, disodium ethylenediamine tetraacetate, silicon dioxide and other ingredients, but the preparation process is to directly mix them, and the paint obtained by direct mixing is just mixing them. The basic characteristics of the material are revealed, but in the actual use of the construction personnel, the luminous time will be short and the luminous brightness will be low. After 2-3 days of use, there will be no luminous phenomenon, and the fluorescence quenching will occur, especially In the case of high temperature, the fluorescence quenching time is shorter, and it cannot play a warning role at night. Therefore, the existing technology needs further improvement

Method used

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  • Preparation method of quick-setting hot-melt marking coating
  • Preparation method of quick-setting hot-melt marking coating

Examples

Experimental program
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Effect test

Embodiment 1

[0013] A preparation method of quick-setting hot-melt marking paint, prepared by the following steps: (1) methyl methacrylate, potassium persulfate, rare earth material and deionized water in N 2 At 65°C, stir for 1 h at a rate of 30rmp / min, centrifuge, filter, take the precipitate, and dry to prepare polymethyl methacrylate nanospheres with fluorescent properties; (2) nano-TiO 2 Mix with rare earth material deionized water, add porous calcium carbonate microspheres, ultrasonic 20min, then add disodium edetate solution, stir for 20min, dry; (3) add benzoyl peroxide, step (1) The prepared polymethyl methacrylate nanospheres, polypropylene, pearl powder, nano-silica, hollow porous glass microspheres, polypropylene, pearl powder, isocyanate, ethylene-vinyl acetate copolymer, polyvinyl chloride, epoxy Resin, rare earth material, silane coupling agent, polydimethylsiloxane, antifoaming agent, mixed, used, it is used after heating.

[0014] The mass volume ratio of methyl methacryl...

Embodiment 2

[0022] A preparation method of quick-setting hot-melt marking paint, prepared by the following steps: (1) methyl methacrylate, potassium persulfate, rare earth material and deionized water in N 2 Stir at 70°C for 1.5h at a rate of 35rmp / min, centrifuge, filter, take the precipitate, and dry to obtain polymethyl methacrylate nanospheres with fluorescent properties; (2) Nano TiO 2 Mix it with rare earth material deionized water, add porous calcium carbonate microspheres, ultrasonicate for 25 minutes, then add disodium edetate solution, stir for 25 minutes, and dry; (3) add benzoyl peroxide, step (1) The prepared polymethyl methacrylate nanospheres, polypropylene, pearl powder, nano-silica, hollow porous glass microspheres, polypropylene, pearl powder, isocyanate, ethylene-vinyl acetate copolymer, polyvinyl chloride, epoxy Resin, rare earth material, silane coupling agent, polydimethylsiloxane, antifoaming agent, mixed, used, it is used after heating.

[0023] The mass volume ra...

Embodiment 3

[0031] A preparation method of quick-setting hot-melt marking paint, prepared by the following steps: (1) methyl methacrylate, potassium persulfate, rare earth material and deionized water in N 2 At 75°C, stir for 2h at a rate of 45rmp / min, centrifuge, filter, take the precipitate, and dry to prepare polymethyl methacrylate nanospheres with fluorescent properties; (2) nano-TiO 2 Mix with rare earth material deionized water, add porous calcium carbonate microspheres, ultrasonic 20-30min, then add disodium edetate solution, stir for 30min, and dry; (3) add benzoyl peroxide, step ( 1) The prepared polymethyl methacrylate nanospheres, polypropylene, pearl powder, nano silicon dioxide, hollow porous glass microspheres, polypropylene, pearl powder, isocyanate, ethylene-vinyl acetate copolymer, polyvinyl chloride, Epoxy resin, rare earth material, silane coupling agent, polydimethylsiloxane, antifoaming agent, mixed and used, use it after heating.

[0032] The mass volume ratio of m...

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Abstract

The invention relates to the technical field of processing of road marking coatings, and in particular, relates to a preparation method of a quick-setting hot-melt marking coating, wherein the preparation method is prepared by the following steps: (1) stirring methyl methacrylate, potassium persulfate, a rare earth material and deionized water in N2 at the temperature of 65-75 DEG C and at the rate of 30-45 rmp / min for 1-2 hours, centrifuging, filtering, taking precipitate, and drying, to obtain polymethyl methacrylate nanospheres with the fluorescence characteristic; and (2) mixing nano TiO2 with rare earth material deionized water, then adding the porous calcium carbonate microspheres, carrying out ultrasonic treatment for 20-30 minutes, then adding an ethylenediamine tetraacetic acid disodium solution, stirring for 20-30 minutes, and drying. The prepared coating has the advantages of high reflection coefficient, high temperature resistance, wear resistance, long fluorescence duration and high fluorescence brightness.

Description

technical field [0001] The invention relates to the technical field of road marking paint processing, in particular to a preparation method of quick-setting hot-melt marking paint. Background technique [0002] Road marking paint is referred to as marking paint for short. It is divided into two types: hot-melt type and solvent type. Most roads in Japan use hot-melt type paint, and countries such as Europe and the United States gradually increase the amount of use. Hot-melt type marking paint on the market is often used Titanium dioxide is used as a pigment, and titanium dioxide will fade and become unclear in the long-term sunshine process, and when using it, the construction personnel also found that the raw materials are prone to agglomeration during use, which is inconvenient to use. At the same time, they also found that Some luminescent paints on the market at night will also add calcium carbonate, titanium dioxide, disodium ethylenediamine tetraacetate, silicon dioxide...

Claims

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Application Information

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IPC IPC(8): C09D133/12C09D123/12C09D123/08C09D127/06C09D163/00C09D7/61C09D7/63C09D5/18C09D5/33C09D5/22
CPCC08K2003/2241C08K2201/011C09D5/004C09D5/18C09D5/22C09D133/12C09D7/61C09D7/63C09D7/70C08L23/12C08L23/0853C08L27/06C08L63/00C08K3/22C08K7/24C08K5/175
Inventor 程博李付宽李长江
Owner 天途路业集团有限公司
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