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Ultrasonic alternating-current flocculation dephosphorization device and method

A technology of alternating current and electric flocculation, applied in chemical instruments and methods, water/sludge/sewage treatment, water pollutants, etc., can solve the problems of discoloration of water body, rise of waste water, easy passivation of plate surface, etc., to prevent extreme Effect of plate passivation, reduction of concentration polarization, and enhancement of treatment effect

Pending Publication Date: 2021-06-01
长沙工研院环保有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The chemical flocculation method will cause the pH of the wastewater to rise and produce a large amount of sludge. Electrodialysis can only concentrate phosphorus together and cannot remove phosphorus fundamentally. The adsorption method is rarely used for phosphorus removal in actual life due to its regeneration problem.
Electrocoagulation is often used in sewage phosphorus removal, but electrocoagulation also has several disadvantages: the surface of the plate is easily passivated, which affects the efficiency of phosphorus removal; the flocs produced quickly settle to the bottom of the tank, and the capture of phosphorus is not complete ;The iron plate is easy to produce ferrous ions, and the ferrous ions react with the color-forming substances in the water to form organic iron compounds that are difficult to flocculate and settle, resulting in discoloration of the water body

Method used

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  • Ultrasonic alternating-current flocculation dephosphorization device and method
  • Ultrasonic alternating-current flocculation dephosphorization device and method
  • Ultrasonic alternating-current flocculation dephosphorization device and method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] In this example, the method for treating phosphorus-containing wastewater by ultrasonic alternating current coagulation of phosphorus-containing wastewater is to adjust the pH of the simulated wastewater to 8 with sodium hydroxide, and the pole plates in the electrocoagulation reaction tank are soluble iron plates, and the iron plates between the iron plates It is formed in parallel, the pole plates are arranged in the form of baffle plates, and the distance between the pole plates is 1cm. The power supply in the electrocoagulation reaction tank is AC power, the input frequency is 50Hz, the voltage is 220V, the output voltage is 35V, the duty cycle is 80%, the output frequency is 1000Hz, and the output current density is 2.5A / dm 2 . Ultrasonic frequency is 30KHz. See Table 1 for the processing results.

[0048] Table 1 Treatment effect of phosphorus-containing wastewater under different residence times

[0049] dwell time indicator TP before treatment (mg...

Embodiment 2

[0051] In this example, the method for treating phosphorus-containing wastewater by ultrasonic alternating current coagulation of phosphorus-containing wastewater is to adjust the pH of the simulated wastewater to 8 with sodium hydroxide, and the pole plates in the electrocoagulation reaction tank are soluble iron plates, and the iron plates between the iron plates It is formed in parallel, the pole plates are arranged in the form of baffle plates, and the distance between the pole plates is 3cm. The power supply in the electrocoagulation reaction tank is AC power, the input frequency is 50Hz, the voltage is 220V, the output voltage is 35V, the duty cycle is 80%, the output frequency is 1000Hz, and the output current density is 2.5A / dm 2 . Ultrasonic frequency is 30KHz. See Table 2 for the processing results.

[0052] Table 2 Treatment effect of phosphorus-containing wastewater under different residence times

[0053] dwell time indicator TP before treatment (mg...

Embodiment 3

[0055] In this example, the method for treating phosphorus-containing wastewater by ultrasonic alternating current coagulation of phosphorus-containing wastewater is to adjust the pH of the simulated wastewater to 8 with sodium hydroxide, and the pole plates in the electrocoagulation reaction tank are soluble iron plates, and the iron plates between the iron plates It is formed in parallel, the pole plates are arranged in the form of baffle plates, and the distance between the pole plates is 1cm. The power supply in the electrocoagulation reaction tank is AC power, the input frequency is 50Hz, the voltage is 220V, the output voltage is 25V, the duty cycle is 80%, the output frequency is 1000Hz, and the output current density is 2.0A / dm 2 . Ultrasonic frequency is 30KHz. See Table 3 for the processing results.

[0056] Table 3 Treatment effect of phosphorus-containing wastewater under different residence times

[0057]

[0058]

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Abstract

The invention discloses an ultrasonic alternating-current flocculation dephosphorization device and method. The ultrasonic alternating-current electric flocculation dephosphorization device comprises an electric flocculation reaction tank and an ultrasonic generator. A plurality of first polar plates and second polar plates which are parallel to each other are alternately arranged in the electric flocculation reaction tank from left to right, and the first polar plates and the second polar plates are connected with two polar plates of a pulse alternating-current power supply respectively. An ultrasonic probe of the ultrasonic generator is inserted into the electric flocculation reaction tank. Alternating-current pulse electric signals are adopted, polar plate polarization can be effectively avoided, each polar plate can generate flocculation substances, wastewater is in full contact with the flocculation substances generated by the polar plates through the high polar plates and the low polar plates, meanwhile, the liquid phase is homogenized through the coupling ultrasonic technology, and polar plate polarization is avoided.

Description

technical field [0001] The invention belongs to the technical field of phosphorus-containing wastewater treatment, and in particular relates to an ultrasonic alternating current flocculation phosphorus removal device and method. Background technique [0002] With the increasing development and utilization of environmental resources by human beings, a large amount of domestic sewage and industrial wastewater containing phosphorus nutrients are discharged into rivers and lakes, which increases the phosphorus load of water bodies and leads to eutrophication of water bodies. According to statistics, the main lakes in my country are polluted by phosphorus and cause eutrophication, accounting for more than 50% of the lakes in statistics. Phosphorus in eutrophic water bodies mainly includes phosphorus entering the water body from the outside, and phosphorus released into the water body from sediments such as the bottom mud inside the water body. Studies have shown that more than 8...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/12C02F101/10C02F101/30
CPCC02F9/00C02F1/463C02F1/36C02F1/66C02F2101/30C02F2101/105
Inventor 陈帅奇周益辉邱敬贤曾木平何曦杨霆杨准
Owner 长沙工研院环保有限公司
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