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High-temperature-resistant conductive copper alloy protective agent, preparation method and copper alloy passivation method

A technology of copper alloy and protective agent, which is applied in the coating process of metal materials, etc., can solve problems such as corrosion, and achieve the effects of improving efficiency, reducing reaction time, and simplifying preparation

Active Publication Date: 2021-07-13
深圳市钝化技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Copper alloys that have been passivated by traditional hexavalent chromium or benzotriazole will usually change color after 1-3 minutes of treatment at a high temperature of 200 ° C, and will disappear after 4-8 hours of treatment in neutral salt spray. Corrosion will occur, but with the development of science and technology, the precision and performance of terminal application products have higher requirements on the performance of copper alloys. Copper alloy protective agent, and applied to the passivation treatment of copper alloy to meet market demand

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] A high-temperature-resistant and conductive copper alloy protective agent, the ratio of its raw materials is shown in Table 1.

[0041] Wherein, the wetting agent is sodium cetyl sulfate, and is selected from Shanghai Gaoming Chemical Co., Ltd.; the chelating agent is ethylenediaminetetraacetic acid, and is selected from Guangzhou Jieluhua Biotechnology Co., Ltd.

[0042] The emulsifying dispersant is a mixture of fatty alcohol polyoxyethylene ether, isomerized tridecyl alcohol polyoxyethylene ether, fatty alcohol polyoxyethylene ether sodium sulfate, and fatty alcohol polyoxyethylene ether, isomeric tridecyl alcohol polyoxyethylene ether, The weight ratio of fatty alcohol polyoxyethylene ether sodium sulfate is 3:5:1; fatty alcohol polyoxyethylene ether is AE0-7, and is selected from Sangda Chemical (Nantong) Co., Ltd.; isomeric tridecyl alcohol polyoxyethylene Ether is E-1309, and is selected from Sangda Chemical (Nantong) Co., Ltd.; fatty alcohol polyoxyethylene ethe...

Embodiment 2-5

[0046] A high-temperature-resistant and conductive copper alloy protective agent, the difference between it and Example 1 is that the raw material ratio of the copper alloy protective agent is different, and the raw material ratio of the copper alloy protective agent in Examples 2-5 is shown in Table 1. Show.

Embodiment 6

[0048] A high-temperature-resistant and conductive copper alloy protective agent, the difference between it and Example 3 is that the raw material ratio of the emulsifying dispersant is different, fatty alcohol polyoxyethylene ether, isomeric tridecyl alcohol polyoxyethylene ether, fat The weight ratio of alcohol polyoxyethylene ether sodium sulfate is 2:4:1.

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PUM

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Abstract

The invention relates to the technical field of copper alloy protective agents, and particularly discloses a high-temperature-resistant conductive copper alloy protective agent, a preparation method and a copper alloy passivation method. The copper alloy protective agent is prepared from the following raw materials in percentage by weight: 4-6% of diethylene glycol diethyl ether, 30-55% of an emulsifying dispersant, 0.5-1.5% of a wetting agent, 0.3-2% of a chelating agent, 1.5-2.5% of 2-mercaptobenzothiazole, 2.5-3.5% of 2-heptadecyl imidazole, 7.5-12.5% of 2-sulfydryl-5-methylbenzimidazole and the balance deionized water. According to the copper alloy protective agent, through the synergistic effect of the raw materials, the high temperature resistance and the salt fog resistance of a passivated copper alloy are effectively improved, the service life of the passivated copper alloy is prolonged, the stability of the passivated copper alloy is improved, the using effect of the copper alloy protective agent is also improved, and the market requirements are met.

Description

technical field [0001] The application relates to the technical field of copper alloy protective agent, more specifically, it relates to a high temperature resistant and conductive copper alloy protective agent, a preparation method and a copper alloy passivation method. Background technique [0002] Copper alloy is an alloy composed of pure copper as the base and adding one or several other elements. It has good thermal conductivity and electrical conductivity, and is widely used in military, industrial, electronic, civil, etc. Due to the limitation of the use environment, if the copper alloy is not treated, its surface is prone to corrosion. Therefore, it is necessary to passivate the copper alloy and improve the service life of the copper alloy. Copper alloys that have been passivated by traditional hexavalent chromium or benzotriazole will usually change color after 1-3 minutes of treatment at a high temperature of 200 ° C, and will disappear after 4-8 hours of treatment...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F11/10C23C22/68
CPCC23F11/10C23C22/68
Inventor 何汉泉谢修性
Owner 深圳市钝化技术有限公司
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